Abstract: A composition having the structure of formula I: [R—Ar—(COOH)2]x[Ar—(COOH)3]2-xM32+??(I) is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C1-C4 alkyl secondary amine, C1-C4 alkyl oxy, Br—(C1-C4 alkyl), NO2—(C1-C4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH3(CH2)mC(O)Cl, or CH3(CH(C1-C4 alkyl)CH2)mC(O)Cl, or CH3(CH2)m-Ph-(CH2)pC(O)Cl, where Ph is a C6 phenyl or C6 phenyl with one or more hydrogens replaced with F, C1-C4 fluoroalkyl, or C1-C4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>×>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.

Abstract: One variation of a method for carbon sequestration includes: mixing ambient air including carbon dioxide and secondary gases with a working fluid to generate a first mixture; conveying the first mixture through a compressor to pressurize the first mixture from a first pressure to a second pressure greater than the first pressure to promote absorption of carbon dioxide into the working fluid; depositing the first mixture in a high-pressure vessel to generate an exhaust stream of secondary gases and a second mixture including carbon dioxide dissolved in the working fluid; conveying the second mixture through a turbine configured to extract energy and reduce pressure of the second mixture, from the second pressure to the first pressure, to promote desorption of carbon dioxide from the working fluid; transferring the second mixture into the low-pressure vessel; and releasing carbon dioxide, desorbed from the working fluid, from the low-pressure vessel for collection.

Abstract: The use of a synergistic mixture of extractants for extracting at least one rare earth element from an aqueous medium comprising phosphoric acid. The mixture comprises: —a first extractant of formula (I): wherein R1 and R2, which are identical or different, represent a linear or branched, saturated or unsaturated hydrocarbon group, comprising from 6 to 12 carbon atoms, or a phenyl group optionally substituted by a linear or branched, saturated or unsaturated hydrocarbon group, comprising from 1 to 10 carbon atoms; and—a second extractant of formula (II): in which R3 represents a linear or branched alkyl group, comprising from 6 to 12 carbon atoms. Use of the synergistic mixture in the treatment of phosphate minerals with a view to recovering the rare earth elements contained in the minerals.

Abstract: The present application pertains to processes producing oxides using a weak acid intermediate. In one embodiment a material comprising calcium carbonate is reacted with a solution comprising aqueous carboxylic acid to form a gas comprising carbon dioxide and a solution comprising aqueous calcium carboxylate. The solution comprising aqueous calcium carboxylate is reacted with sodium sulfate to form a solution comprising aqueous sodium carboxylate and a solid comprising calcium sulfate. The solution comprising aqueous sodium carboxylate is reacted with sulfur dioxide to form sodium sulfite and an aqueous carboxylic acid. The sodium sulfite is separated from said aqueous carboxylic acid and reacted to form a solid comprising calcium sulfite which is decomposed to form calcium oxide and sulfur dioxide.

Abstract: The present application pertains to processes producing oxides using a weak acid intermediate. In one embodiment a material comprising calcium carbonate is reacted with a solution comprising aqueous carboxylic acid to form a gas comprising carbon dioxide and a solution comprising aqueous calcium carboxylate. The solution comprising aqueous calcium carboxylate is reacted with sodium sulfate to form a solution comprising aqueous sodium carboxylate and a solid comprising calcium sulfate. The solution comprising aqueous sodium carboxylate is reacted with sulfur dioxide to form sodium sulfite and an aqueous carboxylic acid. The sodium sulfite is separated from said aqueous carboxylic acid and reacted to form a solid comprising calcium sulfite which is decomposed to form calcium oxide and sulfur dioxide.

Abstract: Methods for preparing and compositions including untreated and surface-treated alkaline earth metal carbonate particulates are described. For example, a method for processing alkaline earth metal carbonate may include introducing alkaline earth metal carbonate into a stirred media mill, and dry grinding the alkaline earth metal carbonate in the stirred media mill to produce an untreated alkaline earth metal carbonate particulate having certain characteristics. In some examples, the method may include introducing carboxylic acid and/or carboxylic acid salt into the stirred media mill, and dry grinding the alkaline earth metal carbonate and the carboxylic acid and/or carboxylic acid salt in an integrated dry grinding and surface-treating process in the stirred media mill to produce a surface-treated alkaline earth metal carbonate particulate. In some examples, heating may be added during the dry grinding process.

