Abstract: Described is a process for augmenting or enhancing the aroma of a dryer-added fabric softener article comprising the step of intimately admixing with any component of said dryer-added fabric softener article prior to forming said article an aroma augmenting or enhancing quantity of at least one compound defined according to the structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and R is hydrogen or acetyl.
Type:
Grant
Filed:
October 9, 1980
Date of Patent:
January 19, 1982
Assignee:
International Flavors & Fragrances Inc.
Inventors:
Mark A. Sprecker, Frederick L. Schmitt, Manfred H. Vock, Joaquin F. Vinals, Jacob Kiwala
Abstract: The invention provides a method of heat-treating a biaxially oriented polyolefin film by constraining the film against shrinkage, heating the constrained film to at least the minimum stress relaxation temperature of the polyolefin, and thereafter cooling the treated film to a temperature below the alpha-relaxation temperature of the polyolefin. The film is preferably heated rapidly to the required temperature and cooled rapidly therefrom. The resultant films exhibit good modulus and thermal shrinkage characteristics. The heat-treatment may be supplemented by a conventional heat-setting operation to improve heat-sealing characteristics of the treated films.
Type:
Grant
Filed:
July 16, 1980
Date of Patent:
January 19, 1982
Assignee:
Imperial Chemical Industries Limited
Inventors:
Peter J. Barham, Jeffrey A. Odell, Frank M. Willmouth
Abstract: Compounds of the formula ##STR1## in which R and R.sub.1 are alkyl are described which compounds are potent inhibitors of premature vulcanization of rubber.
Abstract: A method of forming shaped articles from ionically cross-linked polymer compositions by subjecting an unshaped mass of said polymer composition to radio frequency energy of sufficient degree and time to cause dissociation of the ionically cross-linked regions while maintaining the mass at a temperature below the polymer degradation temperature and subjecting the polymer mass to sufficient shaping forces to form the polymer mass into desired shape.
Abstract: The present invention relates to a method for the production of vinyl chloride polymerizates by emulsion polymerization. The obtained polymerizate is suitable for the production of plastisols having very low viscosity.
Abstract: Outstandingly suitable drilling mud additives are water soluble copolymers consisting essentially of a random distribution of(a) 5 to 95% by weight of units of the formula ##STR1## (b) 5 to 95% by weight of units of the formula ##STR2## and (c) 0 to 80% by weight of units of the formula ##STR3## wherein R.sup.1 and R.sup.2 are the same or different and each is hydrogen, methyl or ethyl; and X.sup..sym. is a cation.
Type:
Grant
Filed:
August 1, 1980
Date of Patent:
January 5, 1982
Assignee:
Cassella Aktiengesellschaft
Inventors:
Friedrich Engelhardt, Ulrich Riegel, Martin Hille, Heinz Wittkus
Abstract: A coating composition comprising as a main component a polymeric resin obtained by solution polymerization of at least one of polymerizable amino acid compounds of either one of the formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each hydrogen, methyl or ethyl, R.sub.5 is hydrogen or C.sub.1 -C.sub.20 alkyl optionally having --SO--, --COO-- or --O-- therein, R.sub.6 is C.sub.1 -C.sub.12 alkylene optionally substituted with --OH, --SH or --SR.sub.7 (R.sub.7 being C.sub.1 -C.sub.4 alkyl) and/or optionally substituted with C.sub.1 -C.sub.4 alkyl or phenylene optionally substituted with C.sub.1 -C.sub.4 alkyl and A is --COOH or --SO.sub.3 H, and ##STR2## wherein R.sub.8, R.sub.9 and R.sub.10 are each hydrogen or C.sub.1 -C.sub.6 alkyl, R.sub.11 is hydrogen or C.sub.1 -C.sub.20 alkyl optionally having --SO--, --COO-- or --O-- therein, or a group of the formula: ##STR3## (R.sub.8, R.sub.9 and R.sub.10 being each as defined above), R.sub.12 is C.sub.2 -C.sub.
