Patents Examined by David Buttner
  • Patent number: 9643057
    Abstract: The present invention relates to compositions for golf equipment that can be applied as a thin paint layer to block oxygen and moisture from underlying structural layers. The compositions include a polymer component present in a resin system, a stabilizing component, and porous particles.
    Type: Grant
    Filed: March 4, 2016
    Date of Patent: May 9, 2017
    Assignee: Acushnet Company
    Inventors: Derek A. Ladd, Nicholas M. Nardacci, Edmund A. Hebert
  • Patent number: 9637625
    Abstract: A golf ball material includes (A) one, two or more resin ingredients selected from among olefin-unsaturated carboxylic acid random copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester random copolymers, and metal ion neutralization products of these copolymers, (B) one two or more resin ingredients selected from among polyethylenes, ethylene-vinyl acetate copolymers and polyesters, and (C) the specific agent for compatibilizing components (A) and (B).
    Type: Grant
    Filed: May 18, 2015
    Date of Patent: May 2, 2017
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Atsushi Nanba, Takanori Tago
  • Patent number: 9617415
    Abstract: A blend comprising from 50 to 95 percent by weight polycarbonate; and from 5 to 50 percent by weight modified methyl methacrylate polymer, wherein the modified methyl methacrylate polymer is selected from the group consisting of modified methyl methacrylate homopolymer, modified methyl methacrylate copolymers, and combinations thereof; wherein the modified methyl methacrylate polymer has one or more end groups provided by reaction with one or more chain transfer agents selected from the group consisting of mercapto esters, cycloalkyl and substituted cycloalkyl thiols, hydroxyl thiols, aryl and substituted aryl thiols, and aminoalkyl thiols, wherein the modified methyl methacrylate polymer has a Mw from 5,000 to 100,000 g/mole; and wherein the blend exhibits a pencil hardness equal to or greater than F measured according to ASTM D3363-05 is provided. A method for preparing a polycarbonate/modified methyl methacrylate blend is also provided.
    Type: Grant
    Filed: March 5, 2013
    Date of Patent: April 11, 2017
    Assignee: Rohm and Haas Company
    Inventors: Veera G. Nelliappan, Eric G. Lundquist, Yannick Saint-Gerard
  • Patent number: 9610477
    Abstract: Golf ball comprising at least one layer having a Shore D material hardness of from about 10 to about 55 and consisting of a millable polyurethane rubber composition comprising rubber consisting of: at least one polyether-based millable polyurethane rubber; at least one polyester-based millable polyurethane rubber; at least one polycaprolactone-based millable polyurethane rubber; or combinations thereof; wherein the millable polyurethane rubber composition is vulcanized. The rubber may be mixed/compounded with additional non-rubber ingredients such as at least one cross linking agent, peroxide initiator, filler, antioxidant, processing agent, light stabilizer, colorant, adhesion promotor, isocyanate and/or polyol, or combinations thereof. The at least one layer may be a cover layer, with a second layer, formed from at least one of a thermoset urethane or a thermoplastic material, being adjacent to an inner surface of the cover layer and meanwhile disposed about a polybutadiene-containing core.
    Type: Grant
    Filed: June 26, 2015
    Date of Patent: April 4, 2017
    Assignee: Acushnet Company
    Inventors: Mark L. Binette, Shawn Ricci, Michael Michalewich, Douglas S. Goguen, Brian Comeau
  • Patent number: 9611386
    Abstract: Provided is a transparent polycarbonate composition that includes: (A) 5 to 95 wt % of biphenyl modified polycarbonate including a repeating unit represented by Chemical Formula 1, a repeating unit represented by Chemical Formula 2, and a repeating unit represented by Chemical Formula 3; and (B) 1 to 50 wt % of an acrylate-based copolymer including (B-1) a repeating unit derived from aromatic (meth)acrylate having a refractive index of 1.58 to 1.70 and (B-2) a repeating unit derived from a mono-functional unsaturated monomer.
