Abstract: A method for preparing a hydrocracking catalyst comprising: (i) providing a shaped body comprising a zeolite and a binder, wherein the shaped body has been obtained by shaping, calcination and cooling, wherein the zeolite is ZSM-5 having a silica (SiO2) to alumina (Al2O3) molar ratio of 25-75; (ii) optionally drying the shaped body at a temperature of 100-300° C. for a period of at least 1 hour; (iii) depositing a hydrogenation metal on the shaped body by an impregnation for a period of at most 2 hours such that the amount of the hydrogenation metal is 0.010-0.30 wt % with respect to the total catalyst; (iv) optionally rinsing the metal deposited shaped body with water; and (v) heat-treating the metal deposited shaped body in air at a temperature of 250-300° C. for a period of 1-5 hours; wherein the catalyst comprises a total of less than 0.05 wt % sodium and cesium.
Type:
Grant
Filed:
October 17, 2017
Date of Patent:
August 17, 2021
Assignee:
SABIC GLOBAL TECHNOLOGIES B.V.
Inventors:
Ashim Kumar Ghosh, Alla Khanmamedova, Scott A. Stevenson
Abstract: The present invention relates to a process for the preparation of a C20 to C60 wax from the thermal decomposition of a particular plastic polyolefin polymer blend. The present invention provides a vacuum pyrolysis process for preparing a C20 to C60 wax from the thermal decomposition of plastic polyolefin polymer, the method comprising the steps of: i) introducing plastic polyolefin polymer into a thermal reaction zone of a vacuum pyrolysis reactor; ii) heating the plastic polyolefin polymer at sub-atmospheric pressure, wherein the temperature in the thermal reaction zone of the reactor is from 500° C. to 750° C.
Abstract: The invention relates to a method for hydroprocessing a hydrocarbon feed, operated at a temperature of between 180° C. and 450° C., in the presence of a catalyst comprising i) a composite material comprising a compound based on at least one crystalline aluminium solid and carbon, the deposited carbon content being between 1 and 25 wt.
Type:
Grant
Filed:
November 26, 2018
Date of Patent:
August 17, 2021
Assignee:
IFP Energies Nouvelles
Inventors:
Amandine Cabiac, Alexandra Chaumonnot, Etienne Girel, Audrey Bonduelle-Skrzypczak
Abstract: A process for the production of middle distillates by the catalytically promoted hydration of olefinic compounds having a carbon number ranging from 7 to 14 to convert the olefins to the corresponding mixed alcohols having a higher boiling point that is in the diesel range, the process being conducted in a continuous stirred tank reactor, e.g., an ebullated-bed reactor, utilizing catalysts that include soluble homogeneous acidic compounds and solid heterogeneous compounds such as resins, and amorphous or structured metal oxides containing elements selected from IUPAC Groups 4-10, 13 and 14, and having Lewis or Bronsted acid sites.
Abstract: The invention relates to a molecular sieve modification method and a catalytic cracking catalyst containing a molecular sieve. The method comprises: mixing a solution containing an ion of a Group MB metal in the periodic table, an organic complexing agent, and/or a dispersant and a precipitation agent, and stirring the same to form a suspension containing a precipitant of a Group IIIB element; and mixing the resulting precipitant and a molecular sieve slurry, stirring the same to obtain a mixed slurry containing the precipitant of the Group MB element and a molecular sieve, and performing spray drying and optional calcination, to obtain a modified molecular sieve. The catalyst comprises, as calculated based on the catalyst mass being 100%, 10-55% of a modified molecular sieve (on a dry basis), 10-80% of clay (on a dry basis), 0-40% of an inorganic oxide (on an oxide basis), and 5-40% of a binding agent (on an oxide basis). The catalyst has good activity stability and heavy metal contamination resistance.
Abstract: Disclosed is a process and system for upgrading low-quality oils. The upgrading process comprises: (1) subjecting a low-quality oil to a conversion reaction in the presence of hydrogen and optionally in the presence of a conversion catalyst to obtain a conversion product, (2) processing the conversion product to obtain a first processed product, wherein the first processed product comprises a specific amount of a special component, and (3) subjecting the first processed product to extraction separation to obtain an upgraded oil and a pitch. The upgrading process and the upgrading system have the advantages of stable operation, high upgrading efficiency, environmental friendliness, low coke yield or high yield of upgraded oil.
Type:
Grant
Filed:
September 11, 2017
Date of Patent:
August 3, 2021
Assignees:
CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
Inventors:
Jun Long, Huandi Hou, Zijun Wang, Haiping Shen, Ming Dong, Lishun Dai, Jianhong Gong, Jiguang Li, Shuhong Zhang, Cuihong Wang, Yucheng She, Yuzhang Wang, Mengying Tao
Abstract: The present disclosure relates to a process for the deolefinization of hydrocarbon streams through an aromatic alkylation reaction by olefins, using a catalyst containing a framework-substituted zirconium and/or titanium and/or hafnium-modified ultra-stable Y (USY) type zeolite.
