Abstract: The present invention relates to a process for the production of a boron-containing zeolitic material having an MWW framework structure comprising YO2 and B2O3, wherein Y stands for a tetravalent element, wherein said process comprises (a) providing a mixture comprising one or more sources for YO2, one or more sources for B2O3, one or more organotemplates, and seed crystals, (b) crystallizing the mixture obtained in (a) for obtaining a layered precursor of the boron-containing MWW-type zeolitic material, (c) calcining the layered precursor obtained in (b) for obtaining the boron-containing zeolitic material having an MWW framework structure, wherein the one or more organotemplates have the formula (I) R1R2R3N??(I) wherein R1 is (C5-C8)cycloalkyl, and wherein R2 and R3 are independently from each other H or alkyl, as well as to a synthetic boron-containing zeolite which is obtainable and/or obtained according to the inventive process as well as to its use.
Type:
Grant
Filed:
November 28, 2018
Date of Patent:
October 6, 2020
Assignee:
BASF SE
Inventors:
Stefan Maurer, Andrei-Nicolae Parvulescu, Ulrich Mueller, Xiangju Meng, Feng-Shou Xiao, Yeqing Wang
Abstract: Disclosed in certain embodiments are ZSM-5 zeolite microspheres. The ZSM-5 zeolite microspheres may contain substantially no clay or calcined clay material. The ZSM-5 zeolite microspheres may have a ZSM-5 zeolite content of at least 70 wt. %. Disclosed in certain embodiments is a method of forming ZSM-5 zeolite microspheres including treating microspheres with at least one alkali solution.
Type:
Grant
Filed:
January 17, 2019
Date of Patent:
September 29, 2020
Assignee:
BASF Corporation
Inventors:
Xingtao Gao, Christopher R. Castellano, Brendan Patrick Dowd
Abstract: Disclosed are method for synthesizing zeolites by using structure directing agent having benzyl groups and zeolites synthesized therefrom. A zeolite having various effects can be produced by using a material including a structure directing agent containing various benzyl groups, and raw material with various SiO2/Al2O3 molar ratios as alumina and silica source.
Type:
Grant
Filed:
November 27, 2017
Date of Patent:
September 22, 2020
Assignees:
INDUSTRY FOUNDATION OF CHONNAM NATIONAL UNIVERSITY, KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION
Inventors:
Sung June Cho, Kwan Young Lee, Soon Hee Park, Seung Gwan Lee
Abstract: According to one or more embodiments, a nano-sized, mesoporous zeolite particle may include a microporous framework comprising a plurality of micropores having diameters of less than or equal to 2 nm and a BEA framework type. The nano-sized, mesoporous zeolite particle may also include a plurality of mesopores having diameters of greater than 2 nm and less than or equal to 50 nm. The zeolite particles may be integrated into hydrocracking catalysts and utilized for the cracking of heavy oils in a pretreatment process.
Abstract: The invention provides methods and compositions for precursors and for the synthesis of zeolites. The invention makes use of intimately homogeneous precursors which avoid the formation of a difficult to work with gel stage in zeolite formation. This allows for the synthesis of zeolite in a much shorter period of time and with much lower amounts of structure directing agents.
Type:
Grant
Filed:
August 2, 2019
Date of Patent:
September 15, 2020
Assignee:
Ecolab USA Inc.
Inventors:
Francois Batllo, Wenyong Lin, Yulia Tataurova, George Salomon, Shiby John
Abstract: The present invention provides for a process for the production of an aluminosilicate zeolite from fly ash, and in particular but not exclusively, to a process for producing a high silica content zeolite from fly ash without the addition of an external silica source, such as sodium silicate.
Abstract: Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.
Type:
Grant
Filed:
December 9, 2019
Date of Patent:
September 8, 2020
Assignee:
Johnson Matthey Public Limited Company
Inventors:
Hai-Ying Chen, Joseph Fedeyko, Raul Lobo, Nicholas McNamara, Trong Pham
Abstract: The present invention provides an amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside and a production method thereof. The production method comprises: dispersing the ZSM-5 spherical nano-molecular sieve into toluene, adding thereto an organosilane containing a hydrophilic group and reacting at 40-80° C. for 2-16 h, to obtain a molecular sieve containing a hydrophilic group; placing the molecular sieve containing a hydrophilic group in an aqueous solution of sodium hydroxide and reacting at 50-90° C. for 10-50 min, to obtain a molecular sieve containing a hydrophilic group on the outside; dispersing the molecular sieve containing a hydrophilic group on the outside into toluene, adding thereto an organosilane containing a lipophilic group and reacting at 40-80° C. for 2-12 h, to obtain the amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside.
Abstract: Zeolites, improved methods for their synthesis, and catalysts, systems, and methods of using these zeolites as catalysts are described. The method of synthesis of the zeolites includes forming a mixture including a zeolitic precursor material and a structure directing agent and subjecting the mixture to high shear processing conditions.
Type:
Grant
Filed:
March 18, 2016
Date of Patent:
August 25, 2020
Assignee:
BASF Corporation
Inventors:
Ivan Petrovic, Ahmad Moini, Bettina Zoellner, Christian Holtze
Abstract: Chabazite zeolites have a problem of low hydrothermal resistance. By steam treating a chabazite zeolite having a silica-alumina ratio and a crystallinity that are within certain ranges, a chabazite zeolite having a high crystallinity and a high hydrothermal resistance can be obtained.
Abstract: Surface treatment compositions and their methods of preparation. Such surface treatment compositions can comprise a solid cross-linking agent and a water-soluble polymer. Such solid cross-linking agent can include a plurality of dialdehyde residues, and the water-soluble polymer can include a plurality of pendant groups capable of covalently bonding with the solid cross-linking agent. The surface treatment compositions can further comprise a fibrous material. Applications for such surface treatment compositions include soil erosion prevention, dust control, and landfill cover.
