Abstract: Diazo dyes of the general formula (I) ##STR1## are described where X.sup.+ is a quaternary ammonium group and Y.sup.- is a counterbalancing anion. The dyes are useful for coloring hair.
Type:
Grant
Filed:
November 26, 1997
Date of Patent:
March 9, 1999
Assignee:
Warner-Jenkinson Europe Limited
Inventors:
Roger W. Pengilly, Francis C. P. McLoughlin, Roger G. J. C. Twigg
Abstract: Compositions for coloring keratinous fibers comprising a sulfo-containing, water-dispersible polymer having carbonyloxy linking groups, and a colorant reacted into or onto the polymer backbone.
Type:
Grant
Filed:
December 6, 1996
Date of Patent:
March 2, 1999
Assignee:
Bristol-Myers Squibb Company
Inventors:
Mario L. Garcia, James J. Krutak, Keith C. Brown, Dante J. Rutstrom
Abstract: A composition for dyeing keratin fibres, and in particular human keratin fibres such as the hair, characterized in that it comprises, in a medium which is suitable for dyeing:at least one coupler selected from 2-iminoindoline derivatives of formula (I) and acid addition salts thereof: ##STR1## in which: R.sub.1 represents hydrogen, alkyl, hydroxyalkyl, alkoxycarbonyl or acyl;R.sub.2 represents hydrogen, alkyl, phenyl or arylsulphonyl;R.sub.3 represents hydrogen or alkyl which may be substituted with one or more hydroxyl, alkoxy, amino, alkylamino, dialkylamino, cyano or aryl groups;R.sub.4 and R.sub.5, which may be identical or different, denote hydrogen, hydroxyl, alkyl, alkoxy, amino, alkylamino, dialkylamino, aralkyl, halogen or a nitro group; andat least one oxidation base.
Type:
Grant
Filed:
August 22, 1997
Date of Patent:
March 2, 1999
Assignee:
L'Oreal
Inventors:
Eric Terranova, Aziz Fadli, Alain Lagrange
Abstract: N-(4-Aminophenol) prolineamide and cosmetically acceptable salts thereof are useful as primary intermediates in oxidative hair dyeing. Compositions which contain a hair dye produced by oxidatively coupling N-(4-aminophenol) prolineamide with a coupler in the presence of an oxidizing agent are applied to the hair in oxidative hair dyeing processes.
Type:
Grant
Filed:
February 17, 1998
Date of Patent:
March 2, 1999
Assignee:
Bristol-Myers Squibb Company
Inventors:
Mu-Ill Lim, Margaret A. Popp, Yuh-Guo Pan
Abstract: The invention relates to an oxidation dyeing composition for keratinous fibres, in particular for human keratinous fibres such as hair, of the type which comprises, in a medium appropriate for dyeing, at least one oxidation dye precursor and at least one coupler, and which is characterized in that it contains, as oxidation dye precursor, at least one para-phenylenediamine which is substituted in position 2 on the benzene ring, and/or at least one of its addition salts with an acid, and, as coupler, at least one specific 6-hydroxy-1,4-benzomorpholine and/or at least one of its addition salts with an acid. The invention also relates to the use of this composition for the dyeing of keratinous fibres, especially hair.
Abstract: The composition for dyeing keratin fibers is mixed with water prior to use and contains from 35 to 75 percent by weight of at least one powdery vegetable dye material; from 25 to 65 percent by weight of at least one oil; and from 0.001 to 15 percent by weight of a physiologically unobjectionable nitro dye compound, azo dye compound, quinone dye compound and/or a triphenylmethane dye compound. A method of dyeing hair using this composition is also described.
Type:
Grant
Filed:
May 1, 1997
Date of Patent:
February 2, 1999
Assignee:
Wella Aktiengesellschaft
Inventors:
Manfred Schmitt, Uwe Lenz, Wolfgang Balzer, Henk Niessink
Abstract: The invention provides compositions and methods containing novel bis-(2,4-diaminophenoxy)benzene coupling compounds, and cosmetically acceptable salts thereof, for use with conventional primary intermediate dye compounds and oxidizing agents for the oxidative coloring of human hair. The compositions of the invention may also contain other components typically used in oxidative hair dye preparations to impart intense and lasting coloration to hair.
