Abstract: A process for preparing silane metal oxides comprising reacting a metal oxide with an amine compound to form an amine metal oxide intermediate, and subsequently reacting said intermediate with a halosilane.
Type:
Grant
Filed:
December 23, 1992
Date of Patent:
December 27, 1994
Assignee:
Xerox Corporation
Inventors:
Carl P. Tripp, Michael L. Hair, Richard P. N. Veregin
Abstract: An insulating composition consisting of Bi, Sr, RE, Cu, O or of Tl, Ba, RE, Cu, O (wherein; RE is an element selected from a group consisting of Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and Y) aligns properly with a crystal face of an oxide superconductor because its crystal structure is the same as or similar to that of the oxide superconductor. An insulating composition in which a part of Bi is replaced by Pb is further near the oxide superconductor its construction, and the modulation structure in this insulating composition is mitigated or disappears.
Abstract: A new silicon carbide material is made following a procedure including hot pressing to provide a finished product having a microstructure with an optimal grain size of less than 7 micrometers. The material exhibits a dominant failure mode of intergranular fracture requiring significant energy for crack propagation. The method of manufacturing is cost-effective by allowing the use of "dirty" raw materials since the process causes impurities to segregate at multi-grain boundary junctions to form isolated pockets of impurities which do not affect the structural integrity of the material. End uses include use as protective projectile-resistant armor.
Abstract: An aqueous composition comprising an active ingredient, a volatile organic compound and water, which is homogenized so that at least 90% by weight of the active ingredient are in particles of less than 1.0 micron in diameter, may be used to deliver an active ingredient. Suitable active ingredients include, but are not limited to, mold releases, coatings, solvents and reactive compounds.
Abstract: Optical fiber composed of a glass doped with at least laser-active ions of an element from the rare earths. An optical fiber of glass, preferably a HMF glass, doped with Tm.sup.3+ is operated at 1.48 .mu.m as a fiber laser or amplifier on the laser transition .sup.3 F.sub.4 -.sup.3 H.sub.4. Since this thereby involves a self-saturating transition, the terminal level is emptied in accelerated fashion for a continuous wave mode by co-doping with de-activators, preferably Ho.sup.3+, Tb.sup.3+, Eu.sup.3+ and/or Pr.sup.3+ ions. The pump light wavelength can be selected from the wavelength range from 700 through 890 nm of GaAlAs emission. The optical fiber can be used in optical amplifiers or fiber amplifiers.
Type:
Grant
Filed:
March 2, 1994
Date of Patent:
November 22, 1994
Assignee:
Siemens Aktiengesellschaft
Inventors:
Hartmut Schneider, Christian Gerndt, Armin Staudt
Abstract: A coating composition comprising an organosilicon compound and modified stannic oxide - zirconium oxide composite colloidal particles which are obtained by partially or fully coating the surface of stannic oxide - zirconium oxide composite colloidal particles with tungstic oxide - stannic oxide composite colloidal particles. The formed cured coating film is excellent in hot water resistance, and light-resistance and weathering resistance are not impaired even when the antireflection film made by vepor deposition of inorganic oxides is applied on the cured coating film.
Type:
Grant
Filed:
July 7, 1993
Date of Patent:
November 22, 1994
Assignees:
Hoya Corporation, Nissan Chemical Industries, Ltd.
Abstract: A synthetic quartz glass optical member for an ultraviolet laser, suitably applicable as a stepper lens of a lithographer using an excimer laser beam and other optical members, wherein the quartz glass has a hydroxyl content of 10 to 100 ppm, a chlorine content of 200 ppm or less, a hydrogen content of 1.times.10.sup.16 molecules/cm.sup.3 or less, a homogeneity of refractive index of 5.times.10.sup.-6 or less in terms of .DELTA.n, and a birefringence of 5 nm/cm or less. The optical member can be produced by subjecting a volatile silicon compound to flame hydrolysis with oxyhydrogen flame, depositing the formed particulate silica on a heat-resistant support to prepare a porous silica matrix, heating the matrix in a vacuum as high as 1.times.10.sup.-2 Torr or above to a temperature of 1,400 .degree. C.
