Patents Examined by Derek Mueller
  • Patent number: 9765260
    Abstract: Disclosed is a process for extracting an oil composition from oil sand. The extraction process is carried out using a fluidizing medium to fluidize oil sand particles within a contact zone in which the fluidizing medium contacts the oil sand and maintains the oil sand in the fluidized state. At least a majority of the fluidizing medium is in a vapor or supercritical state within the contact zone.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: September 19, 2017
    Assignee: Epic Oil Extractors, LLC
    Inventors: Richard D. Jordan, Richard H. Schlosberg
  • Patent number: 9737881
    Abstract: A method of producing a regenerated hydrotreating catalyst, including a first step of preparing a hydrotreating catalyst that has been used for hydrotreatment of a petroleum fraction and has a metal element selected from Group 6 elements of the periodic table; a second step of performing regeneration treatment for part of the catalyst prepared in the first step, then performing X-ray absorption fine structure analysis for the catalyst after the regeneration treatment, and obtaining regeneration treatment conditions in which a ratio IS/IO of a peak intensity IS of a peak attributed to a bond between the metal element and a sulfur atom to a peak intensity IO of a peak attributed to a bond between the metal element and an oxygen atom is in the range of 0.1 to 0.3 in a radial distribution curve obtained from an extended X-ray absorption fine structure spectrum.
    Type: Grant
    Filed: September 14, 2011
    Date of Patent: August 22, 2017
    Assignee: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Yoshimu Iwanami, Takashi Sano, Tomohiro Konishi, Makoto Nakamura, Souichirou Konno
  • Patent number: 9732288
    Abstract: A process and apparatus are disclosed for hydrocracking hydrocarbon feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The hydrocracking unit and the hydrotreating unit share the same recycle gas compressor. A make-up hydrogen stream may also be compressed in the recycle gas compressor. A warm separator separates recycle gas and hydrocarbons from diesel in the hydrotreating effluent, so fraction of the diesel is relatively simple. The warm separator also keeps the diesel product separate from the more sulfurous diesel in the hydrocracking effluent, and still retains heat needed for fractionation of lighter components from the low sulfur diesel product.
    Type: Grant
    Filed: June 4, 2014
    Date of Patent: August 15, 2017
    Assignee: UOP LLC
    Inventors: Paul R. Zimmerman, Andrew P. Wieber
  • Patent number: 9725658
    Abstract: The present invention provides a method for processing low-grade heavy oil, comprising: providing a riser-bed reactor; preheating the low-grade heavy oil and injecting it into the riser reactor to react with solid catalyst particles at the temperature of 550-610° C.; oil-gas, after reacting with the solid catalyst particles in the riser reactor, being introduced into the fluidized bed reactor to continue to react at temperature of 440-520° C. and weight hourly space velocity of 0.5-5 h?1; and the oil-gas, after reacting in the fluidized bed reactor, being separated from coked solid catalyst particles carried therein, and the separated oil-gas being introduced into a fractionation system. The method can effectively remove carbon residues, heavy metals, asphaltenes and other impurities from the low-grade heavy oil, and obtain high liquid product yield in a simple process.
    Type: Grant
    Filed: June 4, 2014
    Date of Patent: August 8, 2017
    Assignees: CHINA UNIVERSITY OF PETROLEUM-BEIJING, CHINA NATIONAL PETROLEUM CORPORATION
    Inventors: Gang Wang, Jinsen Gao, Chunming Xu, Baojian Shen, Hongliang Wang
  • Patent number: 9718050
    Abstract: The invention relates to a catalyst comprising at least one metal selected from the group formed by metals of group VIB and of group VIII of the periodic table, used alone or as a mixture, and a support comprising at least one zeolite NU-86, at least one zeolite Y and at least one porous mineral matrix containing at least aluminum and/or at least silicon. The invention also relates to a process for hydrocracking of hydrocarbon feeds employing said catalyst.
