Abstract: A process for the production of olefins in an olefin plant, which includes an olefin pyrolysis furnace having pyrolysis tubes in which hydrocarbon feedstock is cracked, comprises introducing hydrocarbon feed substantially free of phosphorous-containing compounds into the pyrolysis furnace and operating the furnace under pyrolysis conditions producing olefin-containing effluent therefrom wherein the pyrolysis tubes have an effective passivator of metal catalytic sites bonded to the exposed metal surface by injecting an effective passivator into the furnace at a point above the dew point of water.
Type:
Grant
Filed:
December 9, 1993
Date of Patent:
August 29, 1995
Assignee:
Amoco Corporation
Inventors:
Don M. Taylor, Lynn M. Allen, Myron E. Schroeder
Abstract: The aging rate of the catalyst in a process for the concurrent alkylation of aromatic with olefin and distillation of reaction components (reactants and products) in a distillation column reactor in a catalyst bed wherein the catalyst also serves as the distillation structure, is retarded by limiting the conversion of olefin in the catalyst bed to about 90 percent. A portion up to and including the entire unreacted aromatic and olefin in the overhead from the distillation column reactor are condensed and fed to a fixed bed alkylation reactor to substantially finish the conversion with a portion of the effluent from the fixed bed reactor recycled thereto to control the olefin content in the fixed bed reactor inlet to less than one volume percent, preferably less than 0.50 volume percent and thereby reduce the aging in that catalyst. A fixed bed transalkylation reactor is used to convert the polysubstituted alkylated aromatic products to mono-substituted alkylated aromatic products.
Abstract: A zeolite, designated NU-85, is an intergrowth of zeolites EU-1 and NU-87. The zeolite is a useful catalyst in a wide variety of hydrocarbon conversion reactions including isomerisation and alkylation.
Type:
Grant
Filed:
October 5, 1993
Date of Patent:
August 29, 1995
Assignee:
Imperial Chemical Industries PLC
Inventors:
John L. Casci, Mervyn D. Shannon, Ivan J. S. Lake
Abstract: A method of removing chloride from phosphorus/vanadium/oxygen mixed oxide oxidation catalysts comprising treating a chloride containing catalyst comprising phosphorus, vanadium and oxygen with a stream of gas comprising oxygen, steam and an inert gas at flow rate and temperature and for a period of time to substantially reduce the amount of chloride in the catalyst.
Abstract: Monolithic catalysts with a metal carrier that includes a catalytically coated matrix having at least one stack of several sheet-metal strips of corrugated or alternately corrugated and flat metal strips folded or intertwined with one another are described. The free ends of the metal strips are connected by a joining process with a surrounding jacket tube of any required cross-section. The monolithic catalyst is produced very economically and with a catalytic coating that has a uniform thickness. The at least one stack of sheet-metal strips required for the monolithic catalyst with a metal carrier is assembled from coated metal ribbons cut to length so as to form metal stacks. The stacks may be folded and/or intertwined with themselves or with one another so as to form the matrix. The matrix with intertwined and coated strips is inserted into the jacket tube and the free ends of the metal strips are secured by joining to the jacket tube.
Abstract: An improved process is provided for the manufacture of a catalytically-active carbonaceous char capable of rapidly decomposing hydrogen peroxide in aqueous solutions. The process of the invention uses a low temperature carbonization and extensive oxidation of a bituminous coal or bituminous coal-like material followed by exposure to a nitrogen-containing compound at high temperatures during the initial calcination and/or activation. The resultant catalytically-active chars have the ability to rapidly decompose aqueous solutions of hydrogen peroxide and are useful for catalytic conversion of H.sub.2 S, SO.sub.x, NO.sub.x, chloramines, and/or peroxides in liquid and/or gaseous streams.
Abstract: A low emissions combustor for use in gas turbines which operate at turbine inlet temperatures below about 1250 degrees Kelvin, which comprises;a multiplicity of microlith catalyst elements; andmeans for providing an admixture of fuel and air having an adiabatic flame temperature within the range of 600 to 1250 degrees Kelvin.