Type:
Grant
Filed:
May 15, 1993
Date of Patent:
November 15, 1994
Assignee:
Shin-Etsu Quartz Products Company Limited
Abstract: An infrared and ultraviolet radiation absorbing glass suitable for use in building and vehicle windows, which comprises, on a weight basis, 68-74% of SiO.sub.2, 0.1-3.0% of Al.sub.2 O.sub.3, 8-11% of CaO, 2-4.5% of MgO, 11.5-16% of Na.sub.2 O, 0.5-3.0% of K.sub.2 O, 0.1-0.4% of SO.sub.3, 0.10-0.55% of total iron expressed as Fe.sub.2 O.sub.3, 0.2-0.6% of CeO.sub.2, 15-35 ppm of CoO and 2-18 ppm of Se. In the glass the ratio of ferrous iron to ferric iron is in the range from 0.17 to 0.55. The glass has a neutral grayish tint and is well balanced in visible light transmittance, infrared radiation absorption and ultraviolet radiation absorption, and a sheet of the glass can be easily tempered by a conventional method.
Abstract: A method for preparing granulated alkaline earth metal carbonate, especially barium carbonate and strontium carbonate, by adding a binding agent and optionally water, and granulating the carbonate material by the action of mechanical forces or by accretional granulation in, for example, a flash reactor, with simultaneous drying, and thereafter optionally subjecting the granules to a high-temperature treatment, in which method the material to be granulated and the granulated material do not come in contact with inorganic refractory material either during the granulation or during any subsequent high-temperature treatment.
Type:
Grant
Filed:
March 11, 1993
Date of Patent:
November 8, 1994
Assignee:
Solvay Barium Strontium GmbH
Inventors:
Jacopo Porta, Guido Riccioli, Pierino Trifoni, Christian Schiffling
Abstract: The preparation of porous ceramic bodies by sintering certain curable organopolysiloxanes filled with silicon carbide powders. This process is advantageous in that the green bodies have relative high strengths and thus can be easily handled and, if desired, machined before sintering.
Type:
Grant
Filed:
September 20, 1993
Date of Patent:
October 25, 1994
Assignee:
Dow Corning Corporation
Inventors:
William H. Atwell, Chandan K. Saha, Gregg A. Zank
Abstract: Paraffin wax emulsion is combined with alkali metal silicate solution to form a stable liquid mixture conferring increased strength and water repellency when applied to cellulosic fiber mat products such as paper and paperboard. This product can be varied in application levels and component ratios such that strength and hydrophobicity and recyclability can be optimized, depending on the final product requirements.
Abstract: Submicron sized ceramic particles are produced by combining a ceramic precursor with an organic or carbonaceous carrier material, and exposing droplets of the mixture to a temperature sufficient to cause combustion of the organic material and subsequent vaporization and nucleation, or diffusion and oxidation, of the ceramic precursor to form pure, crystalline, uniform nanophase ceramic particles.
Type:
Grant
Filed:
January 21, 1993
Date of Patent:
October 25, 1994
Assignee:
Physical Sciences, Inc.
Inventors:
Joseph J. Helble, Gary A. Moniz, Joseph R. Morency
Abstract: A method for fabricating Y.sub.3 Al.sub.5 O.sub.12 (YAG) fibers from water soluble polymers includes a pre-YAG polymer synthesis, with solution viscosity adjustment followed by fiber spinning and heat treatment. The polymer synthesis employs polar solvents such as water or alcohol with a carboxylic acid containing at least two carboxyl groups.
Abstract: A coating composition for use with ceramic composites to reduce gas permeability of the composites as well as provide an adhesive force to the composites. The coating composition comprises an aqueous dispersion of an aluminum phosphate precursor, silicon carbide, and aluminoborosilicate.
Type:
Grant
Filed:
June 11, 1993
Date of Patent:
September 27, 1994
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: Cyclodextrin complexes are prepared utilizing processes in which the cyclodextrin/active complex is prepared under concentrated reaction conditions in which there is no more than about 40% solvent, e.g., water, with mechanical working, to provide a complex ultimate particle size of less than about 12 microns and the resulting complex reaction mixture is incorporated, preferably without further operation, into at least one fabric conditioning material, preferably cationic fabric conditioning active, preferably in liquid (molten) form, preferably at a temperature between about 60 and about 95.degree. C., and mechanically worked to reduce complex aggregate particle size below about 200 microns. The resulting complex/fabric conditioning material mixture is used to prepare, e.g., dryer-added fabric softener article, e.g., sheet. The mixture of complex and fabric softener material preferably contains a small amount of an anionic surfactant to help avoid deposition of, e.g.