    Type: Grant
    Filed: November 23, 2012
    Date of Patent: August 1, 2017
    Assignee: IFP ENERGIES NOUVELLES
    Inventors: Audrey Bonduelle, Emmanuelle Guillon, Magalie Roy-Auberger
  • Patent number: 9708553
    Abstract: The present invention relates to a process for handling product fluid streams which are obtained in the catalytic hydrogenation of liquid feeds in laboratory catalysis apparatuses. The liquid feeds are preferably hydrocarbons comprising sulfur- and nitrogen-comprising compounds as impurities. The hydrogenation serves to convert the impurities into hydrogen sulfide and ammonia which in this form can be readily separated off from the other constituents of the liquid feed. The product fluid streams are contacted with an inert gas stream, with the flow rate of the inert gas being a multiple of the flow rate of the product fluid stream. The formation of deposits in lines of the region on the outlet side of the reaction space can be effectively prevented by means of the process of the invention.
    Type: Grant
    Filed: July 30, 2012
    Date of Patent: July 18, 2017
    Assignee: hte GmbH the high throughput experimentation company
    Inventors: Josef Find, Alfred Haas, Armin Brenner
  • Patent number: 9688925
    Abstract: Systems and methods are provided for dewaxing a distillate fuel oil by subjecting an at least partially hydroprocessed distillate fuel oil to cavitation to reduce the pour point, reduce the cloud point, reduce the cold filter plugging point, or a combination thereof of the distillate fuel oil.
    Type: Grant
    Filed: April 21, 2015
    Date of Patent: June 27, 2017
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Patrick Loring Hanks, William Ernest Lewis
  • Patent number: 9688920
    Abstract: A process to facilitate gravimetric separation of alkali metal salts, such as alkali metal sulfides and polysulfides, from alkali metal reacted hydrocarbons. The disclosed process is part of a method of upgrading a hydrocarbon feedstock by removing heteroatoms and/or one or more heavy metals from the hydrocarbon feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase containing alkali metal salts and reduced heavy metals, and an upgraded hydrocarbon feedstock. The inorganic phase may be gravimetrically separated from the upgraded hydrocarbon feedstock after mixing at a temperature between about 350° C. to 400° C. for a time period between about 15 minutes and 2 hours.
    Type: Grant
    Filed: April 15, 2014
    Date of Patent: June 27, 2017
    Assignee: FIELD UPGRADING LIMITED
    Inventors: John Howard Gordon, Javier Alvare, Dennis Larsen, Jeff Killpack
  • Patent number: 9688923
    Abstract: Methods are provided for extracting heterocyclic compounds, organometallic compounds, and polynuclear aromatic hydrocarbons from a hydrocarbon feedstock such as crude oil or a crude fraction. The heterocyclic compounds and organometallic compounds are removed from the hydrocarbon feedstock through one or more successive extractions to form a first raffinate. The extractions use a first solvent system containing an ionic liquid formed from carbon dioxide and water. The polynuclear aromatic hydrocarbons are removed from the first raffinate using a second solvent system containing an aprotic solvent such as NMP, DMSO, aromatics, or combinations thereof. The extracted compounds remain chemically intact and may be fractionated for further applications. Further methods are provided for producing a hydrocarbon raffinate having reduced levels of heterocyclic compounds, organometallic compounds, and 2-4 cycle polynuclear aromatic hydrocarbons.
    Type: Grant
    Filed: June 10, 2014
    Date of Patent: June 27, 2017
    Assignee: Saudi Arabian Oil Company
    Inventors: Zaki Yusuf, Alberto Lozano Ballesteros
  • Patent number: 9683178
    Abstract: A method for processing an acidic hydrocarbon feed comprising a hydrocarbon material and an acidic constituent soluble in the feed is provided. The method may comprise contacting the feed under a first condition with an active agent having an initial solubility in the feed and the acidic constituent and providing a second condition wherein the active agent has a secondary solubility in the feed lesser than the initial solubility to form a separable enriched active agent phase. The acidic constituent solubility in the active agent may be greater than its solubility in the hydrocarbon material under both the first and second conditions such that the acidic constituent dissolves in the active agent. The acidic constituent solubility in the active agent under the second condition may be greater than its solubility in the active agent under the first condition.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: June 20, 2017
    Assignee: Suncor Energy Inc.