    Type: Grant
    Filed: July 8, 2013
    Date of Patent: April 4, 2017
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Kee-Hae Kwon, O-Sung Kwon, In-Chol Kim, Joo-Hyun Jang, Chang-Min Hong
  • Patent number: 9604105
    Abstract: Multi-layer golf balls comprising a center, intermediate layer, and cover are disclosed. The center is formed from a highly-neutralized acid copolymer composition.
    Type: Grant
    Filed: October 5, 2015
    Date of Patent: March 28, 2017
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Derek A. Ladd
  • Patent number: 9605121
    Abstract: A film is obtained by forming a methacrylic resin composition comprising 100 parts by mass of a methacrylic resin (A) and preferably 1 to 10 parts by mass of a polycarbonate resin, the methacrylic resin (A) having a triad syndiotacticity (rr) of not less than 58%, a weight average molecular weight of 50000 to 150000, a content of fraction having a molecular weight of not less than 200000 of 0.1 to 10% by mass and a content of fraction having a molecular weight of less than 15000 of 0.2 to 5% by mass. A polarizer protective film comprising the above film is obtained.
    Type: Grant
    Filed: May 16, 2014
    Date of Patent: March 28, 2017
    Assignee: KURARAY Co., Ltd.
    Inventors: Toru Takahashi, Atsuhiro Nakahara, Hiroshi Ozawa, Toru Abe, Yusaku Nomoto
  • Patent number: 9598578
    Abstract: A polycarbonate composition comprises: a first poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein less than 0.5 mol % of the siloxane units are directly coupled to another siloxane unit; the first poly(carbonate-siloxane) copolymer comprising siloxane units with an average block length of about 10 to about 100, and a siloxane content from 5 wt % to 8 wt %; a second poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein less than 0.5 mol % of the siloxane units are directly coupled to another siloxane unit; the second poly(carbonate-siloxane) copolymer comprising siloxane units with an average block length of 10 to 100, a siloxane content from 10 wt % to 30 wt %, and wherein the weight ratio of the first poly(carbonate-siloxane) copolymer to the second poly(carbonate-siloxane) copolymer is 2 to 20; and optionally a bisphenol polycarbonate; wherein the polycarbonate composition has a total siloxane content of 2.
    Type: Grant
    Filed: November 17, 2015
    Date of Patent: March 21, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V
    Inventors: Ramon Groote, James Franklin Hoover, Robert Dirk Van De Grampel, Mark Adrianus Johannes Van Der Mee, Remco Wirtz, Jian Yang, Junhua Zhang
  • Patent number: 9598577
    Abstract: A polycarbonate composition comprises: a first poly(carbonate-siloxane) copolymer, comprising a polysiloxane block with an average block length of 10 to 100, and a siloxane content from 5 wt % to 10 wt %; and a second poly(carbonate-siloxane) copolymer comprising a polysiloxane block with an average block length of 10 to 100, and a siloxane content from 30 wt % to 60 wt %; wherein the weight ratio of the first poly(carbonate-siloxane) copolymer to the second poly(carbonate-siloxane) copolymer is greater than or equal to 2 to less than 8; and a bisphenol A homopolycarbonate, wherein the polycarbonate composition has a total siloxane content of 2.5 wt % to 10 wt % based on the total weight of the composition; and a molded part of 1 mm thickness has a haze of less than 10% as measured by HazeGard (ASTM D1003-00).
    Type: Grant
    Filed: November 17, 2015
    Date of Patent: March 21, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Ramon Groote, James Franklin Hoover, Robert Dirk Van De Grampel, Mark Adrianus Johannes Van Der Mee, Remco Wirtz, Jian Yang, Junhua Zhang
  • Patent number: 9598522
    Abstract: The present invention provides resin compositions for golf balls which have excellent flexibility, fluidity, and resilience, and golf balls formed from the resin compositions. The present invention relates to a resin composition for golf balls including a polymer that contains a diene polymer moiety and a carboxylic acid-based moiety wherein carboxyl groups derived from the carboxylic acid-based moiety are neutralized.
    Type: Grant
    Filed: December 24, 2014
    Date of Patent: March 21, 2017
    Assignee: DUNLOP SPORTS CO. LTD.