Type:
Grant
Filed:
December 16, 2019
Date of Patent:
August 3, 2021
Assignees:
Saudi Arabian Oil Company, JGC CATALYSTS AND CHEMICALS LTD., JAPAN COOPERATION CENTER, PETROLEUM
Inventors:
Omer Refa Koseoglu, Robert Peter Hodgkins, Mitsunori Watabe, Tomoyasu Kagawa, Koji Uchida
Abstract: A process and apparatus for removing moisture from sludge. The process and apparatus comprise: conveying on a conveyor the sludge on an incline through a housing such that, as the sludge is conveyed, it is deposited onto an exposed portion of the housing; heating the sludge with a heater as it is conveyed on the incline to evaporate moisture in the sludge, whereby the sludge that it is deposited onto the exposed portion of the housing is also heated to thereby evaporate moisture from the sludge; extracting from the housing using a vacuum device an airflow comprising the evaporated moisture, whereby the airflow includes moisture that has been evaporated as a result of the sludge being deposited onto the exposed heated portion of the housing; and discharging from the housing, separately to the extracting of the airflow from the housing, the sludge from which the moisture has been removed.
Abstract: The invention relates to a porous monolith comprising between 20 wt.-% and 70 wt.-% TiO 2 relative to the total weight of the monolith, and between 30 wt.-% and 80 wt.-% a refractory oxide, selected from silica, alumina or silica-alumina, relative to the total weight of the monolith, characterized in that said porous monolith has a bulk density of less than 0.19 g/mL.
Type:
Grant
Filed:
April 23, 2018
Date of Patent:
August 3, 2021
Assignee:
IFP Energies Nouvelles
Inventors:
Sophie Bernadet, Antoine Fecant, Denis Uzio, Renal-Vasco Backov, Serge Ravaine
Abstract: Improved catalytic reforming processes and systems employ reforming reactors in a more efficient manner and can avoid problems associated with yield loss. Aromatics and isoparaffins are separated prior to passing to a reforming unit. An integrated process for producing gasoline blending components includes: separating a naphtha feedstream into an aromatic-rich stream and an aromatic-lean stream; separating the aromatic-lean stream into an isoparaffin-rich stream and an isoparaffin-lean stream; and catalytically reforming the isoparaffin-lean stream to produce a reformate stream.
Abstract: A multilayer thin film evaporator for steam heating includes a housing. A three-layer evaporation cylindrical core arranged in a nested manner with one layer placed inside the other is configured inside the housing. A limiting plate is configured to fix the three-layer evaporation cylindrical core. A feeding tube, a heating medium inlet tube, and a heating medium outlet tube are sequentially fixed under the limiting plate in a crosswise manner. A rotary rack spindle passing through a center of the three-layer evaporation cylindrical core, a rotary rack fixed on the rotary rack spindle and capable of rotating with the rotary rack spindle, and a motor component connected to a top end of the rotary rack spindle and capable of driving the rotary rack spindle to rotate are further provided.
Type:
Grant
Filed:
March 6, 2017
Date of Patent:
July 27, 2021
Assignee:
NANJING TECH UNIVERSITY
Inventors:
Xiang Ling, Xin Huang, Yang Li, Minjie Gao
Abstract: The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least at least one feldspar or feldspathoid with a melting point higher than 1500° C., such as celsian, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from a precursor of the ceramic matrix, obtained from a macroporous zeolitic material with zeolite crystals of a specific size, and a precursor of the oxidation-reduction active mass.
Type:
Grant
Filed:
December 21, 2017
Date of Patent:
July 27, 2021
Assignees:
IFP ENERGIES NOUVELLES, TOTAL RAFFINAGE CHIMIE
Inventors:
Arnold Lambert, Catherine Laroche, Delphine Marti, Elodie Comte
Abstract: A novel process/system for flexibly producing chemicals and fuels from a petroleum feed such as crude comprise a flashing drum, a first cracker (e.g., a fluidized bed pyrolysis cracker or an oxidative cracker), and an olefin-to-gasoline reaction zone. The process/system can also include a steam cracker and a hydrotreater. The process/system can convert crude oil into hydrogen, C2-C4 olefins, gas oil and distillates with various amounts by adjusting the cut point of the bottoms effluent exiting the flashing drum.
Type:
Grant
Filed:
March 11, 2020
Date of Patent:
July 27, 2021
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Mohsen N. Harandi, Paul F. Keusenkothen
Abstract: A low energy desalination system with a venturi device includes a saline water feed, a pump, and a venturi device. The pump provides saline water to the nozzle of the venturi device. The fluid flowing through the nozzle speeds up at the throat or constricted region of the device. This results in a reduction in pressure at the throat of the device. The reduced pressure at the throat of the device makes the fluid susceptible to evaporation which causes a certain amount of water to evaporate from the saline water. Freshwater vapor from the fluid flows through a freshwater vapor outlet at the throat of the venturi device to a freshwater tank and the concentrated brine remaining in the venturi device flows toward the diffuser of the venturi device and then to a brine tank.