    Inventor: Richard A. McFarlane
  • Patent number: 9677012
    Abstract: A method for producing a lubricant base oil that has a predetermined boiling point range, the method including a first step of bringing a feedstock containing a first hydrocarbon oil having a boiling point in the above boiling point range and a second hydrocarbon oil having a lower boiling point than the boiling point range into contact with a hydroisomerization catalyst, wherein the catalyst contains a support that includes a zeolite having a one-dimensional porous structure including a 10-membered ring and a binder, and platinum and/or palladium supported on the support.
    Type: Grant
    Filed: March 29, 2013
    Date of Patent: June 13, 2017
    Assignee: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Marie Iwama, Kazuaki Hayasaka, Yoshiyuki Nagayasu
  • Patent number: 9677009
    Abstract: The present invention relates to a process for breaking of preferred, but not exclusive, oil-in-water emulsions (O/W) and water separation from crude oil emulsions using surfactants as demulsifying agents derived from natural or synthetic amino acids, which are water soluble. The surfactants are of the methanesulfonate series of glycine ester derivatives with hydrocarbon chains, preferably between C10 and C16, at a concentration between 450 and 900 ppm, at a temperature range of 30 to 60° C. The removal of water from the crude oil by using natural or synthetic amino acid-based demulsifiers is highly efficient (about 80%) and complemented with the action of an electric field typically used in electrostatic separators in crude oil terminals ad oil refineries, increasing the efficiency of water separation substantially, and enabling the production of dehydrated crude oil for further processing.
    Type: Grant
    Filed: June 4, 2014
    Date of Patent: June 13, 2017
    Assignee: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Romeo Jesus Reyes Avila, Rafael Martinez Palou, Ricardo Ceron Camacho, Alba Adriana Vallejo Cardona, Rafael Rodriguez Dominguez, Benjamin Chavez Gomez, Jorge Arturo Aburto Anell
  • Patent number: 9670426
    Abstract: Methods and apparatuses for processing hydrocarbons are provided. In one embodiment, a method for processing a hydrocarbon stream including lighter hydrocarbons and heavier hydrocarbons includes hydrocracking the lighter hydrocarbons in a hydrocracking reactor. After hydrocracking the lighter hydrocarbons, the method hydrocracks the heavier hydrocarbons in the hydrocracking reactor. The method includes removing from the hydrocracking reactor a hydrocracking effluent comprising a mixture of components formed by hydrocracking the lighter hydrocarbons and hydrocracking the heavier hydrocarbons.
    Type: Grant
    Filed: June 11, 2014
    Date of Patent: June 6, 2017
    Assignee: UOP LLC
    Inventor: Scott M. Roney
  • Patent number: 9663724
    Abstract: Alumina/NiO/ZnO and Alumina/ZnO are synthesized via a novel modified hydrothermal method and investigated for the desulfurization activities. Sulfur compounds such as thiophene, benzothiophene (BT) and dibenzothiophene (DBT) are tested for their removal from model diesel fuel. The prepared composite materials were examined by the means of N2-adsorption, X-ray diffraction and Fourier transform infrared spectroscopy.
    Type: Grant
    Filed: June 3, 2016
    Date of Patent: May 30, 2017
    Assignees: King Fahd University of Petroleum and Minerals, King Abdulaziz City for Science and Technology
    Inventors: Khalid R. Alhooshani, Abdullah A. Al Swat, Tawfik A. Saleh, Mohammad N. Siddiqui, Mohammed A. Gondal
  • Patent number: 9663731
    Abstract: Processes and apparatuses for producing aromatic compounds from a naphtha feed stream are provided herein. In an embodiment, a process for producing aromatic compounds includes heating the naphtha feed stream to produce a heated naphtha feed stream. The heated naphtha feed stream is reformed within a plurality of reforming stages that are arranged in series to produce a downstream product stream. The plurality of reforming stages is operated at ascending reaction temperatures. The naphtha feed stream is heated by transferring heat from the downstream product stream to the naphtha feed stream to produce the heated naphtha feed stream and a cooled downstream product stream.