Type:
Grant
Filed:
November 21, 1997
Date of Patent:
February 2, 1999
Assignee:
Bristol-Myers Squibb Company
Inventors:
Mu-Iii Lim, Yuh-Guo Pan, Linas R. Stasaitis
Abstract: The oxidation hair dye composition is based on a combination of coupler substance and developer substance, and includes, as developer substance, at least one 2,5-diaminobenzonitrile compound of the formula (I), ##STR1## in which R.sup.1 and R.sup.2, independently of each other, are selected from the group consisting of H, alkyl groups having 1 to 6 carbon atoms, hydroxyalkyl groups having 2 to 4 carbon atoms and dihydroxyalkyl groups having 3 to 4 carbon atoms, with the proviso that both of the R.sup.1 and R.sup.2 groups are not both hydrogen at the same time, or a physiologically compatible water-soluble salt thereof. The invention also includes new 2,5-diaminobenzonitrile compounds of formula I.
Abstract: An oxidation dyeing composition for keratinous fibres, in particular human keratinous fibres such as hair, of the type comprising a medium suitable for dyeing, the medium containing at least one first para-phenylenediamine oxidation dye precursor containing a primary, secondary or tertiary amine function; at least one first meta-phenylenediamine coupling agent; and either at least one second para-aminophenol oxidation dye precursor or at least one second meta-aminophenol coupling agent; or the acid addition salts thereof. The use of this composition for dyeing keratinous fibres, in particular human keratinous fibres such as hair.
Abstract: The invention pertains to granules which incorporate citric acid monohydrate as an exotherm control agent within a peracid containing core. The granules have improved dissolution rates of the peracid in a dishwashing cycle. Compositions containing the granules are also described.
Type:
Grant
Filed:
June 26, 1996
Date of Patent:
January 12, 1999
Assignee:
Lever Brothers Company, Division of Conopco, Inc.
Inventors:
David John Lang, Duane Anthony Raible, Charles Vincent Sabatino
Abstract: A system for mixing and dispensing oxygen sensitive hair dye consists of concentrates in a sealed air-tight system using preferably 3--8 dye concentrates in collapsible bags having an oxygen barrier. The dye concentrates, along with oxygen activating liquids, are sufficient to produce an infinite number of hair dye formulations, thereby avoiding buying and stocking many bottles of specific color dyes. For formulating the dye mixtures, exact charges, i.e., volumes measured to within 1 ml, are raised from the bags and discharged. Each bag is removably connected, in an air-tight seal, to a separate precision lift pump whose piston lift excursion may be selectively set to determine the volume of the dye charge.
Abstract: The invention provides compositions and methods for the oxidative coloring of human hair. The compositions of the invention contain as a primary dye intermediate a 1-(4-aminophenyl) pyrrolidine, or a cosmetically acceptable salt thereof. The compositions may also contain at least one other primary intermediate and conventional coupling compounds, in addition to an oxidizing agent and other components typically used in oxidative hair dye preparations. Preferred dye intermediates in the compositions of the invention include 1-(4-aminophenyl) pyrrolidine and 1-(4-amino-3-methylphenyl) pyrrolidine, or cosmetically acceptable salts thereof, which produce intense neutral colors when used in admixture with a suitable coupling agents, such as 3-aminophenol, in conventional hair dye base formulations.
Abstract: A 2-Substituted-1-naphthol of the formula: ##STR1## wherein R.sub.3 is C.sub.1 -C.sub.6 alkyl or monohydroxy C.sub.1 -C.sub.6 alkyl couples with a primary intermediate of the formula: ##STR2## wherein R.sub.1 and R.sub.2 are each independently C.sub.1 -C.sub.6 alkyl to produce an oxidative dye.