Abstract: Provided is an improved process for removing hydrogen sulfide from fluid streams by contacting a hydrogen sulfide contaminated fluid stream with a novel fluidizable sorbent composition comprising zinc oxide, alumina and silica. Further provided is a novel method for producing a fluidizable sorbent composition containing zinc oxide, alumina and silica.
Abstract: A catalyst for exhaust gas purification, comprising a heat-resistant inorganic monolith carrier and a catalyst layer loaded thereon, the catalyst layer including a catalyst composition containing at least one noble metal selected from Pt, Pd and Rh, as an active catalyst component, and active alumina. The catalyst composition has a specific surface area of at least 50 m.sup.2 /g and a porosity of at least 50%. This catalyst for exhaust gas purification contains noble metal(s) in a well dispersed state, has excellent high-temperature durability, and is low in thermal deterioration of catalyst performance. Hence, the catalyst can be suitably used as a converter installed in engine manifolds of gasoline engine automobiles, or as a heater having improved purification ability for the exhaust gases emitted from automobiles during their cold start.
Abstract: Carboxylic polymers useful in detergent compositions contain keto structural units incorporated into the polymer backbone. The units may be introduced by means of the compound 2,2'-diphenyl-4-methylene-1,3-dioxolane. The polymers show better biodegradability than the acrylic and acrylic/maleic polymers commonly used in detergent compositions, while the detergency building (calcium binding) is comparable or better.
Type:
Grant
Filed:
April 7, 1993
Date of Patent:
August 8, 1995
Assignee:
Lever Brothers Company, Division of Conopco, Inc.
Inventors:
Stephen G. Hales, Ezat Khoshdel, Robert Polywka
Abstract: This invention relates to a shaped composition composed of a carbonaceous pyropolymer having recurring units containing at least carbon and hydrogen atoms. The composition is characterized by a crush strength of at least 6 kg and has a bimodal pore distribution having maxima at pore diameters of about 60 to 900 .ANG. and about 120 to 160 .ANG..
Abstract: A preparing process of activated carbon includes steps of: combusting scrap tires containing metal wire at 400.degree. C. to 900.degree. C. under the presence of oxygen, carbon dioxide and vapor; reheating the generated combustible gases up to 800.degree. C. to 900.degree. C. by adding a further fuel; causing the exhaust gas to heat-exchange with a water pipe boiler so that the temperature of the exhaust gas downs to 180.degree. C. to 250.degree. C.; and introducing the exhaust having a temperature of 180.degree. C. to 250.degree. C. into an electric dust collector so as to collect activated carbon. The particle size of the thus obtained distributed substantially in a range of 90 to 110 mesh and the CEC (cation exchange capacity) of the activated carbon falls within 30 to 40.
Type:
Grant
Filed:
February 17, 1994
Date of Patent:
August 1, 1995
Assignee:
The Social Welfare Foundation Hokkaido Rehabily
Abstract: A plane of a treatment liquid holder having a number of through holes faces a treatment surface of a substrate. A treatment liquid is held between the treatment surface and the liquid holder by utilizing a surface tension of the treatment liquid. Since the treatment liquid is applied only to the treatment surface, an extremely small amount of treatment liquid suffices for the treatment. In addition, since a fresh treatment liquid can be used in every treatment, cross-contamination is suppressed and the treatment can be performed with safety at a low cost.
Abstract: Polymers and prepolymers derived from polyoxyalkyleneamines. The polymers and prepolymers may be used in a process for the treatment of wool so as to impart shrink resistance.
