Abstract: For selectively reducing permeability to water in an underground formation producing oil and/or gas, injecting into the formation a composition comprising water, at least one water soluble aldehyde compound at a concentration (by weight) of 180 to 20,000 ppm and at least one non-ionic polysaccharide at a concentration (by weight) of 200 to 5000 ppm, the concentration of aldehyde compound being higher than that of polysaccharide. The composition may be used in the water injection well or the hydrocarbon producing well and may assist in the recovery of hydrocarbons.
Abstract: A nitrate ester which is 2,4,6-trinitro-1-(2-hydroxyethylamino)-3- (2-hydyethylnitramino)benzenedinitrate; 2,4,6-trinitro-1,3,5-tris(2-hydroxyethylamino)benzenetrinitrate; 2,2',4,4',6,6'-hexanitro-3-(2-hydroxyethylnitramino)stilbenitrate; 2,5-bis[3-(hydroxyethylaminonitrate)-2,4,6-trinitrophenyl]1,3,4-oxadiazole ; or 2,5-bis[3-(hydroxyethylaminonitrate)-5- (hydroxyethylnitraminonitrate)-2,4,6-trinitrophenyl]-1,3,4-oxiazole and a process for preparing these compounds.
Type:
Grant
Filed:
May 17, 1991
Date of Patent:
January 14, 1992
Assignee:
The United States of America as represented by the Secretary of the Navy
Abstract: The invention provides well working fluid compositions containing cotton burrs ground to certain particle size ranges to decrease the seepage loss of the fluid to fluid permeable formations contacted by the compositions. Also provided is a seepage loss additive comprising the ground cotton burrs in combination with one or more of ground oat hulls, ground corn cobs, hydrophobic organophilic water wettable cotton, ground citrus pulp, ground peanut shells, ground rice hulls, and ground nut shells.
Type:
Grant
Filed:
February 22, 1991
Date of Patent:
December 31, 1991
Assignee:
Venture Innovations, Inc.
Inventors:
Jack C. Cowan, Roy F. House, Andree' H. Harrington
Abstract: A process for reducing the corrosiveness of aerated aqueous solutions, which comprises stripping the oxygen with gas containing hydrogen sulfide after addition of a composition which is both catalytic of the reduction of oxygen by hydrogen sulfide gas and inhibiting of hydrogen sulfide corrosion, such composition comprising certain metallic salts and a water-soluble oxyethylenated amine.
Abstract: The invention provides well working fluid compositions containing oat hulls ground to certain particle size ranges to decrease the seepage loss of the fluid to fluid permeable formations contacted by the compositions. Also provided is a seepage loss additive comprising the ground oat hulls in combination with one or more of ground corn cobs, hydrophobic organophilic water wettable cotton, ground citrus pulp, and ground cotton burrs.
Type:
Grant
Filed:
December 10, 1990
Date of Patent:
December 10, 1991
Assignee:
Venture Innovations, Inc.
Inventors:
Roy F. House, Andree H. Harrington, Jack C. Cowan
Abstract: The new 1,3-di-arylmethoxy-4,6-dinitrobenzenes of the formula ##STR1## in which R.sup.1 and R.sup.2 independently of one another denote hydrogen or C.sub.1 -C.sub.4 -alkyl andAr represents C.sub.6 -C.sub.12 -aryl,can be prepared by reaction of 1,3-dihalogeno-4,6-dinitro-benzenes of the formula ##STR2## in which Hal represents chlorine or bromine, with an arylmethanol of the formulaAr--C(R.sup.1, R.sup.2)OH (IV),in which R.sup.1, R.sup.2 and Ar have the said meaning, and a strong base in the temperature range from 0.degree. to 100.degree. C.These di-arylmethoxy-dinitro-benzenes can be converted into 4,6-diaminoresorcinol by catalytic reduction with hydrogen.
Abstract: 1,14-bis(4-nitrophenyl)-1,3,5,7,9,11,13-tetradecaheptaene having the following formula (I): ##STR1## and a method of preparing the above-mentioned 1,14-bis(4-nitrophenyl)-1,3,5,7,9,11,13-tetradecaheptaene having formula (I) by allowing a phosphonium salt having formula (II) to react with 5-(4-nitrophenyl)-2,4-pentadiene-1-al having formula (III) in the presence of a basic catalyst:R.sub.3 P.sup..sym. H.sub.2 C--CH.dbd.CH--CH.sub.2 P.sup..sym. R.sub.3.2X.sup..crclbar.
Abstract: The invention provides for the use of compositions to dissolve sulfate scales from surfaces containing these scales, comprising an aqueous solution of an aminopolycarboxylic acid (APCA) containing 1 to 4 amino groups, e.g., diethylenetriaminepentaacetic acid (DTPA) or ethylenediaminetetraacetic acid (EDTA), or a salt thereof, and a second component which is diethylenetriaminepenta (methylenephosphonic acid) (DTPMP) or a salt thereof, or aminotri(methylenephosphonic acid) (ATMP), or a salt thereof. More particularly, the invention encompasses a method of removing sulfate scales from surfaces on which they have formed utilizing the foregoing solutions, particularly the removal of scales from equipment and wellbore surfaces associated with the operation of crude oil and gas wells.
