Abstract: High purity phenol is obtained from cleavage of cumene hydroperoxide by treating the crude phenol product stream in a first treatment zone with an amine, a coarse distillation to obtain an overhead stream comprising phenol, alpha-methyl styrene, cumene, and impurities, and steam distillation of the overhead stream in combination with addition of an amine to the steam distillation column for a second amine treatment step.
Type:
Grant
Filed:
September 27, 1990
Date of Patent:
November 12, 1991
Assignee:
Allied-Signal Inc.
Inventors:
Michael S. O'Donnell, Lamberto Crescentini
Abstract: A method for the separation of indole by distilling an indole-containing reaction fluid obtained by the reaction of aniline with ethylene glycol or by the reaction of N-(.beta.-hydroxyethyl)aniline, which comprises bringing the reaction fluid into contact with a basic substance prior to and/or during the distillation. This method can prevent the deterioration of indole during the distillation procedure.