Abstract: A biosensor containing ruthenium, measurement using the same, and the application thereof. The biosensor comprises an extended gate field effect transistor (EGFET) structure, including a metal oxide semiconductor field effect transistor (MOSFET), a sensing unit comprising a substrate, a layer comprising ruthenium on the substrate, and a metal wire connecting the MOSFET and the sensing unit.
Type:
Grant
Filed:
June 9, 2006
Date of Patent:
July 13, 2010
Assignee:
National Yunlin University of Science and Technology
Abstract: A method of protecting steel in concrete is disclosed. It consists of connecting the steel (6) to a discrete sacrificial anode assembly (7) comprising a base metal (1), a relatively small quantity of catalytic activating agent in contact with the base metal and a substantially inert porous layer (3) that surrounds the base metal and catalytic activating agent. The inert porous layer efficiently maintains a sustainable concentration gradient of the catalytic activating agent between the base metal and the surrounding environment as a result of the electric field across this layer. The preferred porous layer comprises a material that exhibits a net repulsion of negative ions from its pore system and the preferred catalytic activating agent comprises doubly charged sulphate ions as small electric fields maintain very high concentration gradients of these ions resulting in high concentrations at the base metal surface and insignificant concentrations at the assembly periphery.
Abstract: A cell for the electrowinning of aluminium by the electrolysis from an aluminium compound dissolved in a molten electrolyte (50), comprises: (I) a plurality of non-carbon anodes (10), each anode being suspended in operating in the molten electrolyte by an anode stem (11) that connects the anode (10) to a positive current source; and (II) a thermic insulating cover (60,60?) which covers the electrolyte (50) and through which each anode stem (11) extends from the positive current source to an anode (10). The insulating cover (60,60?) comprises a plurality of movable sections (60) that together cover a substantial part of the electrolyte (50). Each movable section (60) covers a corresponding portion of the electrolyte (50) that is located therebelow and that can be uncovered by moving the corresponding movable section (60).
Abstract: A high current density cathode for electrorefining in a molten electrolyte for the continuous production and collection of loose dendritic or powdery deposits. The high current density cathode eliminates the requirement for mechanical scraping and electrochemical stripping of the deposits from the cathode in an anode/cathode module. The high current density cathode comprises a perforated electrical insulated material coating such that the current density is up to 3 A/cm2.
Abstract: In a procedure to recognize the gas composition of a gas mixture, which consists of at least two gases of preferably different diffusion properties, delivered to a wideband lambda sensor, especially a gas mixture of an exhaust gas of an internal combustion engine of a motor vehicle, whereby the lambda sensor has a pumping cell with at least one gas measurement chamber, provision is made for the recognition of the gas composition of the gas mixture to result by means of modulation of the gas in the gas measurement chamber. Preferably the air number in the gas measurement chamber of the pumping cell is periodically altered, whereby the sensitivity of the lambda sensor to the gases, of which there are at least two, likewise periodically changes.
Abstract: A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.
Type:
Grant
Filed:
March 5, 2007
Date of Patent:
June 29, 2010
Assignee:
Proton Energy Systems, Inc.
Inventors:
Amjad Khan, Ken Wayne Dreier, Lawrence Clinton Moulthrop, Erik James White
Abstract: A cell for electrowinning aluminium from alumina, comprises: a metal-based anode having an electrochemically active outer part comprising a layer that contains predominantly cobalt oxide CoO; and a fluoride-containing molten electrolyte in which the active anode surface is immersed. The electrolyte is at a temperature below 950° C., in particular in the range from 910° to 940° C. The electrolyte consists of: 6.5 to 11 weight. % dissolved alumina; 35 to 44 weight % aluminium fluoride; 38 to 46 weight % sodium fluoride; 2 to 15 weight % potassium fluoride; 0 to 5 weight % calcium fluoride; and 0 to 5 weight % in total of one or more further constituents.
