Abstract: Stable electron acceptor compositions are composed of a plurality of pillared metal complexes disposed on a supporting substrate. At least one Group VIII metal at zero valence is entrapped within this matrix. The complexes comprise from one to about 100 units of the formula:--(Y.sup.1 O.sub.3 --Z--Y.sup.2 O.sub.3)Me.sup.1 --Y.sup.1 and Y.sup.2 being phosphorus or arsenic; Z being a divalent group which reversibly forms a stable reduced form and contains two conjugated cationic centers having a negative E.degree..sub.red value; and Me.sup.1 being a trivalent or tetravalent metal of Group III, IVA, or IVB having an atomic number of at least 21 or a lanthanide. The units are bound to the substrate through a divalent linking group. Counter anions balance the charge of Z. The compositions can be used in the decomposition of water to yield hydrogen gas, the sensing of oxygen, and as catalysts.
Type:
Grant
Filed:
August 9, 1993
Date of Patent:
March 19, 1996
Assignee:
The Trustees of Princeton University
Inventors:
Mark E. Thompson, Jonathan L. Snover, Lori A. Vermeulen
Abstract: The improved dielectric member for carrying electrostatic latent image comprises a support and an overlying dielectric layer, with a thickness of from 3 to 70 .mu.m, that is formed of an polysiloxane/amic acid copolymer. The dielectric member has a relative dielectric constant of 2.0 to 6.0, a surface hardness of 300 to 1,500 on the Vickers scale, and exhibits high reliability in operating characteristics. It can be produced by a process in which the dielectric layer is formed on the support by applying an inorganic polymer compound film-forming material onto the support, and heating the coated layer in vacuum to cure.
Abstract: A multi-layer composite made of at least one copolyamide protective layer, and at least one copolyamide barrier layer, with the protective layer placed such that it is between the barrier layer and a source of moisture. The protective copolyamide layer is composed of a partially aromatic, amorphous copolyamide of a specified composition, and the barrier layer is composed of a partially aromatic barrier copolyamide of a specified composition. This multi-layer composite is especially useful in reusable packaging systems, such as beverage bottles or containers of any kind.