Abstract: A processing method for perennially and deeply polluted sludge containing oils and water, waste residues, or oil sands in natural oil mines, and a processing system thereof. In the method, a solid substance containing oils and water is in full contact with an organic liquid solvent with a low boiling point and a weak polarity or no polarity at room temperature under pressurized condition to extract oil and water from the solid substance to the liquid, the organic solvent with low boiling point and low latent heat is easily separated from oil and water in the liquid after solid-liquid separation by decompression or heating evaporation, the gas solvent is compressed and condensed for recycling, the extracted oil and water are subjected to oil-water separation, and the extracted oil may be used as fuel or used for refining.
Type:
Grant
Filed:
May 15, 2020
Date of Patent:
November 8, 2022
Assignee:
SOUTHEAST UNIVERSITY
Inventors:
Ying Huang, Dong Zhang, Rong Zha, Meng Ying
Abstract: The present disclosure relates to a process for the hydrodealkylation of aromatic rich hydrocarbon streams to produce benzene, toluene and mixed xylenes (BTX), with high selectivity towards high value xylenes. The process uses catalysts containing a framework-substituted zirconium and/or titanium and/or hafnium-modified ultra-stable Y (USY) type zeolite.
Type:
Grant
Filed:
December 9, 2020
Date of Patent:
November 1, 2022
Assignees:
Saudi Arabian Oil Company, JGC Catalysts and Chemicals Ltd., Japan Cooperation Center, Petroleum
Inventors:
Omer Refa Koseoglu, Robert Peter Hodgkins, Mitsunori Watabe, Koji Uchida
Abstract: A system of interlocks for controlling flow of low temperature process streams in a manufacturing process through a cold box to equipment or piping not specified for such temperatures by opening and closing valves and starting and stopping pumps. At least one interlock affects streams heated in the cold box. At least one interlock affects the streams cooled in the cold box. The interlocks are activated by temperatures of process lines to prevent exposure of equipment and piping to low temperatures while preventing the shutdown of the cold box. An override controller including a predictive failure capability is also provided.
Type:
Grant
Filed:
April 29, 2019
Date of Patent:
November 1, 2022
Assignee:
WPT LLC
Inventors:
Tiong-Ee Ting, Kenneth M. Istre, Newton Landreneau, W. Ryan Pitt, Gregory M. Guillory, Jr., Charles R. Demarest, Toby Darbonne, Troy L. Irwin
Abstract: The present invention utilizes mechanical vapor compression and/or thermal vapor compression integrating compression loops across multiple process stages. A sequential network of compressors is utilized to increase the pressure and condensing temperature of the vapors within each process stage, as intra-vapor flow, and branching between process stages, as inter-vapor flow. Because the vapors available are shared among and between compressor stages, the number of compressors can be reduced, improving economics. Balancing vapor mass flow through incremental compressor stages which traverse multiple process stages by splitting vapors between compressor stages enables the overall vapor-compression system to be tailored to individual process energy requirements and to accommodate dynamic fluctuations in process conditions.
Type:
Grant
Filed:
June 7, 2022
Date of Patent:
October 25, 2022
Assignee:
Energy Integration, Inc.
Inventors:
Lynn Allen Crawford, William Bryan Schafer, III
Abstract: A catalyst is provided having: (a) at least one multimetallic salt; and (b) at least one organic acid, wherein the at least one multimetallic salt to the at least one organic acid weight ratio is in the range of 1:0.01-1:0.5. A process is also provided for the preparation of the catalyst and for the preparation of the multimetallic salt.
Abstract: This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval.
Type:
Grant
Filed:
September 28, 2021
Date of Patent:
October 25, 2022
Assignee:
Chevron Phillips Chemical Company, LP
Inventors:
Ronald G. Abbott, Scott G. Morrison, Steven R. Horlacher, Jamie N. Sutherland, Bruce D. Murray
Abstract: A first stream of an aqueous solution flows through an upstream desalination or nanofiltration system. A second stream of the aqueous solution is mixed with the diluate output from the upstream desalination system or with the diluate or concentrate output from the upstream nanofiltration system with a flow ratio of the second stream of the aqueous solution to the feed stream of <0.47 or >0.63. A liquid composition flows into the concentrate channels of an electrically driven separation apparatus, while the feed stream flows into at least the diluate channels at a ratio of 0.3 to 0.81 to the flow of the liquid composition. An applied voltage selectively draws monovalent ions from the feed stream in the diluate channels through the monovalent-selective ion exchange membranes into the concentrate channels to produce a treated diluate having a sodium chloride ratio (SCR)<0.7.
