Patents Examined by Cynthia Harris Kelly
  • Patent number: 5762826
    Abstract: A liquid crystal composition comprising one or more types compounds represented by general formula II: ##STR1## and one or more types of compounds selected from the group consisting of: ##STR2## wherein R, rings A and B, X, Y1, Y2, Y3, Y4 and m are defined herein.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: June 9, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takaaki Shimizu, Tatsushi Kaneko, Tsutomu Ogihara, Takeshi Kinsho, Kazuyuki Asakura, Mutsuo Nakashima
  • Patent number: 5741438
    Abstract: Optically active biphenyl derivatives including optically active biphenyl carboxylic acid derivative, hydroxybiphenyl derivative, alkoxybiphenylalkanol derivative and alkoxybiphenylalkanol derivative have the following structural formula: ##STR1## wherein R.sup.1 represents an alkyl group of 3-20 carbon atoms, R.sup.2 represents an alkyl group or alkoxyalkyl group of 1-20 carbon atoms which may optionally be substituted with at least one halogen atom. X represents --O--, --COO-- or --OCO--, m represents 0 or 1, n represents an integer of 1-6 and p represents 0 or 1, and the * mark represents an asymmetric carbon atom. These optically active biphenyl derivatives are useful as a ferroelectric liquid crystal material or its component having a sufficient spontaneous polarization and by which a high speed response is possible and which further exhibits a ferroelectric liquid crystal phase in a temperature region around room temperature.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: April 21, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Isao Kurimoto, Takayuki Higashii, Shoji Toda, Masayoshi Minai, Chizu Sekine, Takeshi Tani
  • Patent number: 5736068
    Abstract: Novel triphenylene compounds which contain, bonded to the triphenylene framework, at least three ethylenically unsaturated groups or groups carrying oxiranyl or thiiranyl groups, and a process for the preparation of discotic liquid crystalline crosslinked polymers.
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: April 7, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Lukas Haeussling, Dirk Funhoff, Karl Siemensmeyer, Karl-Heinz Etzbach, Friedrich Closs, Helmut Ringsdorf, Peter Schuhmacher
  • Patent number: 5665801
    Abstract: The synthesis of a high-molecular weight phosphorus-containing polyester flame retardant is disclosed. A metal complex is selected as the catalyst to catalyze the addition reaction of phosphorus compounds and unsaturated dicarboxylic acids in the presence of saturated dicarboxylic acids and diols at a relatively lower temperture in one single reactor to form phosphorus-containing diacids, followed by esterification and polymerization to complete the process.
    Type: Grant
    Filed: June 20, 1995
    Date of Patent: September 9, 1997
    Assignee: Industrial Technology Research Institute
    Inventors: Shinn-Jen Chang, Yuung-Ching Sheen, Rong-Shuh Chang, Tsai-Wie Tseng, Jen-Lien Lin
  • Patent number: 5657141
    Abstract: A liquid crystal device is constituted by disposing a chiral smectic liquid crystal between a pair of substrates each provided with an electrode and a uniaxial alignment film. The chiral smectic liquid crystal is placed in such a quasi-smectic A alignment state that the liquid crystal molecules will have a single average molecular axis under no electric field application on a lower temperature side within chiral smectic C phase range, wherein the single average molecular axis can be confirmed as a position providing the darkest state when observed through cross nicol polarizers. Such a quasi-smectic A alignment state is effective in providing a liquid crystal device (or display apparatus) having an improved shock resistance and a good low-temperature storage properties.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 12, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahiro Terada, Syuji Yamada, Hiroshi Mizuno
  • Patent number: 5651918
    Abstract: Optically active 1,3-dioxolane derivatives which carry a mesogenic radical in the 4-position and have the general formula (I) ##STR1## are suitable for use as doping agents in liquid-crystal mixtures--in particular ferroelectric liquid-crystal mixtures. The symbols in the general formula have the following meanings:R.sup.1 is composed analogously to the part of the general formula on the right-hand side of X or is an alkyl or alkylene radical which can be substituted,R.sup.2, R.sub.3 and R.sup.4 are H or alkyl (R.sup.4 is also alkenyl) which can also be substituted [R.sup.2 and R.sup.3, together with the C(2) of the dioxolane ring are also a cycloaliphatic radical or a keto group], J, l and n are zero, 1 or 2 and k and m are zero or 1, subject to the proviso that, if k is zero n is zero and if n is zero m is zero and 1.ltoreq.J+l+n.ltoreq.3,--A.sup.1, --A.sup.2 and --A.sup.3 are an aromatic, heterocyclic or aliphatic ring system, --M.sup.1 and --M.sup.2 are --CO--O, --0--CO, --CH.sub.2 CH.sub.2, --CH.dbd.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: July 29, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gunter Scherowsky, Jurgen Gay, Rainer Wingen, Hans-Rolf Dubal, Claus Escher, Wolfgang Hemmerling, Yoshio Inoguchi, Ingrid Muller, Dieter Ohlendorf