    Inventors: Kazuyoshi Shiga, Masanori Taguchi, Takahiro Shigemitsu
  • Patent number: 9593253
    Abstract: A golf ball resin composition includes (A) (I) an olefin-C3-8 ?,?-unsaturated carboxylic acid copolymer or a metal neutralization product thereof and/or (II) an olefin-C3-8 ?,?-unsaturated carboxylic acid-C3-8 ?,?-unsaturated carboxylic acid ester terpolymer or a metal neutralization product thereof; (B) isocyanuric acid or a haloisocyanuric acid; and (C) a fatty acid or a fatty acid metal salt. When this resin composition is used as a cover material, the paint film adhesion between the cover material and various types of paint, including urethane-based paints, is excellent, enabling various properties of the golf ball to be improved.
    Type: Grant
    Filed: October 29, 2015
    Date of Patent: March 14, 2017
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Atsushi Nanba, Takanori Tago
  • Patent number: 9586093
    Abstract: A golf ball that includes (a) a core comprising a center; (b) an outer cover layer; and (c) one or more intermediate layers; wherein at least one of the core or the intermediate layer comprises a composition that includes (i) at least one polyalkenamer and at least one ionomer. A method for making a golf ball comprising a core, one or more intermediate layers and an outer cover layer is also disclosed, wherein the method includes forming a blend comprising at least one polyalkenamer rubber and at least one ionomer; and injection molding the blend into a spherical mold to form the intermediate or outer cover layer.
    Type: Grant
    Filed: June 27, 2014
    Date of Patent: March 7, 2017
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 9580548
    Abstract: Disclosed herein are crosslinked polycarbonates, composition thereof and methods thereof. The cross-linked polycarbonates can be prepared from allyl or epoxy polycarbonates. Described herein is the formation of functionalized poly(carbonate) particles with an established intermolecular cross-linking process. Six types of ‘nanosponges’ were prepared with the differentiation in crosslinking density and crosslinking chemistry. The intermolecular chain cross-linking process was investigated via the epoxide amine reaction and the thiol-ene click reaction.
    Type: Grant
    Filed: May 8, 2013
    Date of Patent: February 28, 2017
    Assignee: Vanderbilt University
    Inventors: Eva M. Harth, David M. Stevens
  • Patent number: 9580559
    Abstract: Disclosed herein are polydiorganosiloxane-polycarbonate block copolymers having desirable optical properties, and methods of making such block copolymers. Also disclosed herein are analytical methods for evaluating hydroxyaryl end-capped polydialkylsiloxane monomers.
    Type: Grant
    Filed: October 2, 2014
    Date of Patent: February 28, 2017
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Niles Richard Rosenquist, Fabrizio Micciche, Jozua de Heer, Robert Dirk van de Grampel, James F. Hoover, Nathalie Gonzalez Vidal
  • Patent number: 9573021
    Abstract: An object of the present invention is to provide a golf ball excellent in shot feeling, flight distance and durability. The present invention provides a golf ball comprising a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a core rubber composition containing (a) a base rubber, (b) a co-crosslinking agent, (c) a crosslinking initiator, and (x) a crosslinked rubber powder; (x) the crosslinked rubber powder contains (x1) soft particles with a hardness difference (Hs?Hp)between a particle hardness (Hp) of the soft particles and a surface hardness (Hs) of the spherical core being 20 or more in JIS-C hardness, and a hardness difference (Hs5?Hp) between the particle hardness (Hp) of the soft particles and a hardness (Hs5) at 5 mm point inside the surface of the spherical core being 15 or more in JIS-C hardness; and the core rubber composition contains (x1) the soft particles in an amount of 1.0 mass % or more.
    Type: Grant
    Filed: March 30, 2015
    Date of Patent: February 21, 2017
    Assignee: DUNLOP SPORTS CO. LTD.