Abstract: A method for preparing a compound having the following formula (IV): R2—(SO2)—NLi—(SO2)—F (IV), the method including a step a) of reacting a sulphamide having the following formula (A): R0—(SO2)—NH2 (A) with at least one sulphur-containing acid and at least one chlorinating agent, the step a) being carried out: at a temperature between 90° C. and 130° C., and at a pressure which is strictly greater than 7 bar (absolute).

Abstract: The present application pertains to processes producing oxides using a weak acid intermediate. In one embodiment a material comprising calcium carbonate is reacted with a solution comprising aqueous carboxylic acid to form a gas comprising carbon dioxide and a solution comprising aqueous calcium carboxylate. The solution comprising aqueous calcium carboxylate is reacted with sodium sulfate to form a solution comprising aqueous sodium carboxylate and a solid comprising calcium sulfate. The solution comprising aqueous sodium carboxylate is reacted with sulfur dioxide to form sodium sulfite and an aqueous carboxylic acid. The sodium sulfite is separated from said aqueous carboxylic acid and reacted to form a solid comprising calcium sulfite which is decomposed to form calcium oxide and sulfur dioxide.

Abstract: A composition having the structure of formula I: [R—Ar—(COOH)2]x[Ar—(COOH)3]2-xM32+??(I) is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C1-C4 alkyl secondary amine, C1-C4 alkyl oxy, Br—(C1-C4 alkyl), NO2—(C1-C4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH3(CH2)mC(O)Cl, or CH3(CH(C1-C4 alkyl)CH2)mC(O)Cl, or CH3(CH2)m-Ph-(CH2)pC(O)Cl, where Ph is a C6 phenyl or C6 phenyl with one or more hydrogens replaced with F, C1-C4 fluoroalkyl, or C1-C4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>x>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.

Abstract: A system and method for producing hydrogen (H2) gas and a single or hybrid hydrogen active material based aqueous suspension from pre-prepared effervescent tablets are provided. The produced H2 gas can be stored in a tank or directly utilized in a fuel cell, whereas the produced suspension can be employed as an advanced heat transfer fluid in a variety of thermal applications. The effervescent tablets can be fabricated with a homogeneously mixed and well-compressed mixture of hydrogen active metallic particles and effervescent powder in a sealed container to prevent air and humidity from reacting with the raw materials. As a result of the chemical reaction between the tablet and water, H2 gas (in the form of bubbles) and the hydrogen active material-based suspension are produced simultaneously. This system results in two products that can be used individually or all at once by integrating the different system components together.

Abstract: The present disclosure relates to improved solid state sorbent materials and methods for controlling and enhancing carbon dioxide adsorption performance for selected metal-organic framework (MOF) materials. The present disclosure further relates to inventive methods using a novel class of diamine-appended metal-organic frameworks MOF absorbents displaying step-shaped adsorption isotherms with large carbon dioxide capacities. More specifically, the present disclosure relates to diamine-appended MOF materials exhibiting step-shaped adsorption isotherms that are employed in a method utilizing humidity to control and improve carbon dioxide adsorption performance.

Abstract: The invention comprises a method of mineralization of carbon dioxide. The method comprises delivering hyaloclastite, a volcanic glass or pumice to a mill capable of reducing the particle size of the hyaloclastite, a volcanic glass or pumice; processing the hyaloclastite, a volcanic glass or pumice in the mill so that the processed hyaloclastite, a volcanic glass or pumice has a volume-based mean particle size of less than or equal to 40 ?m; and exposing the hyaloclastite, a volcanic glass or pumice to carbon dioxide in gaseous, liquid or solid form during or after the particle reduction process. Optionally a carbon dioxide sorbent or carbonation enhancing agent is added to the hyaloclastite pozzolan or mineral during the grinding or post-grinding process and combined with carbon dioxide during grinding or post grinding.