Abstract: The invention concerns a process for the recovery of a solvent adsorbed in an adsorber, or other substances which are condensable. The adsorber (3) is, at first, heated to a temperature which is below the decomposition temperature of the solvent, then the adsorber chamber (2) is sealed off from the surroundings and a high negative pressure is applied to the adsorber chamber (2), as a result of which the solvent is desorbed. During a portion of the time when this high negative pressure is applied, the temperature of the adsorber (3) is brought to a value which is above the decomposition temperature of the solvent. In spite of this, there is no decomposition under the noted conditions, however, the high temperature does enable an almost complete desorption of the solvent. Finally, the desorbed solvent is drawn off from the adsorber chamber (2) and condensed.
Abstract: Process for the dehydrogenation of a charge incorporating saturated aliphatic hydrocarbons essentially having 3 to 5 carbon atoms per molecule, in which the charge, previously heated to the reaction temperature and without premixing with the hydrogen, is introduced at the inlet of at least one reactor, where the dehydrogenation reaction is performed in the presence of a catalyst, preferably incorporating a support having at least one oxide of an element chosen from among the groups IIA, IIB, IIIA, IIIB, IVA and IVB of the periodic classification of elements, at least one noble metal from the platinum family, at least one promotor metal and at least one alkali metal or alkaline earth metal.
Type:
Grant
Filed:
August 31, 1994
Date of Patent:
July 25, 1995
Assignee:
Institut Francais du Petrole
Inventors:
Fabienne Le Peltier, Sylvie Robert, Jean Paul Boitiaux, Gerard Leger, Jean Pierre Burzynski
Abstract: A self-heat generating type honeycomb filter is mounted in an exhaust pipe line of an engine, and a plane plate and a corrugated plate are layered, then wound, and the first slit portion and second slit portion having openings, respectively, are formed between an up-stream and down stream side end portions of the plane and corrugated plates. An electric current is applied between the up-stream and down stream side end portions, to heat the first and second slit portions. Accordingly, a self-heat generation type catalytic converter capable of realizing both high resistance and low thermal capacity, and further ensuring a reduction in thermal conduction, and durability, and raising the temperature up to the sufficient level with less power consumption, can be provided.
Abstract: Heavy hydrocarbons are hydrotreated to increase content of components boiling below 1000.degree. F. by contact with Group VIII non-noble metal oxide and Group VI-B metal oxide on alumina having a Total Surface Area of 150-240 m.sup.2 /g, a Total Pore Volume, (TPV) of 0.7-0.98, and a Pore Diameter Distribution whereby .ltoreq.20% of the TPV is present as primary micropores of diameter .ltoreq.100 .ANG., at least about 34% of TPV is present as secondary micropores of diameter of about 100 .ANG.-200 .ANG., and about 26%-46% of the TPV is present as mesopores of diameter >200 .ANG..
Type:
Grant
Filed:
May 16, 1994
Date of Patent:
July 25, 1995
Assignee:
Texaco Inc.
Inventors:
Gerald V. Nelson, Govanon Nongbri, Roy E. Pratt, David E. Sherwood, Jr., Pei-Shing E. Dai
Abstract: A naphtha or a middle distillate hydrocarbon is dehydroaromatized by hydrotreating in the presence of a catalyst containing non-noble Group VIII metal and Group VI-B metal on carbon.
Type:
Grant
Filed:
January 31, 1994
Date of Patent:
July 25, 1995
Assignee:
Texaco Inc.
Inventors:
Chakka Sudhakar, Frank Dolfinger, Jr., Dennis J. Pao, John Hazen
Abstract: A process and an apparatus for separating desired clathrate forming gases from a gas mixture containing the desired clathrate forming gases. The process includes providing a stream of the gas mixture, contacting the stream of the gas mixture with an aqueous solvent to form a solid clathrate hydrate suspension in the aqueous solvent. The forming of the solid clathrate hydrate suspension in the aqueous solution causing the gaseous stream to be thereafter leaner in the desired clathrate forming gases. The solid clathrate hydrate suspension and the aqueous solution are subjected to an elevated temperature and to a reduced pressure to produce a product gaseous stream which is richer in the desired clathrate forming gases.