Abstract: A cable, in particular for power transmission, for telecommunications or for data transmission, or also combined power/telecommunications cables, wherein at least one coating layer consists of a recyclable material which is halogen-free and has superior mechanical, electrical, and flame-retardant properties. This material consists of a polymer mixture comprising: (a) a crystalline propylene homopolymer or copolymer; and (b) a copolymer of ethylene with at least one alpha-olefin having from 4 to 12 carbon atoms, and optionally with a diene; the said copolymer (b) being characterized by a density of between 0.90 and 0.86 g/cm3 and by a Composition Distribution Index, defined as the weight percentage of copolymer molecules having an alpha-olefin content within 50% of the average total molar content of alpha-olefin, of greater than 45%. This material may also include a flame-retardant inorganic filler.
Type:
Grant
Filed:
January 21, 2000
Date of Patent:
June 25, 2002
Assignee:
Pirelli Cavi e Sistemi S.p.A.
Inventors:
Luca Castellani, Eduardo Grizante Redondo, Antonio Zaopo, Enrico Albizzati
Abstract: An aqueous composition suitable for use, when dry, as an improved elastomeric coating, caulk, sealant, or pressure sensitive adhesive is provided including a predominantly acrylic aqueous emulsion polymer, the polymer having a glass transition temperature (Tg) from −90° C. to 20° C., formed by the free radical polymerization of at least one ethylenically unsaturated nonionic acrylic monomer and 0.5-5%, by weight based on the total weight of said polymer, ethylenically unsaturated carboxylic acid monomer until 90-99.7% of said monomers by weight, based on the total weight of said polymer, has been converted to polymer and subsequently at least half of the remaining monomer is converted to polymer in the presence of 0.1-1.0 wt %, by weight based on the total weight of said polymer, t-amyl hydroperoxide.
Abstract: An aqueous composition that includes (A) a butadiene polymer latex that is prepared by an emulsion polymerization in the presence of a styrene sulfonate stabilizer and (B) a phenolic resin. A preferred aqueous butadiene polymer latex is one that is prepared by emulsion polymerization of at least 60 weight percent dichlorobutadiene monomer (based on the amount of total monomers used to form the butadiene polymer), in the presence of a styrene sulfonate stabilizer.
Abstract: A process for producing a substantially dry polymer particle powder. A mixture of polymerization reagents is formed from a mixture of at least one monomer source and a solvent selected from the group consisting essentially of water and organic solvents and an initiator source. The mixture of polymerization reagents is sprayed into a heated, controlled atmosphere, forming droplets of the mixture which are allowed to fall through the heated, controlled atmosphere for a sufficient period of time to obtain a desired degree of polymerization. The solvent is continuously evacuated from the atmosphere during the polymerization process.
Type:
Grant
Filed:
December 21, 2000
Date of Patent:
June 4, 2002
Assignee:
Waterguard Telecommunications Technologies, Inc.
Inventors:
Clarence S. Freeman, Matthew Max Freeman, Jon Joseph Freeman
Abstract: Thermally stabilized initiator composition comprising:
(a) at least one dialkyl peroxydicarbonate, and
(b) a stabilizing effective amount of a compound of Structure I:
wherein R1 and R2 are as defined in the summary of the invention section, processes for their preparation and use are disclosed.
Type:
Grant
Filed:
October 17, 2001
Date of Patent:
June 4, 2002
Assignee:
ATOFINA Chemicals, Inc.
Inventors:
Barbara L. Stainbrook, Michael S. Mendolia, Terry N. Myers, Peter A. Callais, Joseph M. Brennan
Abstract: The present invention is directed to copolymers of norbornene and functional group containing norbornene comonomers and processes for the preparation thereof. These polymers may be random, alternating or block copolymers or terpolymers, etc.
Type:
Grant
Filed:
June 9, 2000
Date of Patent:
May 28, 2002
Assignee:
Eastman Chemical Company
Inventors:
Gino Georges Lavoie, Peter Borden Mackenzie
Abstract: The present invention is an improvement upon the known method of anionically polymerizing monomers by contacting the monomers with an anionic polymerization initiator which is an organo-substituted alkali metal compound. The improvement comprises decreasing the viscosity of the polymer cement by adding at least 0.01 equivalent of a metal alkyl compound per equivalent of alkali metal initiator if the metal alkyl is added before or at the beginning of polymerization. If the metal alkyl is added during the polymerization or after but before the living polymer is terminated, then at least 0.01 equivalent of the metal alkyl compound per equivalent of living polymer chain ends is should be used. The alkyl groups of the metal alkyl are chosen such that they do not exchange with the organo substituents of the alkali metal, which can be the living polymer chain ends or the organo substituents of the initiator.
