Abstract: A process for exfoliating untreated 3-dimensional material to produce a 2-dimensional material, said process comprising the steps of mixing the untreated 3-dimensional material in a liquid to provide a mixture; applying shear force to said mixture to exfoliate the 3-dimensional material and produce dispersed exfoliated 2-dimensional material in solution; and removing the shear force applied to said mixture, such that the dispersed exfoliated 2-dimensional material remains free and unaggregated in solution.
Type:
Grant
Filed:
March 14, 2014
Date of Patent:
May 28, 2019
Assignee:
The Provost, Fellows, Foundation Scholars, and the Other Members of Board, of the College of the Holy and Undivided Trinity of Queen Elizabeth Near Dublin
Abstract: Electrochromic compositions for use in devices with electrically controlled absorption of light such as light filters of variable optical density, light emission modulators, and information image displays. The described electrochromic compositions may be used, for example, for creating light-transmitting coatings of buildings for controlling indoor microclimate by regulating the flow of natural light. Specifically, described is an exemplary organic electrochromic composition that is based on biocompatible and biodegradable components and is characterized by an increased service life, a high rate of light-transmission change. The described electrochromic compositions may be prepared in a wide range of light-absorption spectra and coating colors.
Abstract: Copolymers including dioxythiophene repeating units and no acceptor units allow the formation of electrochromic polymers (ECPs) with vivid neutral state colors and very colorless oxidized states that can be switched rapidly. The dioxythiophene repeating units can included in sequences where all of one type of dioxythiophene is included exclusively as isolated dyads or triads within the copolymer, or the copolymer can be an alternating copolymer with propylenedioxythiophene units. Other non-acceptor units can be included in the copolymers. The copolymers are rendered organic solvent soluble by alkyl substituents on repeating units. The inclusion of sterically encumbered acyclic dioxythiophene (AcDOT) units promotes red color while unsubstituted ethylenedioxythiophene (EDOT) units promote blue colors, and their respective content can be manipulated to achieve a desired neutral state color. Soluble copolymers comprising at least 50% EDOT repeating units can be used in supercapacitor applications.
Type:
Grant
Filed:
May 22, 2015
Date of Patent:
May 21, 2019
Assignee:
UNIVERSITY OF FLORIDA RESEARCH FOUNDATION, INCORPORATED
Inventors:
John Robert Reynolds, Michael R. Craig, Aubrey Lynn Dyer, Justin Adam Kerszulis
Abstract: Disclosed is an extension of a partial application of the previous invention (P.R.C. Pat. Application No. 201110357015.X) that overcomes the issues of the previous invention requiring a too long curing time of the accelerator, curing agent and diluent after they are mixed with epoxy resin, polyurethane resin, polyurea resin and polyisocyanate resin at the conditions of low temperature and high humidity and producing amine blushing, amine blooming or treaded surface phenomenon. The present invention reduces the curing time and overcomes the aforementioned drawbacks of the resins effectively.
Abstract: Provided are a break-resistant copolymer having high transparency and heat resistance and also having a high tensile strain at break, and a molded article. A copolymer contains 80% by mass to 98% by mass of structural units derived from a methacrylic ester monomer and 2% to 10% by mass of ester structural units derived from a cyclic ketene acetal monomer. The copolymer has a weight average molecular weight of 80,000 or more and a molecular weight distribution of 1.75 to 3.80.
Abstract: A method of manufacturing a biopolymer optical device includes providing a polymer, providing a substrate, casting the polymer on the substrate, and enzymatically polymerizing an organic compound to generate a conducting polymer between the provided polymer and the substrate. The polymer may be a biopolymer such as silk and may be modified using organic compounds such as tyrosines to provide a molecular-level interface between the provided bulk biopolymer of the biopolymer optical device and a substrate or other conducting layer via a tyrosine-enzyme polymerization. The enzymatically polymerizing may include catalyzing the organic compound with peroxidase enzyme reactions. The result is a carbon-carbon conjugated backbone that provides polymeric “wires” for use in polymer and biopolymer optical devices. An all organic biopolymer electroactive material is thereby provided that provides optical functions and features.