Type:
Grant
Filed:
October 8, 1993
Date of Patent:
September 20, 1994
Assignee:
The Procter & Gamble Company
Inventors:
Dennis R. Bacon, Thomas A. Borcher, Sr., Alessandro Corona, III, Clyde D. Palmer, Toan Trinh
Abstract: An alkali free glass consisting essentially of from 50 to 60 wt % of SiO.sub.2, from 8 to 16 wt % of Al.sub.2 O.sub.3, from 4 to 10 wt % of B.sub.2 O.sub.3, from 1.5 to 5 wt % of MgO, from 0 to 7 wt % of CaO, from 0 to 10 wt % of SrO, from 10 to 20 wt % of BaO and from 0 to 3 wt % of ZnO and essentially free from alkali metal oxides.
Abstract: This invention is directed to the production of transparent glasses exhibiting transmission far into the infrared regime of the radiation spectrum. The glasses consist essentially, in mole percent, of 42-55% CdF.sub.2 and/or CdCl.sub.2, 30-40% NaF and/or NaCl, 2-20% total of BaF.sub.2 and/or BaCl.sub.2 +KF and/or KCl, consisting of 0-15% BaF.sub.2 and/or BaCl.sub.2 and 0-7% KF and/or KCl, 1-12% total of at least one stabilizing metal halide selected from the group LiX, BeX.sub.2, MgX.sub.2, MnX.sub.2, PbX.sub.2, TlX, COX.sub.2, and ZnX.sub.2, and 0,005-0.5% REX.sub.3, wherein Re is at least one rare earth metal selected from the lanthanide series of rare earth metals and X is at least one halide selected from the group consisting of fluoride, chloride, and bromide. The preferred glasses contain at least 2% each of BaF.sub.2 and/or BaCl.sub.2 and KF and/or KCl.
Type:
Grant
Filed:
July 6, 1993
Date of Patent:
September 13, 1994
Assignee:
Corning Incorporated
Inventors:
Bruce G. Aitken, Frank A. Annunziata, Roger F. Bartholomew, Mark A. Newhouse, Mark L. Powley, Andrea L. Sadd
Abstract: A dental ceramic material is disclosed for the preparation and repair of metal ceramic and fully ceramic dentures, which has a processing temperature of 660.degree..+-.30.degree. C., and has the following composition: 60 to 65% by weight of SiO.sub.2, 8.5 to 11% by weight of Al.sub.2 O.sub.3, 8 to 12% by weight of K.sub.2 O, 10.5 to 12% by weight of Na.sub.2 O, 0.7 to 2% by weight of CaO, 0.5 to 2.5% by weight of B.sub.2 O.sub.3, 0.1 to 0.6% by weight of Sb.sub.2 O.sub.3, 0 to 0.5% by weight of CeO.sub.2, 1.0 to 3.8% by weight of TiO.sub.2, 0.8 to 1.4% by weight of Li.sub.2 O, and 0.6 to 2.4% by weight of F.sub.2.
Type:
Grant
Filed:
October 28, 1993
Date of Patent:
September 13, 1994
Assignees:
Degussa Aktiengesellschaft, Ducera Dental Gesellschaft mbH
Abstract: A plastically deformable mixture and method for making a body from the mixture are disclosed. The mixture is composed of powder materials, which when fired form as predominant phases: ceramic, glass-ceramic, glass, and combinations thereof, 0 to an effective amount of burnout agent, water, organic binder which can be cellulose ether, cellulose ether derivatives or combinations thereof, and hydrophilic and hydrophobic additives, to increase the wettability and/or lubricity of the mixture. One advantageous composition for ram extrusion is composed of ceramic-forming powders, water, and in percent by weight based on the powders, about 2% to 8% organic binder which can be methylcellulose, methylcellulose derivatives, and combinations thereof, about 0.3% to 1.0% sodium stearate, and about 0.5% to 2.0% oleic acid.
Abstract: Zinc-containing, lead- and cadmium-free glass frits with a softening point of less than 510.degree. C. are disclosed. Obligatory components of the glass-frit composition are 31-50 mole % ZnO, 10-44 mole % SiO.sub.2, 11-35 mole % B.sub.2 O.sub.3 and 11-25 mole % Na.sub.2 O. The glass frits can be used as base frit for the production of decorative coating masses which can be stoved below 630.degree. C., preferably masses for the decorating of glass.