  • Patent number: 5648021
    Abstract: This invention relates to novel phenanthrene derivatives of the formula (I) which are particularly suitable for use in liquid-crystal mixtures. The compounds of formula (I) have a broad range of applications. Depending on the choice of substituents, they can be used as base materials from which liquid-crystalline phases are predominantly composed. They can also be added to liquid-crystalline base materials to modify the dielectric and/or optical anisotropy of a dielectric and to optimize its threshold voltage or viscosity. Liquid-crystalline mixtures containing compounds of formula (I) are particularly suitable for use in electrooptical switching and display devices.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: July 15, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rainer Wingen, Barbara Hornung
  • Patent number: 5645759
    Abstract: A liquid crystal composition having a low threshold voltage and a suitably large optical anisotropy, while retaining a high specific resistance value, is provided,which composition is composed of compounds expressed by the formulas (1), (2) and (4): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.4 each represent an alkyl group of 1 to 10C; n represents 0 or 1; A.sup.1, A.sup.2, A.sup.3 and A.sup.4 represent trans-1,4-cyclohexylene or 1,4-phenylene; Z.sup.1, Z.sup.3 and Z.sup.4 represent --C.sub.2 H.sub.4 -- or a single bond; and X.sup.1, X.sup.4 and X.sup.5 represent H or F,use of which composition can realize an active matrix type liquid crystal display element of a low drive voltage, a low power consumption and a high speed response.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: July 8, 1997
    Assignee: Chisso Corporation
    Inventors: Yoshitaka Tomi, Etsuo Nakagawa, Shinichi Sawada
  • Patent number: 5641428
    Abstract: Optically active, mesogenic 1,3-dioxolane-4-carboxylates are suitable as dopes in liquid-crystal mixtures. They result in liquid-crystalline ferroelectric phases having short switching times and in electroclinic phases having large electroclinic coefficients. Their particular advantage is that they induce a helix of very large pitch, meaning that helix compensation by further dopes is unnecessary. In addition, the 1,3-dioxolane-4-carboxylates exhibit high UV stability.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: June 24, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rainer Wingen, Hans-Rolf Dubal, Claus Escher, Wolfgang Hemmerling, Ingrid Muller, Dieter Ohlendorf
  • Patent number: 5637253
    Abstract: A chain polymeric liquid crystal compound having a structure expressed by the following general formula [I] as a flexible spacer and a chain polymeric liquid crystal copolymer compound, a polymeric liquid crystal composition containing at least one of their compounds and at least any one of a polymeric compound, a polymeric liquid crystal compound, a low molecular weight liquid crystal compound and a low molecular weight liquid crystal compound, a polymeric liquid crystal device which uses the same, and an apparatus and a method which use the polymeric liquid crystal device: ##STR1## (where X is --O--, --O--CH.sub.2 --CH.sub.2 --, --O--CH.sub.2 --, ##STR2## Y is --(CH.sub.2).sub.n -- (n=1 to 18), Z is a halogen atom, an alkyl group or an alkoxy group, and * is an asymmetric carbon atom).
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: June 10, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Koichi Sato, Kazuo Yoshinaga, Yomishi Toshida, Takeo Eguchi
  • Patent number: 5637254
    Abstract: A ferroelectric, liquid-crystalline polymer is composed of repeating units of the formula (I) ##STR1## in which Y=H, CH.sub.3 or F,R.sup.1 =a radical having at least two chiral centers such as for example ##STR2## a=2 to 20, preferably 6 to 12, b,c,d,e and f=0 or 1 with the proviso that d+e+f=2 or 3,A.sup.1,A.sup.2 and A.sup.3 =for example, 1,4-phenylene, cyclohexylene or 2,5-pyrimidinediyl,M.sup.2 and M.sup.3 =CO--O, O--CO, CO--S, S--CO, CH.sub.2 --O, O--CH.sub.2, and ##STR3## These liquid-crystalline polymers have short response times and resistance to mechanical stresses.They can be prepared by free-radical polymerization.
