Patents Examined by Boone Alexander Evans
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Patent number: 12204279Abstract: A toner based on fly-ash rich carbon and method of producing are disclosed. The process includes preparing a latex and preparing a pigment including fly ash, where the fly ash has been ground to nanoparticle size. The latex, pigment including fly ash, and polyethylene wax are combined in an emulsion aggregation process. The latex is formed by a mixing process including combining ammonium bicarbonate, sodium dodecylbenzene sulfonate, styrene, acrylic acid, and methyl methacrylate. The emulsion aggregation process includes steps of dispersing a mixture of the polyethylene wax, pigment including fly ash, and latex in water, adding zinc oxide, nitric acid, adding Ethylenediaminetetraacetic acid (EDTA), elevating the temperature, neutralizing the product mixture with NaOH solution and cooling the mixture, Centrifuging, washing and drying are performed to achieve a finished toner which includes fly ash pigment, polyethylene wax, poly(styrene-methyl methacrylate-acrylic acid) latex, zinc oxide and a chelating agent.Type: GrantFiled: February 8, 2024Date of Patent: January 21, 2025Assignee: KING SAUD UNIVERSITYInventors: Seham Soliman Alterary, Athar Mohamed Elhadi
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Patent number: 12204280Abstract: The present invention relates to a carrier including: a magnetic core material; and a resin coating layer coating a surface of the magnetic core material, in which the resin coating layer contains a binder resin, and fluorine element-containing resin particles dispersed in the binder resin, the resin coating layer has a coefficient of variation of a film thickness of 25% or less, and the resin coating layer has an average value of the number of the fluorine element-containing resin particles being 3 particles/?m2 or more and 350 particles/?m2 or less per unit area in a cross section of the resin coating layer, and has a coefficient of variation thereof being 20% or less.Type: GrantFiled: February 13, 2020Date of Patent: January 21, 2025Assignee: POWDERTECH CO., LTD.Inventors: Aya Sakuta, Makoto Ishikawa, Hiroki Sawamoto, Tetsuya Uemura
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Patent number: 12189334Abstract: An electrostatic charge image developing toner includes a toner particle that contains a binder resin having an acid value of 5 mgKOH/g or more and 25 mgKOH/g or less, and a pigment having an isoindoline skeleton, in which a total Net intensity NA of an alkali metal and an alkaline earth metal, which is measured by fluorescent X-ray analysis, in the toner particle is 1.50 kcps or more and 4.00 kcps or less.Type: GrantFiled: October 13, 2021Date of Patent: January 7, 2025Assignee: FUJIFILM Business Innovation Corp.Inventors: Satoshi Miura, Yoshimasa Fujihara, Atsushi Sugawara, Shintaro Anno, Daisuke Noguchi
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Patent number: 12181836Abstract: An electrostatic charge image developing carrier, contains: a magnetic particle; and a coating resin layer coating the magnetic particle and containing inorganic particles, in which an area ratio of the inorganic particles that is a ratio of a total area of the inorganic particles to an area of the coating resin layer in a cut surface of the coating resin layer along a thickness direction of the coating resin layer is 10% or more and 50% or less.Type: GrantFiled: July 27, 2021Date of Patent: December 31, 2024Assignee: FUJIFILM Business Innovation Corp.Inventors: Yasuo Kadokura, Yosuke Tsurumi, Takuro Watanabe, Kazutsuna Sasaki, Karin Sakai
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Patent number: 12174583Abstract: An electrostatic charge image developing carrier includes a magnetic particle and a coating resin layer that covers the magnetic particle and contains a silica particle, and a ratio of Si on a surface of the coating resin layer, determined by an X-ray photoelectron spectroscopy (XPS), is 6 atom % or more and 12 atom % or less.Type: GrantFiled: August 24, 2021Date of Patent: December 24, 2024Assignee: FUJIFILM Business Innovation Corp.Inventors: Takuro Watanabe, Kazutsuna Sasaki, Yosuke Tsurumi, Yasuo Kadokura, Karin Sakai
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Patent number: 12174584Abstract: An electrostatic charge image developing toner includes: toner base particles containing a binder resin and a metal pigment; and an external additive containing lanthanum-containing strontium titanate particles.Type: GrantFiled: December 20, 2021Date of Patent: December 24, 2024Assignee: KONICA MINOLTA, INC.Inventor: Keiji Arai
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Patent number: 12164265Abstract: A magnetic carrier including a magnetic core and a coating resin configured to coat the surface of the magnetic core. The coating resin contains a graft resin A and a graft resin B. The coating resin (i) contains 1.0 mass % or more and 50.0 mass % or less of the graft resin A, and (ii) contains 50.0 mass % or more and 99.0 mass % or less of the graft resin B. The graft resin A has a unit Y1 represented by formula (1) and a unit Y2 represented by formula (2). The graft resin B (i) is a comb-shaped polymer having, as a branch, at least one moiety selected from, for example, a styrene-based polymer moiety and a (meth)acrylate-based polymer moiety, and (ii) contains the polysiloxane structure moiety at a content of 0.1 mass % or less.Type: GrantFiled: January 26, 2022Date of Patent: December 10, 2024Assignee: Canon Kabushiki KaishaInventors: Yuto Onozaki, Ryuji Murayama, Nobuhiro Yoshida, Hironori Minagawa
