Abstract: The invention refers to a method, and to a device to produce emulsions and particle suspensions by using electro-hydrodinamic forces and microfluidics This combined use allow the production of droplets with mean diameters which may be either smaller than those obtained in conventional microfluidic devices or larger than those obtained by electrospray, bridging the gap between the two methods acting independently.
Type:
Grant
Filed:
August 30, 2010
Date of Patent:
October 17, 2017
Assignees:
Georgia Tech Research Corporation, Universidad de Sevilla, Universidad de Málaga
Inventors:
Ignacio González-Loscertales, Venkata Ramana Gundabala, Alberto Fernandes-Nieves, Regina Gil Garcia
Abstract: A formulation for application to a substrate including a mixture of a liquid having a first viscosity and an amine-acid adduct. The mixture has a second viscosity greater than the first viscosity. The amine-acid adduct is evaporative and substantially completely removed from the mixture in a functionally dry state as applied as a deposit on the substrate. In particular, the general nature of the formulation is that of a mixture that includes a viscosity control agent, such as an amine-acid adduct that forms a carbamate, and the formulation is for use in coating or printing wherein the final coated product includes little or no viscosity control agent.
Abstract: A method is disclosed of preparing a liquid formulation for application as a deposit on a substrate. The method includes the steps of providing a liquid having a first viscosity in a non-evaporative state; and adding an amine-acid adduct to the liquid to form a mixture having a second viscosity greater than the first viscosity. The amine-acid adduct is evaporative such that the amine-acid adduct is substantially completely removed from the deposit in a functionally dry state.
Abstract: Various compositions, including particularly aerosol compositions containing fluorinated olefins, including particularly 2,3,3,3-tetraluorpropene (HFO-1234yf), in a variety of applications are disclosed.
Abstract: The invention provides a dispersion of zirconium oxide having a content as high as 20% by weight or more, but a low viscosity, and having a high transparency, which has a transmittance of 35% or more at a wave length of 400 nm, a transmittance of 95% or more at a wave length of 800 nm, and a viscosity of 20 mPa·s or less at a temperature of 25° C. Such a dispersion of zirconium oxide can be obtained by reacting a zirconium salt with an alkali in water to obtain a slurry of particles of zirconium oxide; filtering, washing, and repulping the slurry; adding an organic acid to the resulting slurry in an amount of one mole part or more per mole part of the zirconium in the slurry; hydrothermally treating the slurry at a temperature of 170° C. or higher; and washing and concentrating the resulting aqueous dispersion of particles of zirconium oxide.
Abstract: The present invention relates to the use of polyglycerol partial esters as defoamers, in particular in coating and paint applications, to defoamers comprising polyglycerol partial esters, and to corresponding polyglycerol partial esters.
Type:
Grant
Filed:
April 19, 2013
Date of Patent:
August 22, 2017
Assignee:
Evonik Deguesse GmbH
Inventors:
Margitta Nilewski, Philippe Favresse, André Scharf, Petra Gehrmann, Thomas Mettin, Michael Schwan, Oliver Springer, Tobias Wied
Abstract: A process is described for preparing stable suspensions of metal nanoparticles by means of a microwave-assisted metal nanoparticle synthesis undertaken in an aqueous environment at low temperature and at ambient pressure and atmosphere.
Type:
Grant
Filed:
March 1, 2010
Date of Patent:
August 15, 2017
Assignee:
COLOROBBIA ITALIA S.P.A.
Inventors:
Magda Blosi, Stefania Albonetti, Michele Dondi, Giovanni Baldi, Andrea Barzanti, Marco Bitossi
Abstract: The present invention provides microsphere manufacturing method and apparatus capable of stable obtaining microspheres of a desired size and reducing facility cost. According to the method and the apparatus, to manufacture microspheres made of a second liquid in a first liquid, the first liquid is supplied into a first channel to flow therein and the second liquid is supplied to an intermediate part of the first channel through a second channel. The supply velocities of the first and second liquids are set such that the second liquid closes the first channel and the closing part of the second liquid is cut off due to a pressure difference between an upstream side and a downstream side to form microspheres.
Type:
Grant
Filed:
May 28, 2009
Date of Patent:
July 25, 2017
Assignee:
Kobe Steel, Ltd.
