Abstract: Rubber-modified thermoplastic resins are characterized by having a high content of olefinically unsaturated nitriles and good transparency. These thermoplastic resins generally comprise from about 43 to about 75 parts by weight of a monovinyl aromatic monomer, from about 20 to about 40 parts by weight of an olefinically unsaturated nitrile monomer and from about five to about 35 parts by weight of an unsaturated dicarboxylic acid anhydride monomer, providing 100 parts of a thermoplastic terpolymer, and from about two to about 30 parts by weight of rubber polymer per 100 parts of the thermoplastic terpolymer. Other resins characterized by having between about 30 to 45 parts by weight of unsaturated dicarboxylic acid anhydride exhibit good heat distortion temperatures.
Type:
Grant
Filed:
August 5, 1985
Date of Patent:
September 8, 1987
Assignee:
The Standard Oil Company
Inventors:
Christopher L. Bodolus, David A. Woodhead
Abstract: A process for the impact modification of a plastic with a rubber polymer to form a thermoplastic resin in a reactor extruder is provided. The process includes the steps of dissolving a rubber polymer in a solvent selected from the group consisting of ethylenically unsaturated monomers and non-polymerizable organic compounds to form a feed solution, introducing the feed solution into the feed section of a twin screw reactor extruder, introducing a separate feed stream containing a material in sufficient amount to precipitate the rubber polymer, heating the feed solution and feed stream under pressure to a temperature sufficient for polymerization to begin, polymerizing the monomers with the rubber polymer in the reactor extruder to form a thermoplastic resin and extruding the thermoplastic resin through a die. A novel ABS thermoplastic resin is also provided having a uniform distribution of rubber particles dispersed within the plastic phase of the resin, the rubber particles ranging in size of from about 0.
Type:
Grant
Filed:
June 4, 1982
Date of Patent:
July 31, 1984
Assignee:
The Standard Oil Company
Inventors:
Christopher L. Bodolus, William J. Miloscia