Abstract: The present invention relates to a copolymer for high refractive lens having a refractive index equal to or higher than 1.55, obtained by copolymerization of one or more of the first monomer component having the formula (I) ##STR1## wherein R.sub.1 signifies hydrogen atom or methyl radical, R.sub.2 signifies hydrogen atom or methyl radical, and m and n signify integers 0 to 4 in total, with one or more of the radically polymerizable second monomer component, homo-polymer of which has a refractive index equal to or higher than 1.55 and, if necessary, with the radically polymerizable third monomer component, the homo-polymer of which has a refractive index lower than 1.55 and to the lens prepared from said copolymer.
Abstract: A process for sulfonating polymers which are prepared by solution polymerization using a Friedel-Crafts or Ziegler-type catalyst is disclosed. The reactor effluent containing polymer, unreacted light monomers, diluent-solvent and active catalyst is first treated to remove substantially all unreacted light monomer, e.g. by flashing. The effluent is then treated with a sulfonating agent (e.g. acetyl sulfate and acetic acid) which simultaneously deactivates catalyst. Thereafter, the sulfonated polymer is neutralized, e.g. by exposure to metal salts, organic amines, etc., and subjected to normal finishing operations, e.g. deashing, steam stripping, stabilizing and drying.
Abstract: A process for recovering a rubbery polymer from a rubber-in-solvent solution by steam-stripping the solution to produce rubber crumb in aqueous phase using a low molecular weight lactone copolymer as stripping aid.
Abstract: In aqueous dispersions on the basis of polyvinyl chloride the content of residual monomers is reduced by the countercurrent method by contacting the rapidly moved surface of the dispersion with secluded intensely mixed gas atmospheres in several successive chambers. To carry out the process a device is used which permits to obtain under mild conditions residual monomer contents of 10 ppm and therebelow.
Type:
Grant
Filed:
May 19, 1980
Date of Patent:
November 17, 1981
Assignee:
Hoechst Aktiengesellschaft
Inventors:
Christoph Heinze, Franz Botsch, Horst Wolff
Abstract: Latex is shear coagulated to form a paste, the paste heated and sheared to form a desired crumb; the crumb is mechanically dewatered and ground to a desired particle size. Relatively low energy consumption is a feature of the process.
Type:
Grant
Filed:
March 24, 1980
Date of Patent:
November 10, 1981
Assignee:
The Dow Chemical Company
Inventors:
Ronald J. Pingel, Geofrey P. Onifer, Thomas L. Spencer
Abstract: The bulk polymerization of monomers which produce polymer insoluble in the monomers, in which the polymerization is carried out in an autoclave mounted on a horizontal axis and provided with stirring means formed of at least two half-frames arranged symmetrically of the axis of the autoclave and fixed at each end to a rotatable stub shaft axially mounted in the autoclave, each half-frame having a peripheral member serving as a blade which, on rotation of the half-frames, passes in close proximity to the interior surface of the autoclave, and bracing means interconnecting the peripheral members of the half-frames.
Abstract: An improved process for producing an aqueous emulsion of a vinyl chloride/vinyl ester/ethylene copolymer having a small heat fluidity and excellent strength which comprises continuously adding a solution of a specific polybasic acid polyallyl ester in the vinyl chloride and/or vinyl ester and further at least 60% by weight of the vinyl chloride and vinyl ester to the polymerization system during the polymerization reaction. The copolymer thus produced has a large benzene-insoluble part and the aqueous emulsion thereof is stable and is useful as an adhesive, as for paint compositions, or as a binder for fibers and papers.
Abstract: Hydrocarbons are recovered from a subterranean hydrocarbon-bearing formation penetrated by an injection well and a production well by displacing hydrocarbons toward the production well using a drive fluid such as water thickened with a copolymer of (a) vinyl sulfonic acid alkoxylated with 2,3-epoxy-1-propanol and (b) acrylamide. Optionally, the drive fluid can be saturated with carbon dioxide and/or natural gas at the injection pressure.