Inventors:
Hiroyuki Ban, Koji Noishiki, Kazuto Okada, Seiichi Yamamoto
Abstract: Low molecular weight gelators, methods of making such gelators, organogels comprising such gelators and systems and methods of using such gelators for the containment and/or remediation of a release and/or spill of a crude oil, a petroleum product and/or a chemical is described. In exemplary systems and methods, gels and/or emulsions formed from the combination and/or contact of such gelators and at least one of a crude oil, a petroleum product and a chemical from a release and/or spill into the environment can be used to recover these oils or chemicals while allowing the gelators to be recovered and reused to clean up or contain additional crude oil, petroleum products or chemicals.
Type:
Grant
Filed:
August 26, 2011
Date of Patent:
July 18, 2017
Assignee:
GEORGETOWN UNIVERSITY
Inventors:
Richard G. Weiss, Ajaya Mallia Viswanatha Mallya
Abstract: Defoamer compositions are described and the use of defoamer compositions in paper and pulp mills is described, especially for use at the brown stock washing steps in a pulp mill. The defoamer composition comprises: a) about 20 wt % to about 90 wt % of at least one organophosphorous component (e.g., compound or polymer, n-tributoxyethyl phosphate); b) about 1 wt % to about 10 wt % of at least one silane treated silica; c) about 0.5 wt % to about 10 wt % of at least one surfactant that is anionic or non-ionic; and d) optionally, water or an aqueous liquid.
Type:
Grant
Filed:
March 19, 2015
Date of Patent:
June 13, 2017
Assignee:
Buckman Laboratories International, Inc.
Abstract: An improved process for producing substantially non-polar doped or un-doped cerium oxide nanoparticle dispersions is disclosed. The cerium-containing oxide nanoparticles of an aqueous colloid are transferred to a substantially non-polar liquid comprising one or more amphiphilic materials, one or more low-polarity solvents, and one or more glycol ether promoter materials. The transfer is achieved by mixing the aqueous and substantially non-polar materials, forming an emulsion, followed by a phase separation into a remnant polar solution phase and a substantially non-polar organic colloid phase. The organic colloid phase is then collected. The promoter functions to speed the transfer of nanoparticles to the low-polarity phase. The promoter accelerates the phase separation, and also provides improved colloidal stability of the final substantially non-polar colloidal dispersion.
Type:
Grant
Filed:
January 30, 2013
Date of Patent:
June 6, 2017
Assignee:
CERION, LLC
Inventors:
Gary Robert Prok, Stephen Charles Williams
Abstract: A method for breaking emulsions includes applying a polymer mixture to an emulsion. The emulsion can be energized, such as through centrifugation or vibration. In particular, the polymer mixture can be in liquid form. The polymer mixture includes first and second liquid polymer, the second liquid polymer being less hydrophilic than the first liquid polymer. Example polymer useful as the first or second liquid polymers includes polyether. In a water-in-oil emulsion, the less hydrophilic polymer can preferentially reside within the oil phase.
Abstract: A cross-linked phenolic resin demulsifier may be added to a water-in-oil emulsion having at least one foulant therein. The demulsifier may separate at least a portion of the foulant(s) from the water-in-oil emulsion, and the separated foulant(s) may be removed from the water-in-oil emulsion. In a non-limiting embodiment, the amount of the demulsifier present in the water-in-oil emulsion may range from about 0.1 ppm to about 50,000 ppm.
Type:
Grant
Filed:
February 10, 2014
Date of Patent:
May 30, 2017
Assignee:
Baker Hughes Incorporated
Inventors:
Jianzhong Yang, Jack B. Ward, Trevor Cappel
Abstract: The invention relates to oil-in-water emulsions based on fatty alcohols and mono- or diesters of glycerol and the use thereof as antifoams or deaerators for aqueous compositions. The oil phase of the emulsions according to the invention consists to at least 95% by weight of the following constituents: a) 40 to 95% by weight, based on the total weight of the oil phase, of a mixture of at least two alcohols as component A, consisting of: a1) at least one alkanol having 12 to 30 carbon atoms as component A1, a2) at least one mono- or diester of glycerol with at least one fatty acid having 14 to 24 carbon atoms as component A2; b) 0.1 to 10% by weight, based on the total weight of the oil phase, of at least one further component B, which is selected from esters of C12-C36-alkanecarboxylic acids with polyglycerol, amides of C12-C36-alkanecarboxylic acids with alkylenediamines or oligoalkyleneamines, and esters of C12-C36-alkanecarboxylic acids with C12-C36-alkanols, and mixtures thereof, c) 4.