Type:
Grant
Filed:
February 18, 2016
Date of Patent:
May 7, 2019
Assignee:
Tufts University
Inventors:
David L. Kaplan, Fiorenzo Omenetto, Brian Lawrence, Mark Cronin-Golomb
Abstract: A curable liquid composition, such as an alkyd paint or resin, contains a binder curable by oxidative crosslinking, a siccative compound for catalyzing oxidative crosslinking of the binder, and a matting agent. The matting agent is a precipitated silica, with a surface area, measured by BET, of 250 m2/g or less, a precipitated metal silicate such as Ca, Mg or Al silicate, or a mixture, and may be amorphous in nature. The siccative compound is a transition metal chelate complex comprising a ligand, such as an iron- or a manganese-based chelate complex. The compositions are capable of oxidative curing, within acceptable times, to form a cured solid, such as a coating, having a matt finish.
Abstract: Disclosed here is a method for sensing temperature-dependent electrical switching response, comprising: exposing a polymer-carbon composite to a temperature change, wherein the polymer-carbon composite comprises (a) a semi-conductive or conductive carbon network intercalated with (b) a polymer matrix, wherein the carbon network comprises at least one covalently bonded carbon material, and wherein the polymer matrix comprises at least one polymer having a net electron withdrawing character and adapted to apply a gating effect on the conductive carbon; and detecting a change in electrical conductivity of the polymer-carbon composite of at least three orders of magnitude. Also disclosed is a smart switching device comprising the polymer-carbon composite and a switch triggerable by an increase or decrease in electrical conductivity of the polymer-carbon composite of at least three orders or magnitude.
Type:
Grant
Filed:
March 9, 2016
Date of Patent:
April 30, 2019
Assignee:
Lawrence Livermore National Security, LLC
Abstract: SET-LRP polymerization of acrylic monomers under acidic conditions is described. The source of the acidity may be the solvent (e.g., an acetic acid-containing solvent) or in the monomer content (e.g., acrylic acid or methacrylic acid, optionally in combination with other monomers such as methyl methacrylate).
Type:
Grant
Filed:
July 22, 2011
Date of Patent:
April 30, 2019
Assignees:
ROHM AND HAAS COMPANY, THE TRUSTEES OF THE UNIVERSITY OF PENNSYLVANIA
Inventors:
Antony K. Van Dyk, Susan J. Fitzwater, Sven Fleischmann, Virgil Percec
Abstract: The present invention relates to a polymer comprising an N-vinyl amide monomer and a dual functional monomer. In the case where the dual functional monomer incorporates a glycidyl acrylate, a third polymerizable monomer is also included. The polymer can be varied in charge.
Abstract: A binder for capacitive deionization electrode is provided, which is formed by reacting a polyether polyol, a diisocyanate, and a diol having a hydrophobic side chain. The binder may bind an electrode material and to form a capacitive deionization electrode. The electrode material and the binder may have a weight ratio of 90:5 to 90:25.
Type:
Grant
Filed:
December 29, 2015
Date of Patent:
April 16, 2019
Assignee:
INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
Abstract: Provided is an organic pigment composition for color filters, which can be used preferably for a color filter that allows to produce a liquid crystal display device which has excellent heat resistance, a brighter display screen, and accordingly higher brightness; a method for producing the same; and a color filter which includes the organic pigment composition for color filters. The color filter has higher heat resistance by using the organic pigment composition for color filters which includes a phthalocyanine pigment and a pigment derivative in which the ratio of a multi-substituted phthalimide alkyl group to the whole amount of the pigment derivative is limited.
Abstract: The invention relates to a method for producing a solid nanocomposite material comprising nanoparticles of a metal coordination polymer with ligands CN, said nanoparticles satisfying the formula [Alk+x]Mn+[M?(CN)m]z? where Alk is an alkali metal, x is 1 or 2, M is a transition metal, n is 2 or 3, M? is a transition metal, m is 6 or 8, and z is 3 or 4; said Mn+ cations of the coordination polymer being bound by an organometallic bond or a coordination bond to an organic group R2 of an organic graft, and said organic graft furthermore being chemically attached, preferably by a covalent bond, to at least one surface of a solid support, by reaction of a group R1 of said graft with said surface.