    Type: Grant
    Filed: March 29, 1995
    Date of Patent: June 10, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Gunter Scherowsky, Andreas Schliwa, Wolfgang Trapp
  • Patent number: 5632929
    Abstract: A novel LCP material based on forked side chain acrylates is disclosed having a general formula I; ##STR1## wherein W=H, CH.sub.3, Cl R.sub.1 and R.sub.2 may or may not be the same but have the following general structure: ##STR2## p=2 to 14; q=0 or 1;r=1 or 2;s=1 or 2;X=O, CO.sub.2, O.sub.2 C, CH.sub.2 ;Y=C.sub.2 H.sub.4, O, CO.sub.2, O.sub.2 C;Z=CN, halogen, R, CO.sub.2 R, OR, O.sub.2 CR, wherein R=chiral or achiral.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: May 27, 1997
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Mark A. Verrall, Owain L. Parri, David Coates
  • Patent number: 5630962
    Abstract: 2-Fluoropyridines, processes for their preparation and their use in ferroelectric liquid crystal mixturesA 2-fluoropyridine of the formula (I) ##STR1## in which the symbols have the following meaning: R.sup.1, R.sup.2, independently of one another, are, for example, H or straight-chain or branched alkyl, A.sup.1, A.sup.2, A.sup.3, A.sup.4, identical or different, are, for example, 1-phenylene, pyrazine-2,5-diyl or trans-1,4-cyclohexylene, M.sup.1, M.sup.2, M.sup.3, M.sup.4, identical or different, are, for example, --O-- or --CO--O--, R.sup.3, R.sup.4, R.sup.6, R.sup.7, independently of one another, are, for example, H or straight-chain or branched alkyl, M.sup.5 is, for example, --O--CO-- or a single bond, k, l, m, n, o, p, q, r are zero or one, with the proviso that the sum of k+m+p+r is less than 4 and greater than zero, can advantageously be used as a component in ferroelectric liquid crystal mixtures.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: May 20, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Hubert Schlosser, Rainer Wingen, Gerd Illian, Claus Escher
  • Patent number: 5626791
    Abstract: An aromatic compound of the formula (I)R.sup.1 (--A.sup.1).sub.a (--M.sup.1).sub.b (--A.sup.2).sub.c (--M.sup.2).sub.d --B(--M.sup.3).sub.c (--A.sup.3).sub.f (--M.sup.4).sub.g (--A.sup.4).sub.h --R.sub.2 (I)in whichB is one of the two following aromatic groups: ##STR1## Q.sup.1, Q.sup.2, Q.sup.3 and Q.sup.4 are identical or different and are CH.sub.2, CF.sub.2, N--R.sup.3, S, O or C.dbd.O;P.sup.1, P.sup.2 and P.sup.3 are identical or different and are C--H, C--F or N; andthe remaining symbols and indicies define mesogenic radicals, The compounds are suitable as components of liquid-crystalline mixtures.
    Type: Grant
    Filed: August 2, 1994
    Date of Patent: May 6, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Franz Fenkl, Javier Manero, Hubert Schlosser, Dietmar Jungbauer
  • Patent number: 5624601
    Abstract: A silacyclohexane compound of the following formula (I) ##STR1## wherein R represents an organic residue; ##STR2## represents a trans-1-sila-1,4-cyclohexylene group or trans-4-sila-1,4-cyclohexylene group having a substituent of H, F, Cl or CH.sub.3 ; L.sub.1 represents F, L.sub.2 and L.sub.3 independently represent H, F, Cl or CH.sub.3 ; X represents an organic residue, F or Cl; and n is an integer of 0, 1, or 2 and a and b are, respectively, 0 or 1 provided that a+b=1. Silacyclohexane compounds are useful in liquid crystal compositions and also in liquid crystal devices.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: April 29, 1997
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takaaki Shimizu, Takeshi Kinsho, Tsutomu Ogihara, Tatsushi Kaneko, Mutsuo Nakashima, Hideshi Kurihara
  • Patent number: 5614652
    Abstract: There is provided a means of cellular level therapy or prophylaxis whereby endocytosable particles are administered so as to emit cytotoxic radiation or to release metal cations having a therapeutic or prophylactic effect, eg. a vital replication suppressing effect, within cells such as macrophages following their uptake by these cells.