Abstract: A process for converting a feedstock comprising an organic compound to a conversion product by contacting said feedstock at organic compound conversion conditions with a catalyst comprising a mordenite zeolite having a mesoporous surface area of greater than 30 m2/g and an average primary crystal size as measured by TEM of less than 80 nm.
Type:
Grant
Filed:
May 21, 2018
Date of Patent:
August 18, 2020
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Wenyih F. Lai, Nicholas S. Rollman, Guang Cao
Abstract: An incipient wetness impregnation method for preparing a tin-containing zeolitic material having framework type BEA, a novel tin-containing zeolitic material having framework type BEA and its use.
Type:
Grant
Filed:
December 7, 2016
Date of Patent:
August 11, 2020
Assignee:
BASF SE
Inventors:
Nicolas Vautravers, Joaquim Henrique Teles, Ralf Pelzer, Daniel Schneider, Florian Garlichs, Andreas Keller, Andrei-Nicolae Parvulescu, Ulrich Müller, Sumana Roy
Abstract: Provided are a novel form of AEI zeolite, a novel synthesis technique for producing pure phase AEI zeolite, a catalyst comprising the AEI zeolite in combination with a metal, and methods of using the same.
Type:
Grant
Filed:
September 28, 2017
Date of Patent:
August 11, 2020
Assignee:
Johnson Matthey Public Limited Company
Inventors:
Hai-Ying Chen, Joseph Fedeyko, Raul Lobo, Trong Pham, Sanyuan Yang
Abstract: The present invention relates to a molecular sieve, particularly to an ultra-macroporous molecular sieve. The present invention also relates to a process for the preparation of the molecular sieve and to its application as an adsorbent, a catalyst, or the like. The molecular sieve has a unique X-ray diffraction pattern and a unique crystal particle morphology. The molecular sieve can be produced by using a compound represented by the following formula (I), wherein the definition of each group and value is the same as that provided in the specification, as an organic template. The molecular sieve is capable of adsorbing more/larger molecules, thereby exhibiting excellent adsorptive/catalytic properties.
Type:
Grant
Filed:
April 26, 2017
Date of Patent:
August 11, 2020
Assignees:
CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
Abstract: A method is provided for synthesizing a zeolite of the SSZ-26/33 family of zeolites using 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane as a structure directing agent.
Abstract: A method of forming composite zeolite catalyst particles includes combining a silicon source, an aqueous organic structure directing agent having a polyquaternary ammonium compound, water and an aluminum source to form a catalyst gel. The method also includes heating the catalyst gel to form the composite zeolite catalyst particle having an intergrowth region with a mixture of both Mordenite crystals and ZSM-5 crystals. An associated method of making xylene includes feeding heavy reformate to a reactor, the reactor containing the composite zeolite catalyst particles, and producing xylene by simultaneously performing dealkylation and transalkylation of the heavy reformate in the reactor, where each composite zeolite catalyst particle is able to catalyze both the dealkylation and transalkylation reactions.
Type:
Grant
Filed:
March 12, 2019
Date of Patent:
July 28, 2020
Assignees:
Saudi Arabian Oil Company, Universitat Politecnica De Valencia, Consejo Superior De Investigaciones Cientificas
Inventors:
Raed Hasan Abudawoud, Avelino Corma Canos, M. Teresa Portilla Ovejero, Vicente J. Margarit Benavent, M. Teresa Navarro Villalba, M. Cristina Martinez Sanchez, Ibrahim M. Al-Zahrani
Abstract: JMZ-5, an aluminosilicate having an SZR framework type and a sea-urchin type morphology is described. A calcined product, JMZ-5C, formed from JMZ-5 is also described. JMZ-6, an aluminosilicate having an SZR framework type and a needle, aggregate morphology is described. A calcined product, JMZ-6C, formed from JMZ-6 is also described. Methods of preparing these zeolites and their metal-containing calcined counterparts are described along with methods of using these zeolites and their metal containing calcined counterparts in treating exhaust gases.
Type:
Grant
Filed:
August 15, 2019
Date of Patent:
July 28, 2020
Assignee:
Johnson Matthey Public Limited Company
Inventors:
Hai-Ying Chen, Joseph Fedeyko, Raul Lobo, Jelvehnaz Mirzababaei
Abstract: A method of forming a composite zeolite catalyst includes combining a silicon source and an aqueous organic structure directing agent having a polyamino cation compound to form a silica intermediary gel, introducing an aluminum precursor to the silica intermediary gel to form a catalyst precursor gel, evaporating water in the catalyst precursor gel to form a catalyst gel, and heating the catalyst gel to form a composite zeolite catalyst particle having an intergrowth region with a mixture of both Beta crystals and ZSM-5 crystals. An associated method of making xylene includes feeding heavy reformate to a reactor, the reactor containing the composite zeolite catalyst, and producing xylene by simultaneously performing dealkylation and transalkylation of the heavy reformate in the reactor, where each composite zeolite catalyst particle is able to catalyze both the dealkylation and transalkylation reactions.
Type:
Grant
Filed:
March 12, 2019
Date of Patent:
July 28, 2020
Assignees:
Saudi Arabian Oil Company, Universitat Politecnica De Valencia, Consejo Superior De Investigaciones Cientificas
Inventors:
Mohamed Elanany, Raed Abudawoud, Avelino Corma Canos, M. Teresa Portilla Ovejero, Vicente J. Margarit Benavent, M. Teresa Navarro Villalba, M. Cristina Martinez Sanchez, Ibrahim M. Al-Zahrani, Khalid A. Al-Majnouni