Type:
Grant
Filed:
September 11, 2015
Date of Patent:
April 2, 2019
Assignee:
COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
Abstract: Disclosed is a non-linear optical crystal containing pyridinium represented by the following Formula (1), 4-substituted phenylsulfonate represented by the following Formula (2a), and 2,4,6-substituted phenylsulfonate represented by the following Formula (2b).
Abstract: This invention relates generally to the field of quasicrystalline structures. In preferred embodiments, the stopgap structure is more spherically symmetric than periodic structures facilitating the formation of stopgaps in nearly all directions because of higher rotational symmetries. More particularly, the invention relates to the use of quasicrystalline structures for optical, mechanical, electrical and magnetic purposes. In some embodiments, the invention relates to manipulating, controlling, modulating and directing waves including electromagnetic, sound, spin, and surface waves, for pre-selected range of wavelengths propagating in multiple directions.
Type:
Grant
Filed:
January 19, 2017
Date of Patent:
April 2, 2019
Assignee:
The Trustees of Princeton University
Inventors:
Paul Joseph Steinhardt, Paul Michael Chaikin, Weining Man
Abstract: The invention relates to a phthalocyanine compound, which has a structure as represented by Formula I, wherein A represents a transition metal or a rare earth metal; R1 represents a phenyl group, a naphthyl group, or a C4-C16 n-alkyl group. The aromatic phthalocyanine compound having the structure of Formula I provided in the invention contains a transition metal or a rare earth metal, and introduces a peripheral substituent into a linearly extended ?-conjugated system. It is relatively stabler at 400° C. or less and will be easily evaporated in vacuum to form a uniform thin film, and has good thermal stability, high chemical stability, and high mobility. The organic semiconductor device has the features of relatively fast on-off speed, relatively high on-off ratio, and strong reliability.
Abstract: An electrophoretic medium including a mixture of charge control agents, for example quaternary amine salts of polyisobutylene combined with quaternary amine salts of unsaturated monomers. The described electrophoretic medium exhibits improved color saturation as compared to similar electrophoretic media having only one of the charge control agents.
Type:
Grant
Filed:
August 6, 2018
Date of Patent:
March 19, 2019
Assignee:
E INK CALIFORNIA, LLC
Inventors:
Hui Du, Joshua A Ritchey, Olga Vladimirovna Barykina-Tassa, Vladimir Sofiyev
Abstract: Disclosed are methods for making a cured sealant. The methods include depositing an uncured sealant composition on a substrate and exposing the uncured sealant composition to actinic radiation to provide a cured sealant. The uncured sealant composition includes a thiol-terminated polythioether, a polyene comprising a polyvinyl ether and/or a polyallyl compound, and a hydroxy-functional vinyl ether. Related sealant compositions are also disclosed.
Type:
Grant
Filed:
May 1, 2018
Date of Patent:
March 19, 2019
Assignee:
PRC-DeSoto International, Inc.
Inventors:
Raquel Keledjian, Renhe Lin, Chandra Rao, Bruce Virnelson
Abstract: A method to transfer a layer of harder thin film substrate onto a softer, flexible substrate. In particular, the present invention provides a method to deposit a layer of sapphire thin film on to a softer and flexible substrate e.g. quartz, fused silica, silicon, glass, toughened glass, PET, polymers, plastics, paper and fabrics. This combination provides the hardness of sapphire thin film to softer flexible substrates.
Type:
Grant
Filed:
February 15, 2018
Date of Patent:
March 12, 2019
Assignee:
Hong Kong Baptist University
Inventors:
Kok Wai Cheah, Wing Yui Lam, Hoi Lam Tam
Abstract: Provided is a glass composition that exhibits greater Faraday effect than ever before. A glass composition contains 48% or more of Tb2O3 (exclusive of 48%) in % by mole.