Type:
Grant
Filed:
March 29, 2000
Date of Patent:
May 21, 2002
Assignee:
KRATON Polymers US LLC
Inventors:
Carl Lesley Willis, Robert Charles Bening, Peter Taylor Murany, Steven Jon Weddle, Dale Lee Handlin, Jr.
Abstract: What is claimed are copolymers consisting essentially of from 1 to 90% by weight of the repetitive structural unit of the formula (1)
in which R1 is hydrogen or methyl, Z is a C1-C4-alkylene group and X is hydrogen, an alkali metal or ammonium, from 10 to 99% by weight of a repetitive structural unit which is derived from olefinically unsaturated comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and from 0 to 20% by weight of crosslinking structures originating from monomers having at least two olefinic double bonds.
These copolymers are suitable for use as drift control agents for crop protection compositions.
Abstract: Solid substrates and methods for their preparation are provided, where enhanced functionalization of solid substrates is achieved, so that higher levels of binding of a wide variety of moieties can be obtained. The surface is nitrated with a nitronium agent, where the nitro groups may be modified in a variety of ways to serve as sites for linking. The resulting solid substrates find use in therapy, diagnosis and processing.
Abstract: The invention pertains to a process wherein peroxides are dosed to a polymerization mixture, with essentially all of the organic peroxide that is used in the polymerization process having a half-life from 0.05 hour to 1.0 hour at the polymerization temperature. The dosing of such peroxide allows for accurate control of the polymerization rate, and the process will render a polymer with a low residual peroxide level.
Type:
Grant
Filed:
July 16, 2001
Date of Patent:
May 7, 2002
Assignee:
Akzo Nobel NV
Inventors:
Andreas Petrus Van Swieten, Hans Westmijze, Jacobus Schut
Abstract: A low color or colorless polymaleate as determined by a Gardner color number of 8 or less, said polymaleate is prepared by aqueous solution polymerization of 70 to 99.9 weight percent of maleic acid, 0.1 to 30 weight percent of an allylic sulfonate monomer, and 0.5 to 50 &mgr;m, based on the moles of monomer, of a polyvalent transition metal ion selected from group consisting of Group IVA, VA, VIA, VIIA, VIIIA, IB, IIB, and combinations thereof, wherein the weight percents are based on the total weight of monomer, provided that 10 to 60 mole percent of the carboxylic acid groups on the maleic acid are neutralized prior to polymerization. The low color or colorless polymaleates provide permanent press properties to textiles treated therewith and increases the resistance of such textiles to laundering abrasion. The polymaleates also may be used in cleaning compositions to disperse and suspend soils.
Type:
Grant
Filed:
November 16, 2000
Date of Patent:
May 7, 2002
Assignee:
National Starch and Chemical Investment Holding
Corporation
Inventors:
Anne-Marie Austin, Allen M. Carrier, Klein A. Rodrigues
Abstract: Rigid-rod monomers and polymers are provided for use in applications such as rapid prototyping, composites and adhesives. The monomers can be photocured through the end groups and then thermally post cured through the acetylene groups. The result is a highly crosslinked polymer having an effective glass transition temperature well above 200° C.
Type:
Grant
Filed:
October 16, 2000
Date of Patent:
April 30, 2002
Assignee:
University of Dayton
Inventors:
Richard P. Chartoff, Jayprakash C. Bhatt, Tat H. Tong
Abstract: A process for preparing polymers which comprises conducting polymerization in the presence of free radicals of the formula I
where Q is NR2 or S and T is CR3R4 or S and R1, R2, R3 and R4 can be identical or different and independently are hydrogen, C1- to C20-alkyl or C6- to C18-aryl.
Type:
Grant
Filed:
March 10, 1999
Date of Patent:
April 30, 2002
Assignees:
BASF Aktiengesellschaft, Max-Planck Gesellschaft zur Foerderung der Wissenschaften
e.V.