Abstract: Method and plant for fluid purification by distillation comprising a reservoir (1) with a fluid containing diluted solids provided with an impurities filter on its outlet (2); a pump (3) connected to the reservoir outlet (1) and set up to increase the fluid containing solids pressure and temperature; and a heat area (4) for the fluid containing solids comprising a plurality of ducts contacting with a heat transfer fluid; and, furthermore, comprising a convergent-divergent nozzle (5) connected to the heat area outlet (4) and set to increase the biphasic liquid-vapor fluid speed so the diluted solids contained in the fluid already heated settle in a solids reservoir (6), whereas the fluid passes to a condenser (7) and then to a purified fluid reservoir (8) already in liquid state.
Abstract: This invention relates to an additive capable of increasing the gasoline octane (by 2-3 units) with minimum loss of gasoline. More specifically, the present invention discloses a fluid catalytic cracking additive composition capable of enhancing gasoline octane, said composition comprising 5-50 wt. % zeolite component, 0-15 wt % alumina, 5-20 wt % colloidal silica, 10-60 wt % kaolin clay, 5-15 wt % phosphate, and 0.1 to 5.0 wt. % of bivalent metal selected from Group-IIA or Group-IB, wherein the zeolite component comprises of medium pore pentasil zeolite in an amount of 1 to 50 wt. % and said zeolite consists of one or more MFI topology zeolite having SiO2/Al2O3 mole ratio in the range of 10-280. The present invention also discloses a process for preparation of the additive.
Abstract: The present invention relates to a catalyst including: a porous carrier including at least one element X selected from the group consisting of elements belonging to Groups 13 and 14 of the periodic table; an oxide of at least one metal element A selected from the group consisting of elements belonging to Groups 3 to 6 of the periodic table; and at least one oxide of a metal element B selected from the group consisting of elements belonging to Group 2 and Groups 7 to 12 of the periodic table, wherein at least a part of the oxide of the metal element A is bonded to the porous carrier.
Abstract: Process for the preparation of a catalyst and a catalyst comprising more than one silica is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 10 to about 45 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized colloidal silica, greater than about 0 to about 30 wt % silica from ammonia stabilized or lower sodium colloidal silica, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with good performance.
Type:
Grant
Filed:
January 11, 2019
Date of Patent:
October 4, 2022
Assignee:
Albemarle Corporation
Inventors:
Amir Sabahi, Andrew Loebl, Sandra Gavalda, Julie Francis, Eswaramoorthi Iyyamperumal, Min Li, Andrea Marcinkova
Abstract: This invention disclosure reported here a supported metal hydroxide adsorbent and a method for its preparation as well as a method for its oxidative regeneration. The supported metal hydroxide adsorbent comprises metal hydroxide and support with a mass ratio of 5-30:100. The adsorbent disclosed in present invention exhibited outstanding adsorption capacity and high selectivity to sulfur impurity in gasoline. The method of oxidative regeneration provides an efficient way for the recovery of the saturated adsorbent.
Type:
Grant
Filed:
July 6, 2020
Date of Patent:
October 4, 2022
Assignees:
SOUTH CHINA UNIVERSITY OF TECHNOLOGY, DEEP PURE TECHNOLOGIES (SHENZHEN), LTD.
Inventors:
Jing Xiao, Cuiting Yang, Lei Dong, Neng Liao, Guang Miao, Zhong Li
Abstract: An integrated process that is operated to create both a higher value pipelineable crude and a higher value carbon fiber product from a lower value common heavy hydrocarbon feedstock where the feedstock is processed in a thermal reactor followed by a solvent deasphalting unit with the liquids being gathered and processed to reduce olefins for pipeline transport and the solids are processed to generate a marketable carbon fiber product with any gases generated throughout the entire process reused in the process or sold.
