Abstract: A method of controlling a chemical reaction is disclosed. The method may include feeding a solution at a first flow rate into a reactor and detecting a sound in the reactor using a sound sensor that is adjacent to the reactor. The sound sensor may convert the sound into a sound signal. After the sound signal is acquired, it is compared to a stored sound signal or a stored sound threshold to detect a reaction event. The method may include adjusting the flow rate of solutions into the reactor in response to the reaction event.

Abstract: A system configured to capture CO2 and able to be washed of the captured CO2 includes a material including an ionic liquid configured to capture CO2 in response to exposure to a gas comprising CO2 and to a thermal energy source and an aerogel holding the ionic liquid therein. The system may also include a washing solution configured to wash the captured CO2 from the material.

Abstract: The present disclosure relates, in part, to enhanced weathering systems and/or apparatuses and methods of use thereof. In one aspect, the present disclosure provides a method of at least partially sequestering CO2 from an influent aqueous solution comprising aqueous and/or gaseous CO2. In another aspect, the present disclosure provides a method of at least partially sequestering CO2 from a gaseous CO2 source. In another aspect, the present disclosure provides systems and/or apparatuses suitable for use in the methods described herein. In another aspect, the present disclosure provides a method of optimizing the design and operation of a system for at least partial sequestration of CO2 from a water source.

Abstract: The present invention discloses a method for removing carbon dioxide from a reaction gas. The present invention fully utilizes the available heat in each part of the carbon dioxide removal system to reduce external heat exchange, and thereby significantly reduces the carbon dioxide content in the gas returned to the reactor, and also greatly reduces the steam consumption during the regeneration of the rich decarburizing solution. The present invention also discloses a system for removing carbon dioxide from the reaction gas and use thereof.

Abstract: A method for extracting a rare earth metal from a mixture of one or more rare earth metals, said method comprising contacting an acidic solution of the rare earth metal with a composition which comprises an ionic liquid to form an aqueous phase and a non-aqueous phase into which the rare earth metal has been selectively extracted, wherein the ionic liquid has the formula [Ca++][X?], where [X?] represents a phosphinate anion.

Abstract: A method for removing methane and non-methane volatile organic compound concentrations from a gas stream. The method includes exposing the target gas to a halogen gas and a light from a suitable light source having a wavelength sufficient to activate halogen gas to halogen radicals, wherein the halogen radicals react with the VOC in the target gas to provide the target gas with a removed concentration of VOC as well as a device including a reaction chamber for reacting the halogen radicals with the VOC in the target gas.

Abstract: A selective desulfurization method implemented based on a high gravity reactor is provided, in the technical field of desulfurization separation. The selective desulfurization method includes the following steps: driving the packed bed to rotate through the driving device; introducing feed gas containing hydrogen sulfide into the reactor through the air inlet, and enabling the feed gas to enter the packed bed and move along a direction from a outer packing area of multiple areas to an inner packing area of the multiple of packing areas; introducing a desulfurizer into the packed bed through the liquid inlet, and enabling the desulfurizer to move along a direction from the inner packing area to the outer packing area under an action of centrifugal force. Deflectors can change the flow direction of the desulfurizer liquid after passing through the inner packing area.

Abstract: A process for obtaining vanadium component in the form of vanadium oxide from gasifier slag is disclosed. The process comprises pulverizing the slag to obtain pulverized slag, which is blended with water and an alkali salt to obtain a slurry. The slurry is dried and then roasted in the presence of air to obtain a roasted slag. The roasted slag is leached to obtain a first filtrate comprising the vanadium component. The first filtrate is reacted with a magnesium salt to remove a silica component in the form of a precipitate. The silica free second filtrate is reacted with an ammonium salt to obtain ammonium metavanadate, which is further calcined to obtain the significant amount of vanadium pentoxide (V2O5).

Abstract: This invention provides compositions and methods that inhibit formation of alkenyl sulfide polymers and allow the hydrogen sulfide to be removed when scavenging hydrogen sulfide by reaction with aldehydes.

Abstract: According to one embodiment, a magnesium-recycling hydrogen generation system includes: a by-product acquisition unit that separates a by-product from a post-reaction solution, which is a solution after reacting with a hydrogen generation material containing a hydrogen-containing magnesium compound that generates hydrogen via a reaction with the solution, to acquire the by-product including more than one type of oxygen-containing magnesium compound that contains oxygen produced by the reaction, a raw material production unit that reacts the by-product with a halogen-containing substance containing halogen and other atoms than the halogen to produce a raw material containing magnesium halide, a hydrogen generation material production unit that reduces the raw material with plasma containing hydrogen to produce the hydrogen generation material, and a hydrogen generator that reacts the hydrogen generation material with the solution to generate hydrogen.

Abstract: A hybrid post-combustion carbon dioxide capture system for capturing carbon dioxide from a flue gas includes a compressor adapted to produce a compressed flue gas stream, a membrane-based carbon dioxide separation unit configured to receive a first portion of the compressed flue gas stream from the compressor, and an aqueous-based carbon dioxide capture unit configured to receive a second portion of the compressed flue gas stream from the compressor whereby the compressed flue gas stream is processed in parallel by the membrane-based carbon dioxide separation unit and the aqueous-based carbon dioxide capture unit.