    Inventors: Ryota Sakamine, Katsumi Terakawa
  • Patent number: 9566476
    Abstract: An object of the present invention is to provide a golf ball excellent in flying performance, in particular, to provide a golf ball traveling a great flight distance. The present invention provides a golf ball having a spherical core and at least one cover layer covering the spherical core, wherein the spherical core is formed from a rubber composition containing (a) a base rubber, (b) an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, and (d) a carboxylic acid, provided that the rubber composition further contains (e) a metal compound in the case of containing only (b) the ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms as the co-crosslinking agent.
    Type: Grant
    Filed: December 2, 2011
    Date of Patent: February 14, 2017
    Assignee: DUNLOP SPORTS CO. LTD.
    Inventors: Chiemi Mikura, Kazuhisa Fushihara, Mikio Yamada, Shun Kurihara, Ayaka Shindo
  • Patent number: 9551946
    Abstract: A polycarbonate copolymer includes: a repeating unit represented by a formula (1) below; and a repeating unit represented by a formula (2) below, in which the repeating unit represented by the formula (1) is formed from a bischloroformate oligomer having an average number of monomer units n represented by a formula (100) below in a range from 0.1 to 1.3. In the formulae (100) and (1), Ar1 represents a group represented by a formula (3) below. In the formula (2), Ar2 represents a divalent aromatic group. In the formula (3) below, X1 represents a single bond or an oxygen atom. R11 each independently represents a methyl group or an ethyl group.
    Type: Grant
    Filed: May 22, 2014
    Date of Patent: January 24, 2017
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Kengo Hirata, Hironobu Morishita
  • Patent number: 9550095
    Abstract: Multi-piece golf balls having at least one layer made from a polyamide non-ionomeric composition are provided. The polyamide composition consists essentially of about 40 to about 99% by weight polyamide; about 1 to about 60% by weight of an acid anhydride-modified polyolefin; and about 1 to about 60% of a fatty acid additive selected from the group consisting of fatty acid salts, fatty acid amides, and mixtures thereof. The ball includes a core, preferably a dual core construction; and a cover of at least one layer. In another preferred construction, a multi-layered core containing an inner, intermediate, and outer core layer is made. For example, the intermediate core layer may be made of a rubber composition; and each of the inner core and outer core layers may be made of the polyamide composition. The resulting ball has high resiliency along with a soft feel.
    Type: Grant
    Filed: August 28, 2015
    Date of Patent: January 24, 2017
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Mark L. Binette, Brian Comeau, David A Bulpett, Robert Blink
  • Patent number: 9546245
    Abstract: This invention provides a chlorinated poly(propylene carbonate) and the preparation method thereof, the chlorinated poly(propylene carbonate) is as represented by formula (I). Compared to the prior poly(propylene carbonate)s, the chlorinated poly(propylene carbonate) has relatively stronger electronegativity due to the presence of chlorine atoms and the interaction of the chlorinated poly(propylene carbonate) with other polar materials can be enhanced, so that it can be widely used as a compatilizer, a binder, a paint, an ink, and the like. After the introduction of chlorine atoms, hydrogen bond interaction is generated within the chlorinated poly(propylene carbonate), so that its processability and mechanical properties are both improved. Furthermore, the chlorine atom may improve the flame retardancy of chlorinated poly(propylene carbonate) materials.
    Type: Grant
    Filed: April 14, 2015
    Date of Patent: January 17, 2017
    Assignee: Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
    Inventors: Wei Jiang, Guiyan Zhao, Lisong Dong, Jing Jin, Jie Cui
  • Patent number: 9545543
    Abstract: The invention provides a method of manufacturing a golf ball having a core and a cover of one or more layer over the core, wherein an outermost layer of the cover is molded of a thermoplastic material selected from the group consisting of polyurethane, polyurea and mixtures thereof. The method includes at least the following steps (1) and (2): (1) treating a surface of the cover with an isocyanate compound; and (2) washing off and physically removing excess isocyanate compound by blasting the cover surface with a specific substance at high pressure.
    Type: Grant
    Filed: December 23, 2015
    Date of Patent: January 17, 2017
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Katsunobu Mochizuki, Hiroyuki Nagasawa, Kanae Tajima, Masahiro Yamabe