    Type: Grant
    Filed: October 5, 1993
    Date of Patent: March 25, 1997
    Assignee: Syngenix Limited
    Inventors: Aaron G. Filler, Andrew M. Lever
  • Patent number: 5606108
    Abstract: The preferred oligomers of the present invention are polyureas having a number average molecular weight of <10,000. These oligomers are water-soluble, have a rigid backbone, have recurring units coupled by carbonyl linking moieties which have anionic groups, display predominantly linear geometry such that regular spacing between anionic groups exists in an aqueous medium, and are pharmaceutically-acceptable. These oligomers are prepared by reacting an aromatic diamine with a difunctional electrophile, in the presence of an acid acceptor, in water as the solvent or water with up to about 1 mole of water immiscible cosolvent, at a temperature of from 0.degree. to 100.degree. C. and at a pH between about 7 to about 9. The oligomers are useful for the treatment and/or diagnosis of AIDS and ARC.
    Type: Grant
    Filed: October 6, 1993
    Date of Patent: February 25, 1997
    Assignees: Merrell Pharmaceuticals Inc., The Dow Chemical Co.
    Inventor: Michael J. Mullins
  • Patent number: 5605672
    Abstract: The invention features a method of blood pool imaging which utilizes an imaging agent which can be easily labelled with a radioactive isotope and injected into a patient. The imaging agent is a covalent conjugate of a polymeric carrier, protective groups, and chelating groups. The imaging agent is preferably provided in the form of a blood pool imaging composition, which includes an imaging agent of the invention, a buffer and a reducing compound. A radioactive isotope is added to the blood pool imaging composition to label the imaging agent, and the composition containing the labelled imaging agent is injected intravenously into a patient.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: February 25, 1997
    Assignee: The General Hospital Corporation
    Inventors: Alexei A. Bogdanov, Ralph Weissleder, Thomas J. Brady, Ronald Callahan
  • Patent number: 5599479
    Abstract: A ferroelectric chiral smectic liquid crystal composition, comprising at least one optically active compound represented by the following formula (I): ##STR1## wherein R.sub.1 denotes a linear or branched alkyl group having 1-18 carbon atoms capable of having a subtituent; X.sub.1 denotes a single bond, ##STR2## Z denotes a single bond or ##STR3## denotes ##STR4## and n is an integer of 1-12; and at least one compound represented by the following formula (II): ##STR5## wherein R.sub.2 and R.sub.3 respectively denote a linear or branched optically inactive alkyl group having 1-18 carbon atoms capable of having an alkoxy group of 1-12 carbon atoms; X.sub.2 and X.sub.3 respectively denote a single bond, ##STR6## and p and q are respectively 0, 1 or 2 with proviso that both of p and q are not 0.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: February 4, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenji Shinjo, Takao Takiguchi, Hiroyuki Kitayama, Kazuharu Katagiri, Masataka Yamashita, Takeshi Togano, Masahiro Terada, Akio Yoshida, Yoshiko Kimura
  • Patent number: RE35568
    Abstract: The present invention is directed to a method for replacing a carboxylic acid group with a fluorine .[.group.]. in a halogenated aliphatic carboxylic acid compound having the formula, R-COOH, to prepare a fluorinated product having the formula, R-F, wherein R is a halogenated aliphatic group including straight- and branched-chain aliphatic groups selected from the group consisting of halogenated aliphatic and .Iadd.halogenated .Iaddend.alkoxy-substituted .[.halogenated.]. aliphatic groups, wherein the method comprises the step of (a) reacting the halogenated aliphatic carboxylic acid compound with bromine trifluoride, and (b) recovering the fluorinated product.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: July 22, 1997
    Assignee: Ohmeda Pharmaceutical Products Division Inc.
    Inventors: Donald F. Halpern, Mark L. Robin