    Type: Grant
    Filed: June 19, 2013
    Date of Patent: May 30, 2017
    Assignee: UOP LLC
    Inventors: David A. Wegerer, Keyur Y. Pandya
  • Patent number: 9657236
    Abstract: The present invention relates to a catalyst combination for hydrotreating raw oils and a process for hydrotreating raw oils with the catalyst combination. The catalyst combination comprises one or both of at least one hydrogenation protection catalyst I and at least one hydrogenation demetalling catalyst I; at least one hydrogenation demetalling catalyst II; and at least one hydrogenation treatment catalyst III.
    Type: Grant
    Filed: March 29, 2013
    Date of Patent: May 23, 2017
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PERTROLEUM PROCESSING, SINOPEC
    Inventors: Qinghe Yang, Dawei Hu, Shuling Sun, Jia Liu, Hong Nie, Xinqiang Zhao, Xuefen Liu, Dadong Li, Lishun Dai, Zhicai Shao, Tao Liu
  • Patent number: 9657233
    Abstract: Process for the fluidized-bed catalytic cracking of a weakly coking feedstock having a Conradson carbon residue equal to or less than 0.1% by weight and a hydrogen content equal to or greater than 12.7% by weight, comprising at least a step of cracking the feedstock, a step of separating/stripping the effluents from the coked catalyst particles and a step of regenerating said particles, the process being characterized in that at least one coking, carbonaceous and/or hydrocarbonaceous effluent having a content of aromatic compounds of greater than 50% by weight, comprising more than 20% by weight of polyaromatic compounds, is recycled to homogeneously distributed and weakly coked catalyst, before regeneration, in order to adjust the delta coke of the process.
    Type: Grant
    Filed: December 9, 2011
    Date of Patent: May 23, 2017
    Assignee: TOTAL RAFFINAGE FRANCE
    Inventors: Marc Bories, Patrick Leroy
  • Patent number: 9637686
    Abstract: Disclosed is a method for improving a heavy hydrocarbon, such as mined bitumen, to a lighter more fluid product and, more specifically, to a hydrocarbon product that is refinery-ready and that meets pipeline transport criteria without requiring the addition of diluent. The invention is suitable for enhancing recovery from mined Canadian bitumen, but has general application for processing any heavy hydrocarbon, converting the heavy hydrocarbon to a product that is more suitable for pipeline transport.
    Type: Grant
    Filed: April 17, 2014
    Date of Patent: May 2, 2017
    Assignee: CANADIAN NATURAL RESOURCES LIMITED
    Inventors: Darius Simon John Remesat, Alvaro Blanco
  • Patent number: 9623397
    Abstract: A system for processing hydrocarbon materials, comprising a hydrocarbon feedstock source; a process gas source; a waveguide; and a reaction tube structure. The process gas source comprises one or more sources of gases selected from the group consisting of helium, argon, krypton, neon, xenon, methane, propane, butane, ethane, acetylene, propylene, butylene, ethylene, carbon monoxide, carbon dioxide, water vapor, hydrogen, and nitrogen. The waveguide comprises a lateral portion comprising housing having a first end portion configured to be connected to a microwave generator, a closed opposite end portion, a primary axis extending from the first end portion to the second end portion, and a central portion having an opening, wherein the central portion has a depth that is smaller than a corresponding depth of the first end portion and the second end portion, and a coaxial portion having a first end portion connected to the opening and a lateral dimension that is perpendicular to the primary axis.
    Type: Grant
    Filed: June 1, 2015
    Date of Patent: April 18, 2017
    Assignee: H Quest Partners, LP
    Inventors: George L. Skoptsov, Alan A. Johnson
  • Patent number: 9617483
    Abstract: A quenching medium is delivered directly to selected regions or locations within a catalyst bed in a hydroprocessing reactor vessel in order to control the reactivity of a hydroprocess occurring in the selected regions or locations separately from other regions or locations. Temperature sensors for providing temperature indications and conduits for delivering the quench medium are distributed throughout the catalyst bed. One or more conduits can be selected for delivery of the quenching medium to selected regions or locations so that separate control of the level of reactivity in each of various regions or locations throughout the bed can be achieved.
    Type: Grant
    Filed: November 26, 2013
    Date of Patent: April 11, 2017
    Inventor: Jeffrey N. Daily