Abstract: A method for separating a Lewis acid gas from a fluid mixture, comprising contacting the fluid mixture with a reduced electroactive species; a non-aqueous electrolyte; and a stabilizing additive to form an anion adduct between the Lewis acid gas and the reduced electroactive species, wherein the electroactive species comprises an oxidized state, and at least one reduced state that bonds with the Lewis acid gas to form the anion adduct, wherein the stabilizing additive comprises a cationic Lewis acid, a hydrogen-bond donor, or a combination thereof, and the stabilizing additive is present in an effective amount to kinetically favor the forming of the anion adduct from the reduced electroactive species and thermodynamically favor the forming of the anion adduct in the thermodynamic equilibrium between the anion adduct and the reduced electroactive species.

Abstract: Condensable metal halide materials, such as but not limited to tungsten hexachloride and tungsten pentachloride can be used deposit films metal or metal containing films in a chemical vapor deposition (CVD) or atomic layer deposition process. Described herein are high purity tungsten hexachloride and tungsten pentachloride systems and methods to purify tungsten hexachloride and tungsten pentachloride raw materials. There is provided a purified tungsten hexachloride and tungsten pentachloride containing less than 10 ppm, preferably less than 5 ppm, more preferably less than 1 ppm, and most preferably less than 0.5 ppm of iron and/or molybdenum; and less than 10 ppm, preferably less than 5 ppm of all other trace metals combined including but not limited to aluminum, potassium and sodium.

Abstract: Disclosed are a method and a system for recycling carbon dioxide. The method includes chlorinating a calcium-containing silicate and/or a magnesium-containing silicate to obtain a calcium chloride and/or magnesium chloride, mixing the calcium chloride and/or magnesium chloride with ammonia water and carbon dioxide and performing a carbonation reaction to recover the carbon dioxide and convert it into calcium carbonate and/or magnesium carbonate while generating an ammonium chloride solution, and recovering the ammonium chloride solution generated in the carbonation reaction. The ammonium chloride solution after being concentrated or hydrogen chloride generated from a decomposition reaction of the ammonium chloride solution is directly used to chlorinate the calcium-containing silicate and/or the magnesium-containing silicate. The ammonium chloride is used as a catalyst for the entire mineralization of the carbon dioxide, the final product is the calcium carbonate and/or the magnesium carbonate.

Abstract: A cooling absorption tower for a CO2 recovery device, comprises: an outer shell; a cooling section for cooling a flue gas, the cooling section being disposed in the outer shell; and an absorbing section configured to cause CO2 in the flue gas cooled by the cooling section to be absorbed in an absorption solvent, the absorbing section being disposed in the outer shell and above the cooling section.

Abstract: Disclosed herein are methods of producing a gas at a controlled rate, the methods comprising directing air through a layered bed to produce a gas. The layered bed comprises alternating layers of a layer of dry particles comprising a precursor and a layer of dry particles comprising a proton-generating species. The gas is produced at a rate that is controlled by controlling the presence or absence of air flowing though the layered bed, the amount of time the air flows through the layered bed, the total number of layers in the layered bed, the average thickness of each of the layers of dry particles comprising the precursor in the layered bed, the average thickness of each of the layers of dry particles comprising the proton-generating species in the layered bed, the temperature the method is performed at, or a combination thereof.

Abstract: Disclosed are metal organic frameworks (MOFs) for adsorbing guest species, methods for the separation of gases using the MOFs, and systems comprising the MOFs. The MOFs comprise a plurality of secondary building units (SBUs), each SBU comprising a repeating unit of one metal cation connected to another metal cation via a first moiety of an organic linker; a layer of connected adjacent SBUs in which a second moiety of the linker in a first SBU is connected to a metal cation of an adjacent SBU, and wherein adjacent layers are connected to each other via linker-to-linker bonding interactions.

Abstract: The present invention relates to a method for recovering a rare metal salt, the method including: an acid treatment step of obtaining a rare metal-containing acidic aqueous solution by bringing a material including a monovalent rare metal and a polyvalent rare metal into contact with an acidic aqueous solution; a separation step of obtaining permeated water including the monovalent rare metal and non-permeated water including the polyvalent rare metal from the rare metal-containing acidic aqueous solution by using a nanofiltration membrane satisfying the condition (1); and a concentration step of obtaining non-permeated water having a higher concentration of the monovalent rare metal and permeated water having a lower concentration of the monovalent rare metal than that of the permeated water in the separation step, by using a reverse osmosis membrane.

Abstract: Methods, kits, cartridges, and compounds related to generating chlorine dioxide by exposing ClO2? to at least one of an iron porphyrin catalyst or an iron porphyrazine catalyst are described.

Abstract: In a method for producing hydrogen cyanide by passing a feed mixture comprising ammonia and methane through reaction tubes, coated on the inner surface with a catalyst comprising platinum, at a reaction temperature of 1000° C. to 1400° C., operated for a time period of at least 100 h, the concentration difference between the ammonia concentration and the methane concentration in the product gas mixture is maintained in a range of from 1.05 % by volume to 3.0% by volume for at least 80% of the time.