Inventors:
Michael Fischer, Jürgen Koch, Wolfgang Paulus, Klaus Müllen, Markus Klapper, Marco Steenbock, Daniel M. Colombani
Abstract: A process/apparatus is disclosed for continuously separating a liquid medium comprising diluent and unreacted monomers from a polymerization effluent comprising diluent, unreacted monomers and polymer solids, comprising a continuous discharge of the polymerization effluent from a slurry reactor through a discharge valve and transfer conduit into a first intermediate pressure flash tank with a conical bottom defined by substantially straight sides inclined at an angle to that of horizontal equal to or greater than the angle of slide of the slurry/polymer solids and an exit seal chamber of such diameter (d) and length (l) as to maintain a desired volume of concentrated polymer solids/slurry in the exit seal chamber such as to form a pressure seal while continuously discharging a plug flow of concentrated polymer solids/slurry bottom product of said first flash tank from the exit seal chamber through a seal chamber exit reducer with inclined sides defined by substantially straight sides inclined at an angle to t
Abstract: A cement dispersant having excellent ability to prevent slump loss and high water-reducing property which comprises a polycarboxylic acid type polymer having a specific molecular weight distribution, a method for the production thereof, and a cement composition using the dispersant are provided. The cement dispersant comprises as a main component thereof a polycarboxylic acid type polymer (A), having a weight average molecular weight in the range of 10,000 to 500,000 in terms of polyethylene glycol determined by gel permeation chromatography, and having a value determined by subtracting the peak top molecular weight from the weight average molecular weight in the range of 0 to 8,000.
Abstract: Phase change (hot melt) ink compositions for use in a phase change (hot melt) ink jet recording device in which recording is conducted by thermally melting the ink at a temperature above ambient temperature (20° C.) to provide prints that possess high quality images, scratch resistance, abrasion resistance, low-temperature storage stability and flexibility, offset and pick resistance, adhesion, and other desired properties are disclosed to comprise:
(a) from about 0.1% to about 30% of one or more colorants; and
(b) from about 0.1 to about 99.9% of one or more hybrid polymers.
Components other than those listed above may be included in the ink compositions to achieve specific printer, substrate, or end use requirements.
Abstract: At least one metal wire embedded in a vulcanized elastomeric matrix obtained from a mixture comprising at least one vulcanizable elastomer and at least one vulcanization agent such as sulfur. The metal wire is galvanized steel and the vulcanizable mixture contains at least 0.2% by weight of trimercapto triazine, with respect to the weight of said elastomer, and 0.1-0.5% by weight of cobalt, with respect to the weight of said elastomer.
Abstract: A method is disclosed for increasing the rate of vulcanization of a halogenated isobutylene sulfur rubber composition comprising heating said halogenated isobutylene rubber composition to a temperature ranging from 100° C. to 200° C., wherein said halogenated isobutylene rubber composition contains from 0.05 to 10 phr of sodium thiosulfate pentahydrate.
Type:
Grant
Filed:
June 19, 2001
Date of Patent:
April 16, 2002
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Richard Michael D'Sidocky, Bernard Matthew Bezilla, Jr., Leighton Randolph Spadone, David Michael Smith, Sr., Mark Andrew Marinko
Abstract: A solvent based composition containing a non-aqueous solvent and a substantially non-gelled polymeric composition is disclosed. The polymeric composition comprises the reaction product of an A polymer which is an addition polymer having 3.5 or more reactive functional groups per polymer chain and a B polymer having about 2 to about 3 functional groups per polymer chain that are co-reactive with the reactive functional groups of the A polymer. The solvent based composition includes coatings, adhesives, inks, primers, overprint varnishes and the like.
Abstract: Rigid-rod monomers and polymers are provided for use in applications such as rapid prototyping, composites and adhesives. The monomers can be photocured through the end groups and then thermally post cured through the acetylene groups. The result is a highly crosslinked polymer having an effective glass transition temperature well above 200° C.
Type:
Grant
Filed:
March 10, 1999
Date of Patent:
April 9, 2002
Assignee:
University of Dayton
Inventors:
Richard P. Chartoff, Jayprakash C. Bhatt, Tat H. Tong