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Patent number: 12158725Abstract: A toner comprises a toner particle comprising a core particle comprising a resin component, a shell coating the surface of the core particle, and a polyvalent metal. The resin component comprises a polyester resin, and the shell comprises an amino resin; in an electron image of a cross section of the toner acquired using a transmission electron microscope, a polyvalent metal content P(M) obtained by energy-dispersive x-ray analysis at the core/shell interface and in the vicinity of this interface is 0.0010 to 2.00 atomic %; and the surface storage elastic modulus of the toner at a load of 30 ?N at 25° C., according to nanoindentation measurement of the toner, is from 6.50 GPa to 12.00 GPa.Type: GrantFiled: November 1, 2021Date of Patent: December 3, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Mai Kato, Hirofumi Kyuushima, Naoya Isono, Kenichi Nakayama, Yoshiaki Shiotari
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Patent number: 12135507Abstract: Provided is an electrophotographic member that includes a surface with excellent abrasion resistance and allows toner to have an increased charge amount, thereby eliciting uniform and high transfer efficiency. This electrophotographic member is provided with a surface layer including at least one of an acrylic resin and methacrylic resin, the surface layer further including a positively chargeable charge control agent, wherein a surface of the surface layer is free from a convex portion having a height of more than 15 ?m resulting from the charge control agent.Type: GrantFiled: September 22, 2021Date of Patent: November 5, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Noriaki Egawa, Tomoaki Nakai
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Patent number: 12130586Abstract: A method for producing a resin fine particle includes dissolving or melting an oily mixture containing at least a polyester resin, a base, and a basic dye while applying a shearing force to the oily mixture, and emulsifying the dissolved or molten oily mixture by adding a surfactant and an aqueous medium while applying a shearing force to the dissolved or molten oily mixture to prepare a dispersion liquid of the resin fine particle. The resin fine particle includes the polyester resin and the basic dye, has a volume average particle diameter of 0.05 ?m or more and 1 ?m or less, and has a ratio of a concentration of the basic dye in a center of gravity portion of the resin fine particle to a concentration of the basic dye in a surface layer portion having a depth of 10 nm or less from a surface of the resin fine particle of 0.8 or more.Type: GrantFiled: July 27, 2022Date of Patent: October 29, 2024Assignee: FUJIFILM BUSINESS INNOVATION CORP.Inventors: Daisuke Tomita, Takahiro Yamashita, Yukiaki Nakamura, Takahisa Tatekawa, Masaru Takahashi
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Patent number: 12130587Abstract: The toner includes a toner particle that comprising a core particle containing a resin component and a shell on a surface of the core particle, wherein the resin component comprises more than 50.0 mass % of a polyester resin comprising a monomer unit that contains a heterocyclic group, and the shell comprises at least one resin selected from the group consisting of prescribed (meth)acrylic resins and melamine resins.Type: GrantFiled: March 18, 2021Date of Patent: October 29, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Naoya Isono, Kenichi Nakayama, Hirofumi Kyuushima, Mai Kato
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Patent number: 12124212Abstract: A toner comprising a toner particle that comprises a core particle comprising a binder resin and a surface layer comprising inorganic fine particles and an organosilicon polymer, wherein the organosilicon polymer has T3 structure represented by R—Si(O1/2)3, in 29Si-NMR measurement of THF insoluble-matter of the toner particle, a proportion of a peak area assigned to the T3 structure relative to a total peak area for the organosilicon polymer is at least 5.0%, and in observation of a cross section of the toner particle using TEM, the toner has a prescribed surface layer thickness, a prescribed number of inorganic fine particles in contact with the core particle in the surface layer, and a prescribed number of inorganic fine particles present in the core particle and not in contact with the surface layer.Type: GrantFiled: May 25, 2021Date of Patent: October 22, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Shintaro Kawaguchi, Masatake Tanaka, Tatsuya Saeki, Masamichi Sato
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Patent number: 12111612Abstract: An electrophotographic photosensitive member capable of maintaining a charging ability during repeated use is provided. An electrophotographic photosensitive member having a support, a conductive layer, a photosensitive layer and a protective layer in this order, wherein the protective layer contains a binding resin and a metal oxide particle, the metal oxide particle has a core and a coating layer, the core and the coating layer each contain titanium oxide, and the coating layer further includes niobium.Type: GrantFiled: June 27, 2023Date of Patent: October 8, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Kunihiko Sekido, Masashi Nishi