Abstract: The present invention relates, generally, to a method for electrowinning copper powder, and more particularly to a method for electrowinning copper powder from a copper-containing solution using the ferrous/ferric anode reaction. In accordance with various embodiments of the present invention, a process for producing copper powder by electrowinning employs alternative anode reaction technology, namely, the ferrous/ferric anode reaction, and enables the efficient and cost-effective production of copper powder at a total cell voltage of less than about 1.5 V and at current densities of greater than 50 A/ft2. A copper powder electrowinning process in accordance with the present invention also reduces or eliminates acid mist generation that is characteristic of electrowinning operations utilizing conventional electrowinning chemistry (e.g., oxygen evolution at the anode), which is advantageous.
Type:
Grant
Filed:
December 11, 2008
Date of Patent:
June 15, 2010
Assignee:
Freeport-McMoran Corporation
Inventors:
Scot P Sandoval, Antonioni C Stevens, Timothy G Robinson, John O Marsden, Stanley R Gilbert
Abstract: This invention relates to a system and method for producing a metal powder product using either conventional electrowinning or alternative anode reaction chemistries in a flow-through electrowinning cell. The present invention enables the production of high quality metal powders, including copper powder, from metal-containing solutions using conventional electrowinning processes, direct electrowinning, or alternative anode reaction chemistries.
Type:
Grant
Filed:
November 4, 2008
Date of Patent:
June 15, 2010
Assignee:
Freeport-McMoran Corporation
Inventors:
Stanley R Gilbert, Scot P Sandoval, Antonioni C Stevens, Timothy G Robinson, John O Marsden
Abstract: The present invention relates generally to a process for recovering copper and/or other metal values from a metal-bearing ore, concentrate, or other metal-bearing material using pressure leaching and direct electrowinning. More particularly, the present invention relates to a substantially acid-autogenous process for recovering copper from chalcopyrite-containing ore using pressure leaching and direct electrowinning in combination with a leaching, solvent/solution extraction and electrowinning operation.
Type:
Grant
Filed:
December 29, 2008
Date of Patent:
June 15, 2010
Assignee:
Freeport-McMoran Corporation
Inventors:
John O Marsden, Robert E Brewer, Susan R Brewer, Joanna M Robertson, David R Baughman, Philip Thompson, Wayne W Hazen, Christel M. A. Bemelmans
Abstract: This invention relates to a system and method for producing a metal powder product using conventional electrowinning chemistry (i.e., oxygen evolution at an anode) in a flow-through electrowinning cell. The present invention enables the production of high quality metal powders, including copper powder, from metal-containing solutions using conventional electrowinning processes and/or direct electrowinning.
Type:
Grant
Filed:
May 23, 2008
Date of Patent:
June 15, 2010
Assignee:
Freeport-McMoran Corporation
Inventors:
Antonioni C Stevens, Stanley R Gilbert, Scot P Sandoval, Timothy G Robinson, John O Marsden
Abstract: The invention pertains to a sacrificial anode for cathodic corrosion protection that comprises an anode body (1), a mounting component (8) for mounting the sacrificial anode on the device to be protected, an insulating component (4) that in certain areas surrounds the anode body (1) and electrically insulates the anode body (1) from the mounting component (8), and a resistive element (9) that is inserted between the anode body (1) and the mounting component (8), where the insulating component (4) is fixed on the mounting component (8). According to the disclosure, a securing component (6) is fixed on the anode body (1) and prevents the anode body (1) from moving out of the insulating component (4). This results in a sacrificial anode of this type that can be reliably operated over its entire service life.
Abstract: A method and apparatus for fluid sealing a workpiece retained by a workpiece holder are described. A pressure differential can be formed across a fluid seal to counteract fluid attempting to penetrate the fluid seal, which can contaminate the underside of the workpiece. The apparatus can include a ring forming a barrier to fluid entry with the workpiece and a source providing pressure to form the pressure differential. The pressure or the pressure differential can counteract hydroscopic fluid pressure or hydrostatic fluid pressure that is acting to force fluid through the barrier between the ring and the workpiece.
Type:
Grant
Filed:
November 2, 2005
Date of Patent:
June 1, 2010
Assignee:
NEXX Systems, Inc.