Type:
Grant
Filed:
May 9, 2012
Date of Patent:
May 16, 2017
Assignee:
BASF SE
Inventors:
Claudius Kormann, Wolfgang Gaschler, Christian Holtze
Abstract: The present invention provides for a demulsifying composition comprising a blend of a) an emulsion; and b) a demulsifying-effective amount of a silicon containing co-polymer. The present invention also provides for a method for separating emulsions using the demulsifying composition discussed.
Type:
Grant
Filed:
August 2, 2010
Date of Patent:
April 18, 2017
Assignee:
Momentive Performance Materials Inc.
Inventors:
Kalman Koczo, Benjamin Falk, Antonio Palumbo
Abstract: Disclosed is an emulsion formed using, as an emulsifier, 0.01 to 30 parts by weight of a perfluoroalkylethyl phosphonic acid salt represented by the general formula: CnF2n+1CH2CH2P(O)(OM1)(OM2) [III] (M1: a hydrogen atom, ammonium salt, or organic amine salt, M2: an ammonium salt or organic amine salt, n: 1 to 6), based on 100 parts by weight of a perfluoropolyether oil represented by the general formula: RfO(C3F6O)p(C2F4O)q(CF2O)rRf? [I] (Rf and Rf?: C1-C5 perfluoroalkyl groups, p+q+r: 2 to 200) or the general formula: F(CF2CF2CF2O)nCF2CF3 [II] (n: 2 to 100), or a perfluorocarbon compound. In spite of using, as an emulsifier, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, the emulsion exhibits excellent emulsification stability, and therefore can be effectively used as a surface-treating agent, such as a mold-releasing agent.
Abstract: A method for producing a high purity silica sol is provided. This method has enabled use of water glass for the starting material, and the resulting silica sol has a reduced metal impurity Cu and Ni content compared to conventional methods. The method comprises (1) ultrafiltration of an aqueous solution of an alkali silicate; (2) ion exchange process for removal of at least a part of cationic components in the purified aqueous solution of an alkali silicate; (3) another ion exchange process using a chelating ion exchange resin to obtain high purity silicate solution; and (4) adjustment of a part of the high purity silicate solution (seed solution) to alkaline pH and mixing of this solution with another part of the solution (feed solution) to produce a high purity silica sol having a Cu concentration and a Ni concentration (in relation to the dry silica) of up to 50 ppb.
Abstract: Collectors for froth flotation including oxidized fatty acid compositions and oxidized and maleated compositions. In particular, use of oxidized tall oil compositions and oxidized and maleated fatty acid compositions are disclosed.
Abstract: A method of forming a colloidal dispersion includes providing a first continuous material flow, providing a second continuous material flow, combining the first and second continuous material flows, and moving a continuous flow of a colloidal dispersion in a direction downstream of the first and second continuous flows. The first continuous material flow includes one or more of a diluent (e.g., deionized water), a base, and an acid, and the second continuous material flow includes an abrasive particle solution. The first and second material flows are combined with a Reynolds number greater than about 4400 and less than about 25000 (e.g., about 7400 to about 25000). The colloidal dispersion includes the diluent, the base, the acid, and abrasive particles from the abrasive particle solution.
Type:
Grant
Filed:
September 14, 2012
Date of Patent:
January 31, 2017
Assignee:
Fujifilm Planar Solutions, LLC
Inventors:
Saeed H. Mohseni, Elizabeth K. Gramm, Deepak Mahulikar
Abstract: Provided is a water-swelling layered double hydroxide characterized by having an organic sulfonic acid anion (A?) between layers, and by being represented by the below mentioned general formula (1): QZR(OH)2(Z+1)(A?)(1?y)(Xn?)y/n.mH2O . . . (1). Here, Q is a divalent metal, R is a trivalent metal, A? is an organic sulfonic acid anion, m is a real number greater than 0, and z is in the range of 1.8?z?4.2. Xn? is the n-valent anion remaining without A? substitution, n is 1 or 2, y represents the remaining portion of Xn?, and 0?y<0.4.
Type:
Grant
Filed:
January 18, 2012
Date of Patent:
January 17, 2017
Assignee:
NATIONAL INSTITUTE FOR MATERIALS SCIENCE