Abstract: A precious metal tip on the side of a ground electrode is indirectly joined to the front end portion of the ground electrode via a mounting part interposed therebetween. The mounting part includes a base part and a protruding part. First, in the state where the precious metal tip is in contact with the protruding part, laser welding or the like is performed thereon to form a fused part and obtain a complex, and the base part is joined to a flat surface of the ground electrode by resistance welding. The grain size of grains of the mounting part in the vicinity of the of the fused part is greater than the grain size of the grain size of the grains thereof in the vicinity of the ground electrode, and the grain size of the grains of the flange part of the mounting part is smaller than the grain size of the grains of the protruding part.