Type:
Grant
Filed:
January 6, 2021
Date of Patent:
September 27, 2022
Inventors:
Tom Corscadden, Darius Remesat, David Denton
Abstract: A reactor for steam-methane reforming is adapted to be received in a tube on a focal axis of a parabolic trough. The reactor may comprise an array of micro-reactors interconnected by a water manifold, a gas manifold, a syngas manifold, and at least one steam-methane reforming chamber configured for reforming steam and methane into syngases, the micro-reactors having a vaporization portion for producing steam. Radiation plates may extend on sides of the array of micro-reactors Glazing may face and be spaced apart from a portion of the array of micro-reactors including at least one steam-methane reforming chamber, the glazing being conductively connected to the radiation plates for heat transfer therebetween, the at least one glazing allowing light from the parabolic trough to pass therethrough to reach the array of micro-reactors.
Type:
Grant
Filed:
November 16, 2018
Date of Patent:
September 27, 2022
Assignee:
SOCIETE DE COMMERCIALISATION DES PRODUITS DE LA RECHERCHE APPLIQUÉE SOCPRA SCIENCES ET GÉNIE S.E.C.
Abstract: A solar vapor generator system and method are provided. In some embodiments, the system has near perfect energy conversion efficiency in the process of solar vapor generation below room temperature. Remarkably, when the operation temperature of the system is below that of the surroundings, the total vapor generation will be higher than the upper limit that can be produced by the input solar energy.
Type:
Grant
Filed:
November 30, 2017
Date of Patent:
September 20, 2022
Assignee:
The Research Foundation for The State University of New York
Inventors:
Qiaoqiang Gan, Zongfu Yu, Zhejun Liu, Haomin Song, Matthew Singer, Chenyu Li
Abstract: A fluid catalytic cracking catalyst composition (FCC catalyst composition) includes a framework-substituted ultra-stable Y-type zeolite (USY zeolite) having one or more transition metals substituted into the framework of a USY zeolite and a FCC zeolite cracking additive. A method for upgrading a hydrocarbon feed includes contacting the hydrocarbon feed with the FCC catalyst composition of the present disclosure at reaction conditions sufficient to upgrade at least a portion of the hydrocarbon feed. A method for upgrading a hydrocarbon feed includes passing the hydrocarbon feed to a fluid catalytic cracking unit, contacting the hydrocarbon feed with a FCC catalyst composition in the fluid catalytic cracking unit under reaction conditions sufficient to cause at least a portion of the hydrocarbon feed to undergo cracking reactions to produce a cracking reaction mixture comprising a used FCC catalyst composition and a cracked effluent comprising one or more olefins.
Type:
Grant
Filed:
July 2, 2020
Date of Patent:
September 20, 2022
Assignees:
Saudi Arabian Oil Company, JGC Catalysts and Chemicals Ltd., Japan Cooperation Center Petroleum
Abstract: Disclosed is a hydrofining catalyst comprising: an inorganic refractory component comprising a first hydrodesulfurization catalytically active component in a mixture with at least one oxide selected from the group consisting of alumina, silica, magnesia, calcium oxide, zirconia and titania; a second hydrodesulfurization catalytically active component; and an organic component comprising a carboxylic acid and optionally an alcohol. The hydrofining catalyst of the present application shows improved performance in the hydrofining of distillate oils. Also disclosed are a hydrofining catalyst system comprising the hydrofining catalyst, a method for preparing the catalyst and catalyst system, and a process for the hydrofining of distillate oils using the catalyst or catalyst system.
Type:
Grant
Filed:
April 9, 2019
Date of Patent:
September 13, 2022
Assignees:
CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
Inventors:
Wenbin Chen, Le Zhang, Xiangyun Long, Hong Nie, Mingfeng Li, Dadong Li, Qinghe Liu, Xueyan Ju
Abstract: The present invention discloses a process for nitration of benzene. More particularly, the present invention discloses an efficient, environmental friendly process for the nitration of benzene using a modified solid acid catalyst.