Abstract: A composition having the structure of formula I: [R—Ar—(COOH)2]x[Ar—(COOH)3]2-xM32+??(I) is provided where M is Mn, Cu, Co, Fe, Zn, Cd, Ni, or Pt; R is a bromine, nitro, a primary amine, C1-C4 alkyl secondary amine, C1-C4 alkyl oxy, Br—(C1-C4 alkyl), NO2—(C1-C4 alkyl), a mercaptan, and reaction products of any of the aforementioned with acyl chlorides of the formulas: CH3(CH2)mC(O)Cl, or CH3(CH(C1-C4 alkyl)CH2)mC(O)Cl, or CH3(CH2)m-Ph-(CH2)pC(O)Cl, where Ph is a C6 phenyl or C6 phenyl with one or more hydrogens replaced with F, C1-C4 fluoroalkyl, or C1-C4 perfluoroalkyl; m is independently in each occurrence an integer of 0 to 12 inclusive; p is an integer of 0 to 36 inclusive, to form an amide, a thioamide, or an ester; Ar is a 1,3,5-modified phenyl, and 1.4>x>0. A process of synthesis thereof and the use to chemically modify a gaseous reactant are also provided.

Abstract: The present invention refers to a process for the preparation of a surface-treated magnesium hydroxide-comprising material, a surface-treated magnesium hydroxide-comprising material as well as the use of the surface-treated magnesium hydroxide-comprising material in polymer composition, in paper making, paper coatings, agricultural applications, paints, adhesives, sealants, composite materials, wood composite materials, construction applications, pharma applications and/or cosmetic applications as well as surrounding materials, wherein the surface treatment agent of the surface-treated magnesium hydroxide-comprising material is undergoing a reaction with the surrounding material.

Abstract: A process, composition, and apparatus for carbon dioxide (CO2) sequestration are disclosed. The process includes passing air containing the CO2 through a cyclopropeneimine (CPI)-functionalized material. The composition includes a CPI-functionalized material that reacts with CO2 when mixed with air containing the CO2. The apparatus includes a component for providing a CPI-functionalized material and mixing the material with CO2 gas.

Abstract: A primary amine polymer aerogel comprising greater than 5 wt. % of primary amine monomers covalently bound to cross-linking monomers, wherein the primary amine monomers are selected from vinyl amine. A secondary amine polymer aerogel comprising secondary amine monomers covalently bound to cross-linking monomers, the secondary amine monomers being a result of substituting a hydrogen atom from a primary amine polymer aerogel, the primary amine polymer aerogel comprising vinyl amine monomers covalently bound to the cross-linking monomers. A tertiary amine polymer aerogel comprising tertiary amine monomers covalently bound to cross-linking monomers, the tertiary amine monomers being a result of substituting hydrogen atoms from a primary amine polymer aerogel, the primary amine polymer aerogel comprising vinyl amine monomers covalently bound to the cross-linking monomers.

Abstract: Provided herein are methods comprising a) calcining limestone in a cement plant to form carbon dioxide and calcium compound selected from calcium oxide, calcium hydroxide, or combination thereof; b) treating the calcium compound with N-containing salt in water to produce an aqueous solution comprising calcium salt and N-containing salt; and c) contacting the aqueous solution with the carbon dioxide under one or more precipitation conditions to produce a precipitation material comprising calcium carbonate and a supernatant aqueous solution wherein the calcium carbonate comprises vaterite.

Abstract: Novel radioactive iodide molecular traps, in which one or more metal atoms are functionalized by coordinating to an amine containing two or more nitrogens, and methods of using the molecular traps to capture radioactive iodide.

Abstract: The present disclosure relates to a method for preparing a mordenite zeolite, the method including crystallizing, at a temperature of 150° C. to 190° C., a gel which includes, in mol based on 1 mol of silica, 0.02 to 0.2 of an alumina precursor, 0.01 to 0.04 of a structure-directing agent, 0.1 to 0.18 of a pH control agent, and 10 to 100 of water. According to the present disclosure, a mordenite zeolite having high particle size uniformity and a particle size controllable while maintaining the particle size uniformity may be prepared.

Abstract: Effluent water is combined with carbon dioxide sourced from a carbon dioxide-containing emission stream to produce a reaction solution. The pH of the reaction solution is controlled to induce precipitation of a carbonate salt from the reaction solution.