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Patent number: 12098288Abstract: The azomethine compound provided by this case is a compound showing high chroma and having excellent light resistance.Type: GrantFiled: December 28, 2020Date of Patent: September 24, 2024Assignee: Canon Kabushiki KaishaInventors: Taichi Shintou, Koromo Shirota, Ai Hayakawa, Tsuyoshi Santo
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Patent number: 12099326Abstract: A toner comprising a toner particle containing a binder resin containing at least 50 mass % of a polyester resin, wherein the polyester resin contains a polyester resin A having a silicone segment, and in XPS analysis, when X is a ratio of the number of silicon atoms attributable to silicone segments relative to a total number of measured atoms, X1 is a value of the X on the toner particle surface, X2 is a value of the X at a depth of 30 nm from the surface, Z is a ratio of the number of carbon atoms attributable to ester bonds relative to a total number of measured atoms, Z1 is a value of the Z on the toner particle surface and Z2 is a value of the Z at a depth of 30 nm from the toner particle surface, X1, Z1, X2 and Z2 satisfy a specific relationship.Type: GrantFiled: March 24, 2021Date of Patent: September 24, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Shin Kitamura, Nobuyoshi Sugahara, Daisuke Tsujimoto, Kazunari Ooyama, Yuu Nishimura, Kazuki Murata, Toru Takahashi, Ryo Nakajima, Hitoshi Sano, Koh Ishigami, Takaho Shibata
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Patent number: 12078960Abstract: A toner including toner particles having a resin component containing a crystalline resin and an amorphous resin, in which the resin component contains a tetrahydrofuran-insoluble component, and the content of the tetrahydrofuran-insoluble component with respect to the content of the resin component is 5.0% to 80.0% by mass, wherein a maximum endothermic peak temperature of the tetrahydrofuran-insoluble component is 55.0 to 80.0° C., and the amount of heat absorption in the maximum endothermic peak of the tetrahydrofuran-insoluble component is 10.0 to 80.0 J/g, and toner particles have a structure which comprises a matrix containing the crystalline resin and domains containing the amorphous resin.Type: GrantFiled: October 4, 2021Date of Patent: September 3, 2024Assignee: Canon Kabushiki KaishaInventors: Hiroki Kagawa, Shuhei Moribe, Shuntaro Watanabe, Hiroki Akiyama
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Patent number: 12078962Abstract: A toner comprising a toner particle comprising a core particle comprising a binder resin and a diester wax, and a shell on a surface of the core particle, wherein the following formulas (1) and (2) are satisfied, where Sp is a partition coefficient of the shell and Wp is a partition coefficient of the diester wax: Sp?0.40??(1), and 16.00?Wp?Sp?20.00??(2).Type: GrantFiled: July 16, 2021Date of Patent: September 3, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Tomohisa Sano, Kazuyuki Sato
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Patent number: 12032332Abstract: A magenta toner is provided. The magenta toner comprises toner particles each comprising a binder resin and a colorant. From 1.0% to 25.0% by number of the toner particles have a CH rate of 25.0% or more in absolute value. The CH rate is calculated from the following formula (1): CH rate(%)=[(In?Iave)/Iave]×100??Formula (1) where, in a Raman spectrum of each toner particle, In represents an integrated intensity within a wavenumber region of from 2,750 to 3,250 cm?1 when an intensity at a wavenumber ? within a wavenumber region of from 1,200 to 3,250 cm?1 is s normalized to 1, where a total intensity of all the toner particles is maximum at the wavenumber ?; and Iave represents an average of the In.Type: GrantFiled: February 12, 2021Date of Patent: July 9, 2024Assignee: Ricoh Company, Ltd.Inventors: Hiyori Fujino, Keisuke Tada, Shoki Matsuda, Fumihiko Chimoto, Takashi Okano, Ayumi Satoh
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Patent number: 12025950Abstract: A resin fine particle includes a polyester resin; and a basic dye, in which a volume average particle diameter of the resin fine particle is 0.05 ?m or more and 1 ?m or less, and a ratio of a concentration of the basic dye in a center of gravity portion of the resin fine particle to a concentration of the basic dye in a surface layer portion having a depth of 10 nm or less from a surface of the resin fine particle is 0.8 or more.Type: GrantFiled: August 5, 2020Date of Patent: July 2, 2024Assignee: FUJIFILM Business Innovation Corp.Inventors: Daisuke Tomita, Takahiro Yamashita, Yukiaki Nakamura, Takahisa Tatekawa, Masaru Takahashi
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Patent number: 12013661Abstract: A method for producing a carrier for electrostatic charge image development includes coating magnetic particles by adding the magnetic particles and a coating liquid containing a resin and a solvent to a mixer with a stirring blade to form a resin coating layer on surfaces of the magnetic particles and taking a carrier having the resin coating layer out of the mixer. In the coating, the stirring conditions after the solvent is evaporated and dried by heating in the mixer until the carrier is taken out of the mixer satisfy Formula 1 below and Formula 2 below: 0.2?peripheral speed ?Dn (m/s) of stirring blade?2.Type: GrantFiled: August 27, 2021Date of Patent: June 18, 2024Assignee: FUJIFILM Business Innovation Corp.Inventors: Takeshi Tanabe, Shintaro Anno