Abstract: An aqueous alkaline flood for recovering oil from a reservoir containing acidic oil is improved by adding to the injected aqueous alkaline solution both a stoichiometric excess of the alkaline material and a kind and amount of preformed cosurfactant material that increases the salinity of that solution so that, in contact with the oil in the reservoir, it will form a surfactant system having a salinity requirement which minimizes the interfacial tension between it and the oil.
Type:
Grant
Filed:
August 9, 1989
Date of Patent:
November 26, 1991
Assignee:
Shell Oil Company
Inventors:
David R. Thigpen, Jimmie B. Lawson, Richard C. Nelson
Abstract: A surfactant composition, suitable for enhanced oil recovery comprising in a 60:40 to 10/90 weight ratio a) (o,m)- and/or (o,p)-dialkylbenzene alkali sulfonate and b) polyalkoxyphenyl ether alkali sulfonate.
Type:
Grant
Filed:
June 4, 1990
Date of Patent:
November 5, 1991
Assignee:
Shell Oil Company
Inventors:
Herman M. Muijs, Nicolaas C. M. Beers, Sebastianus P. F. M. Roefs
Abstract: A stable aqueous gel is formed from a polyvinyl alcohol or vinyl alcohol copolymer and a partially methylated melamine-formaldehyde resin in the presence of a pH regulating agent which provides an initial acid pH during the formulation of the gel.
Abstract: Surfactant composition comprising an alkyl amine ethoxylate and a gel breaker, wherein the gel breaker is a random copolymer of ethylene oxide with propylene oxide/or butylene oxide.
Abstract: The invention provides for the use of compositions to dissolve sulfate scales from surfaces containing these scales, comprising an aqueous solution of an aminopolycarboxylic acid (APCA) containing 1 to 4 amino groups, e.g., diethylenetriaminepentaacetic acid (DTPA) or ethylenediaminetetraacetic acid (EDTA), or a salt thereof, and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC) or a salt thereof. More particularly, the invention encompasses a method of removing sulfate scales from surfaces on which they have formed utilizing the foregoing solutions, particularly the removal of scales from equipment and wellbore surfaces associated with the operation of crude oil and gas wells.
Abstract: A process for the preparation of crystalline oxytitanium phthalocyanine showing a distinct diffraction in peak at a Bragg angle (2.theta..+-.0.2.degree.) of 27.3.degree. in the X-ray diffraction spectrum, which comprises mechanically pulverizing oxytitanium phthalocyanine, dispersing it in water to form a suspension, adding an organic solvent into the suspension and heating the suspension.
Abstract: Described herein is a continuous process for preparing dinitrotoluene by reacting toluene with dilute nitric acid to produce mononitrotoluene, then reacting the mononitrotoluene with concentrated nitric acid to produce dinitrotoluene.
Abstract: Brine-in-glycol emulsions are shown for use as well working fluids. The fluids have a glycol external phase and a brine internal phase. The separate phases are emulsified to create an emulsion and weighted with traditional weighting agents. The external phase is soluble or dispersible in sea water when diluted upon discharge.
Abstract: The viscosity of Xanthan gum polymer solutions is reduced by the addition of hydrogen peroxide and adjustment of the pH of the solution to at least 8.0.
Abstract: A process for dissolving wax, paraffin and/or sulfur deposits in an oil or gas pipeline or well comprises providing at the site of the deposit an acid and a compound which liberates carbon disulfide upon contact with the acid, whereby the deposit is dissolved by the liberated carbon disulfide.
Type:
Grant
Filed:
March 30, 1990
Date of Patent:
October 1, 1991
Assignee:
Atochem North America, Inc.
Inventors:
Paul J. McElligott, Jr., Stanley R. Sandler, John F. Kennoy, William J. Tuszynski
Abstract: An aqueous composition comprises an aminopolycarboxylic acid and a water-soluble organosilicon compound. The composition is useful for removing scale from well equipment and/or openings in a subterreanean formation, and for stabilizing fine particles within the formation to prevent their subsequent movement. Fluid flow through formations and wells treated with the composition tends to be increased and more stable.
Type:
Grant
Filed:
October 10, 1990
Date of Patent:
September 24, 1991
Assignee:
Union Oil Company of California
Inventors:
Leonard J. Kalfayan, David R. Watkins, Gregory S. Hewgill
Abstract: The present invention relates to an improved water based drilling fluid and an improved spotting fluid utilizing unhydrogenated synthetic hydrocarbon compositions which are non-polluting and minimally toxic. The invention provides excellent drilling fluid properties under a wide variety of drilling conditions. The synthetic hydrocabons are selected from the group consisting of branched chain oligomers synthesized from one or more olefins containing a C.sub.2 to C.sub.14 chain length and wherein the oligomers have an average molecular weight of from 120 to 1000. The compositions of these hydrocarbons are free of aromatics and petroleum based toxic impurities. The synthetic hydrocarbons are unhydrogenated.