Abstract: A thermosetting coating composition which may have nonvolatile solids content as high as 60% or greater and which may be employed as an automotive topcoat. The composition, exclusive of pigments, solvent, reactive and non-reactive diluents and other non-reactive components, consists essentially of:(A) A binder composition consisting essentially of:(1) Between about 30 and about 75 weight percent of one or more low viscosity resins selected from hydroxy functional acrylic polymers, hydroxy functional polyethers and hydroxy functional polyesters, each of which (i) is substantially soluble in the solvent of the composition and (ii) has a number average molecular weight of between about 1000 and about 2500; and(2) Between about 70 and about 25 weight percent of one or more crosslinked dispersion polymers each of which is substantially insoluble in the solvent of the composition; and(B) An aminoplast crosslinking agent in an amount of between about 5 and about 40 parts per 100 parts of said binder composition.
Type:
Grant
Filed:
October 17, 1979
Date of Patent:
October 27, 1981
Assignee:
Ford Motor Company
Inventors:
Yun-Feng Chang, Henk V. Oene, Elaine C. Beckwith
Abstract: The present invention relates to a process for the reduction of the vinyl chloride content of aqueous dispersions of vinyl chloride polymers and copolymers by counter-current stripping with steam in a perforated plate column, by (1) adjusting the amount of steam introduced at the bottom of the column in such relation to the perforated area of an individual plate that the pressure drop across one plate gives a steam space between two adjacent plates of not more than 50 mm in height, such that the steam space is established just underneath the upper perforated plate and whereby the liquid layer is maintained above the lower perforated plate, and the liquid by bubbling steam therethrough, flushes the wall (surfaces) of the column in the steam space and said perforated plates to become clear of polymer particles; (2) the amount of dispersion fed to the top of the column and the amount of outgoing, stripped dispersion are adjusted in such relation to each other that at any time, the liquid layer is maintained well
Type:
Grant
Filed:
December 19, 1979
Date of Patent:
October 27, 1981
Assignee:
Norsk Hydro a.s
Inventors:
Glor T. Mejdell, Odd E. Palmgren, Arne Talmoen, Bjarne Vik
Abstract: Described is a dryer-added fabric softener article comprising a substrate, a substrate coating and an outer coating, said outer coating coated on said substrate coating and said substrate coating coated on said substrate, said substrate comprising a water dissolvable paper and said outer coating comprising an aroma augmenting or enhancing quantity of at least one indane alkanol or tricyclic isochroman having the structure: ##STR1## wherein X is hydrogen, methyl or --CH.sub.2 --; the dashed line is either a carbon-carbon single bond or no bond; R.sub.1 is hydrogen or methyl; R.sub.2, R.sub.3, R.sub.4 and R.sub.5 represent hydrogen, methyl or isopropyl; with the proviso that R.sub.2 and R.sub.3 are methyl when R.sub.4 is hydrogen and R.sub.5 is isopropyl or R.sub.4 and R.sub.5 represent methyl when R.sub.2 is hydrogen and R.sub.3 is isopropyl; and with the further proviso that the dashed line is a carbon-carbon single bond when X is --CH.sub.2 -- and the dashed line is no bond when X is hydrogen or CH.sub.3.
Type:
Grant
Filed:
November 13, 1980
Date of Patent:
October 20, 1981
Assignee:
International Flavors & Fragrances Inc.
Inventors:
Wilhelmus J. Wiegers, Mark A. Sprecker, Hugh Watkins, Manfred H. Vock, Frederick L. Schmitt
Abstract: A water and oil repellent essentially consisting of a copolymer comprising units of (a) at least one of fluoroalkyl group-containing polymerizable compounds and of (b) at least one of 2-hydroxy-3-chloropropyl acrylate and methacrylate of the formula:CH.sub.2 .dbd.CRCOOCH.sub.2 CH(OH)CH.sub.2 Clwherein R is hydrogen or methyl, which is highly resistant to laundering and dry cleaning.