Abstract: The present disclosure relates to a membrane-electrode assembly for fuel cells and a method of manufacturing the same, and more particularly to a membrane-electrode assembly to which an electrolyte membrane including a cerium oxide and phosphoric acid functionalized graphene oxide is applied, whereby chemical durability and proton conductivity of the membrane-electrode assembly are improved.

Abstract: Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO4 displayed room temperature conductivity up to 0.26 mS cm?1 and stability up to 10.0 V (vs. Li+/Li0). This outcome portends use of COFs as solid-state electrolytes in batteries.

Abstract: According to an embodiment, there is provided an electrode including an active material-containing layer. A logarithmic differential pore volume distribution curve of the active material-containing layer by a mercury intrusion method includes first and second peaks. The first peak is a local maximum value in a range where a pore size is from 0.1 ?m or more to 0.5 ?m or less. The second peak is a local maximum value in a range where the pore size is from 0.5 ?m or more to 1.0 ?m or less. An intensity A1 of the first peak and an intensity A2 of the second peak satisfy 0.1?A2/A1?0.3. A density of the active material-containing layer is from 2.9 g/cm3 or more to 3.3 g/cm3 or less.

Abstract: Described herein is a polymer-electrolyte-membrane fuel cell (PEMFC) that incorporates a shunt into the membrane separator that becomes electronically conductive around a well-defined anodic onset potential, thereby preventing excessive anodic potentials at the positive electrode that would otherwise drive deleterious parasitic reactions such as catalyst dissolution or catalyst and carbon oxidation.

Abstract: An electrochemical cell including at least one nitrogen-containing compound is disclosed. The at least one nitrogen-containing compound may form part of or be included in: an anode structure, a cathode structure, an electrolyte and/or a separator of the electrochemical cell. Also disclosed is a battery including the electrochemical cell.

Abstract: An energy storage device includes a nano-structured cathode. The cathode includes a conductive substrate, an underframe and an active layer. The underframe includes structures such as nano-filaments and/or aerogel. The active layer optionally includes a catalyst disposed within the active layer, the catalyst being configured to catalyze the dissociation of cathode active material.

Abstract: This disclosure relates to semi-solid electrodes which are pre-formed prior to inclusion in lithium ion batteries, lithium ion batteries which incorporate the semi-solid electrodes and methods of making the semi-solid electrodes. An electrochemical cell includes a semi-solid anode formed of anode active material injected with an electrolyte and a first electrolyte additive, the semi-solid anode having a first SEI layer; and a semi-solid cathode formed of a cathode active material injected with an additional electrolyte and a second electrolyte additive, the semi-solid cathode having a second SEI layer, wherein the first electrolyte additive and the second solid electrolyte additive are different.

Abstract: A problem to be solved by the present invention is to provide a carbonaceous material suitable for a negative electrode active material for non-aqueous electrolyte secondary batteries (e.g., lithium ion secondary batteries, sodium ion secondary batteries, lithium sulfur batteries, lithium air batteries) having high charge/discharge capacities and preferably high charge/discharge efficiency as well as low resistance, a negative electrode comprising the carbonaceous material, a non-aqueous electrolyte secondary battery comprising the negative electrode, and a production method of the carbonaceous material. The present invention relates to a carbonaceous material having a nitrogen element content of 1.0 mass % or more and an oxygen content of 1.5 mass % or less obtained by elemental analysis, a ratio of nitrogen element content and hydrogen element content (RN/H) of 6 or more and 100 or less, a ratio of oxygen element content and nitrogen element content (RO/N) of 0.1 or more and 1.

Abstract: A method for producing an LGPS-type solid electrolyte can be provided, the method includes preparing a homogeneous solution by mixing and reacting Li2S and P2S5 in an organic solution such that the molar ratio of Li2S/P2S5 is 1.0-1.85; forming a precipitate by adding, to the homogeneous solution, at least one MS2 (M is selected from the group consisting of Ge, Si, and Sn) and Li2S and then mixing; obtaining a precursor by removing the organic solution from the precipitate; and obtaining the LGPS-type solid electrolyte by heating the precursor at 200-700° C.

Abstract: The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, wherein these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li7La3Zr2O12.

Abstract: Aspects of the present disclosure involve various battery can designs. In general, the battery can design includes two fitted surfaces oriented opposite each other and seam welded together to form an enclosure in which a battery stack is located. To form the enclosure, the two fitted surfaces are welded together along the large perimeter. Other swelling-resisting advantages may also be achieved utilizing the battery can design described herein including, but not limited to, the ability to modify one or more can wall thicknesses to control a pressure applied to the battery stack by the can, overall reduction in wall thickness of the can through the use of stronger materials for the can surfaces, additional supports structures included within the can design, and/or bossing or other localized thinning of surfaces of the can.