Type:
Grant
Filed:
January 17, 2021
Date of Patent:
June 29, 2021
Assignee:
UNITED ARAB EMIRATES UNIVERSITY
Inventors:
Mohsen Sherif, Fadi Alnaimat, Bobby Mathew
Abstract: A method for improving peroxidase-like activity of nanozyme and a product thereof are disclosed, which relate to the field of artificial enzymes in biochemistry. The method adopts a hydrogen peroxide solution with high concentration to treat the VO2(B) powder for obtaining a product with high peroxidase-like activity. Compared with the pure VO2(B) powder, the peroxidase-like activity of the product obtained by the method is increased by 4 to 12 times. The method provided by the present invention adopts raw materials with low cost and mild reaction conditions, is simple in operation and low in cost, which is conducive to batch preparation. The powder product obtained by the method is able to be applied to detect hydrogen peroxide, glucose, etc., and has great application prospects in biosensing, industrial wastewater treatment and sewage treatment.
Type:
Grant
Filed:
November 5, 2019
Date of Patent:
June 15, 2021
Assignee:
UNIVERSITY of Electronic Science and Technology of China
Inventors:
Deen Gu, Yonghai Ma, Yadong Jiang, Licheng Lin
Abstract: Disclosed herein are compositions and methods of mitigating scale in phosphoric acid and ammonium phosphate plants. Scale-mitigating compositions of the invention can be added to phosphoric acid before or during the concentration in the evaporator cycle of a phosphoric acid plant. The compositions retard the formation of scale on surfaces in contact with the phosphoric acid, and thus time between cleaning is extended and plant productivity increased. Further, the scale that forms is softer and more easily cleaned from surfaces, reducing non-operation time of the plant and/or evaporator. Methods of mitigating scale formation in phosphoric acid production and phosphoric acid handling plants are disclosed. In the methods, scales accumulate more slowly and are softer, more tractable, and more easily cleaned from surfaces to which they adhere.
Type:
Grant
Filed:
February 14, 2020
Date of Patent:
June 8, 2021
Assignee:
Ecolab USA Inc.
Inventors:
Sankar Bhattacharja, Jasbir Gill, Yuhuan Jin, Paul Wiatr
Abstract: The invention relates to a catalyst comprising an alumina-, silica- or silica-alumina-based support, at least one group VIII element, at least one group VIB element, and a furan compound. The invention also relates to the method for producing said catalyst and to the use thereof in a hydrotreating and/or hydrocracking method.
Abstract: Provided herein are supercritical upgrading reactors and reactor systems for upgrading a petroleum-based composition by using one or more supercritical upgrading reactors and one or more supercritical standby reactors that alternate functions such that the supercritical upgrading reactor is converted to a supercritical standby reactor and the supercritical standby reactor is converted to a supercritical upgrading reactor. The supercritical upgrading reactor upgrades a combined feed stream while a supercritical standby reactor delivers a cleaning fluid into the supercritical standby reactor. The supercritical reactors may have one or more catalyst layers and one or more purging fluid inlets, and the catalyst layers may have differing void volume ratios.
Type:
Grant
Filed:
December 9, 2019
Date of Patent:
June 1, 2021
Assignee:
Saudi Arabian Oil Company
Inventors:
Ki-Hyouk Choi, Abdullah T. Alabdulhadi, Mohammad A. Al-Abdullah
Abstract: The present invention discloses a catalytic phase change dielectric sphere for methanol combustion and a preparation method therefor. The catalytic phase change dielectric sphere for methanol combustion is mainly prepared from a high-temperature phase change material, an active material, a carrier material, a catalyst, a nano-semiconductor material, a nano-transition metal and an adhesive. A catalytic phase change dielectric solid sphere is prepared with a mixed pressing and sintering process, the methanol energy conversion rate reaches 87.5%, the furnace temperature of methanol combustion reaches 900° C. or higher, and waste heat recovery is realized; or, a catalytic phase change dielectric microporous hollow sphere is prepared through electrostatic adsorption and in-site redox reaction, the methanol energy conversion rate reaches 99% or higher, the furnace temperature of methanol combustion reaches 1000° C. or higher, and waste heat recovery is realized.
Abstract: Method and apparatus to facilitate recycling of at least one fraction of bitumen-containing materials. This can be accomplished by dissolving the at least one fraction, for example, maltenes or asphaltenes in roofing shingles, into at least one solvent. In one aspect, the apparatus comprises a dissolution vessel, a tumbler positioned therein, and at least one solvent distributor. The tumbler is configured to facilitate wetting the bitumen-containing materials with solvent. In a second aspect, a system comprises the apparatus, a solid-liquid separator, for example, a vibratory screen, and at least one solvent-fraction separator, for example, a flash drum. The at least one solvent can comprise one or more solvents useful to extract the at least one fraction. In a third aspect, a first fraction is extracted from the bitumen-containing materials with a first solvent composition, then a second fraction is extracted from the remaining bitumen-containing materials with a second solvent composition.
Type:
Grant
Filed:
April 27, 2018
Date of Patent:
May 25, 2021
Assignee:
SHINGLE RESOURCE RECYCLING, LLC
Inventors:
Robert William Palmer, Stephen Woodson Craig, David Woodson Craig, Randell Gween Shelton, Jr.