Inventors:
Arthur Keigler, Qunwei Wu, Zhenqiu Liu, John Harrell
Abstract: A suction pad used for use in a substrate treatment apparatus which treats a substrate by immersing the substrate in a solution while the pad attaches to the substrate, including: a main face for attaching to the substrate; an outer face disposed along the outer periphery of the substrate; and a suction opening formed in the main face. In a cross-sectional shape including the main face and the outer face, the angle formed between a line corresponding to the main face and a line corresponding to the outer face is an acute angle.
Abstract: A lead free, galvanic sensor. The sensor having a housing, a cathode, an anode, a diffusion barrier, contact wires and an electrolyte, the anode being made of a tin containing alloy. The sensor electrolyte is an aqueous solution of phosphoric acid or an aqueous solution of a cesium salt.
Abstract: A system and process for recovering copper from a copper-containing ore, concentrate, or other copper-bearing material to produce high quality cathode copper from a leach solution without the use of copper solvent/solution extraction techniques or apparatus. A process for recovering copper from a copper-containing ore generally includes the steps of providing a feed stream containing comminuted copper-containing ore, concentrate, or other copper-bearing material, leaching the feed stream to yield a copper-containing solution, conditioning the copper-containing solution through one or more physical or chemical conditioning steps, and electrowinning copper directly from the copper-containing solution in multiple electrowinning stages, without subjecting the copper-containing solution to solvent/solution extraction prior to electrowinning.
Type:
Grant
Filed:
November 19, 2008
Date of Patent:
May 25, 2010
Assignee:
Freeport-McMoran Corporation
Inventors:
John O Marsden, Joanna M Robertson, Robert E Brewer, Susan R. Brewer, legal representative, David R Baughman, Philip Thompson, Wayne W Hazen, Christel M. A. Bemelmans
Abstract: A method and apparatus for retaining a workpiece against a workpiece holder are described. A flexible member can be used to provide a substantially uniform force to securely retain the workpiece, which can allow the workpiece to be consistently positioned in a process module. In one detailed embodiment, a barrier to fluid entry is formed between the workpiece and a ring for retaining the workpiece against a workpiece holder. This provides a reliable seal during fluid processing to prevent fluid from reaching the underside of a workpiece. In various embodiments, the workpiece holder can be used to align a workpiece in a process module or to hold one or more workpieces in a configuration that allows for higher throughput.
Type:
Grant
Filed:
October 22, 2004
Date of Patent:
May 25, 2010
Assignee:
NEXX Systems, Inc.
Inventors:
Arthur Keigler, John Harrell, Zhenqiu Liu, Qunwei Wu
Abstract: A fuel stabilization device reduces the amount of dissolved oxygen within a fuel stream utilizing the combination of an electrochemical device to produce hydrogen gas and water and a catalyst that promotes the formation of water utilizing dissolved oxygen within the fuel and hydrogen gas generated by the electrochemical device.
Abstract: An electrochemical suspended element-based sensor system includes a solution cell for holding an electrolyte comprising solution including at least one electrochemically reducible or oxidizable species. A working electrode (WE), reference electrode (RE) and a counter electrode (CE) are disposed in the solution. The CE includes an asymmetric suspended element, wherein one side of the suspended element includes a metal or a highly doped semiconductor surface. The suspended element bends when current associated with reduction or oxidation of the electrochemically reducible or oxidizable species at the WE passes through the suspended element. At least one measurement system measures the bending of the suspended element or a parameter which is a function of the bending.
Abstract: An electrode, a method of producing the same, and a fuel cell including the electrode are disclosed. The electrode includes: a support; and a catalyst layer formed on the support, the catalyst layer includes: a support catalyst; and a proton conductor having an amorphous phase greater than about 60% by weight. The proton conductor includes: at least one material from the group of B2O3, ZrO2, SiO2, WO3, and MoO3; and P2O5, the proton conductor being 0.5-60 parts by weight where the support catalyst is 100 parts by weight. The proton conductor can be synthesized at a low enough temperature so that it can be applied to the support with catalyst particles to form a catalyst layer. The coated proton conductor is in a solid state so the fuel cell is stable over time and it does not obstruct a fuel gas so that the catalyst can be more efficiently used.