Abstract: A lithium cobalt-based positive electrode active material is provided. The lithium cobalt-based positive electrode active material includes a core portion including a lithium cobalt-based oxide represented by Formula 1 and a shell portion including a lithium cobalt-based oxide represented by Formula 2, wherein the lithium cobalt-based positive electrode active material includes 2500 ppm or more, preferably 3000 ppm or more of a doping element M based on the total weight of the positive electrode active material. An inflection point does not appear in a voltage profile measured during charging/discharging a secondary battery including the lithium cobalt-based positive electrode active material.

Abstract: Disclosed is a rechargeable lithium battery including a positive electrode including a positive active material; a negative electrode including a negative active material; an electrolyte solution including a lithium salt and a non-aqueous organic solvent; and a separator between the positive and the negative electrodes, the separator including a porous substrate and a coating layer positioned on at least one side of the porous substrate. The negative active material includes a Si-based material; the non-aqueous organic solvent includes cyclic carbonate including ethylene carbonate, propylene carbonate, or combinations thereof, the cyclic carbonate being included in an amount of about 20 volume % to about 60 volume % based on the total amount of the non-aqueous organic solvent; and the coating layer includes a fluorine-based polymer, an inorganic compound, or combinations thereof. The rechargeable lithium battery has improved cycle-life and high temperature storage characteristics.

Abstract: Described herein are acidified metal oxide (“AMO”) materials useful in applications such as a battery electrode or photovoltaic component, in which the AMO material is used in conjunction with one or more acidic species. Advantageously, batteries constructed of AMO materials and incorporating acidic species, such as in the electrode or electrolyte components of the battery exhibit improved capacity as compared to a corresponding battery lacking the acidic species.

Abstract: The present invention relates to a method of making of hydrocarbon soluble metal composition comprising of one or more metals of group VIB of the periodic table, wherein the metal having 4+ oxidation state predominantly forms highly active metal sulfide catalyst for hydro-conversion of heavy oil feedstocks in liquid phase. More particularly, present invention relates to a hydrocarbon soluble metal composition comprising of reaction products of a metal source, a lipophilic phenolic acid, a surfactant and an organophosphorus compound. The present invention also provides a one-pot process for preparation of the hydrocarbon soluble metal composition comprising reacting a metal source, a lipophilic phenolic acid, a surfactant, an organophosphorus compound and water to obtain a reaction product and drying the reaction product to obtain the hydrocarbon soluble metal composition.

Abstract: To provide a separator which has a combination of a preferable air permeability enabling high prevention of internal short circuit and a high retention rate of such an air permeability in an electrolytic solution, and has more improved uniformity of the air permeability. A separator comprising a porous sheet and cellulose nanofibers, wherein the porous sheet comprises a binder component having the SP value of 11 to 16 (cal/cm3)1/2, and the porous sheet has the cellulose nanofibers at the inside and on the surface thereof, and wherein the cellulose nanofibers are combined with the porous sheet by fusion of the binder component.

Abstract: Various implementations of a method of forming an electrochemical cell include providing a first electrode, a second electrode, a separator between the first and second electrodes, and an electrolyte in a cell container. The first electrode can include silicon-dominant electrochemically active material. The silicon-dominant electrochemically active material can include greater than 50% silicon by weight. The method can also include exposing at least a part of the electrochemical cell to CO2, and forming a solid electrolyte interphase (SEI) layer on the first electrode using the CO2.

Abstract: A method of preparing a positive electrode active material for a secondary battery is provided, which includes preparing a lithium composite transition metal oxide, and mixing the lithium composite transition metal oxide and a metal borate compound and performing a heat treatment to form a coating portion on surfaces of particles of the lithium composite transition metal oxide. The positive electrode active material prepared includes lithium composite transition metal oxide particles, and a coating portion formed on surfaces of the lithium composite transition metal oxide particles, wherein the coating portion includes lithium (Li)-metal borate.

Abstract: The present invention relates to an electrode active material, a method for manufacturing the same, and a lithium secondary battery comprising the same. A method for producing carbide using bean curd or waste bean curd according to an embodiment of the present invention comprises the steps of: drying bean curd or waste bean curd; thermally treating the dried bean curd or waste bean curd under an air atmosphere; and carbonizing the thermally treated bean curd or waste bean curd under an inert gas atmosphere.

Abstract: Electrolytes and electrolyte additives for energy storage devices comprising a sulfonate ester compound are disclosed. The energy storage device comprises a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode, a separator between the first electrode and the second electrode, an electrolyte, and at least one electrolyte additive selected from a sulfonate ester compound.