Abstract: The disclosure relates to a process to perform an endothermic steam reforming of hydrocarbons, said process comprising the steps of providing a fluidized bed reactor comprising at least two electrodes and a bed comprising particles, wherein the particles are put in a fluidized state to obtain a fluidized bed; heating the fluidized bed to a temperature ranging from 500° C. to 1200° C. by passing an electric current through the fluidized bed to conduct the endothermic reaction. The process is remarkable in that the particles of the bed comprise electrically conductive particles and particles of a catalytic composition, wherein at least 10 wt. % of the particles are electrically conductive particles and have a resistivity ranging from 0.001 to 500 Ohm·cm at 800° C. and in that the step of heating the fluidized bed is performed by passing an electric current through the fluidized bed.

Abstract: Provided herein are catalyst materials and processes for processing hydrocarbons. For example, doped ceria-supported metal catalysts are provided exhibiting good activity and stability for commercially relevant DRM process conditions including low temperature and long term operation.

Abstract: A method of making a multicomponent photocatalyst, includes inducing precipitation from a pre-cursor solution comprising a pre-cursor of a plasmonic material and a pre-cursor of a reactive component to form co-precipitated particles; collecting the co-precipitated particles; and annealing the co-precipitated particles to form the multicomponent photocatalyst comprising a reactive component optically, thermally, or electronically coupled to a plasmonic material.

Abstract: The present invention relates to a process for production of high yield of hydrogen by carrying out the dry reforming of the dry gas generated from the process itself by utilizing the same catalyst for cracking and producing high yield of light olefins such as ethylene, propylene and butylenes from residue feedstocks.

Abstract: A method for controlling a fuel reformation reaction in a fuel reformation reactor is provided. Furthermore, a non-transitory computer-readable storage medium is provided, which is configured to store a program for controlling a fuel reformation reaction in a fuel reformation reactor. In addition, a fuel reformation system for controlling a fuel reformation reaction is provided, which includes a fuel reformation reactor and a control unit.

Abstract: In one aspect, disclosed herein are devices comprising a disclosed hybrid microwave-thermal chemical reactor device. Also disclosed herein are methods of preparing hydrogen and a crystalline carbon material, such as a carbon nanotube, from methane using a hybrid heating comprising heating with both a thermal fluid and microwave irradiation of a catalyst. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

Abstract: A two-step thermochemical reactor and method are disclosed. The reactor includes a housing and a reactor cavity formed within, and surrounded by, thermal insulation within the housing. The reactor cavity includes at least one unit cell, each cell having an electric heat source and a reactive material. The reactor also includes a feedstock inlet and a product outlet in fluid communication with the reactor cavity. The reactor also includes a reducing configuration, with the inlet being closed and the electric heat source of each unit cell being driven to thermally reduce the reactive material at a first temperature, releasing oxygen into the cavity. The reactor also has a splitting configuration where the reactive material is at a second temperature that is lower than the first, the feedstock inlet open and introducing feedstock gas into the cavity to reoxidize the reactive material and split into a product gas.

Abstract: The present invention relates to a perovskite metal oxide catalyst substituted with metal ions for reducing carbon deposition, a method for producing the same, and a process for performing a methane reforming reaction using this catalyst. According to the present invention, a novel type of catalyst is produced in which Ni, iron or cobalt in ionic form is substituted at a portion of the Ti site (B-site) of SrTiO3, MgTiO3, CaTiO3 or BaTiO3, which is a multicomponent metal oxide having a perovskite (ABO3) structure. Then, various methane reforming reactions (e.g., steam-methane reforming (SMR), dry reforming of methane (DRM), catalytic partial oxidation of methane (CPOM), etc.) may be efficiently and economically performed using this catalyst. The nickel-substituted perovskite metal oxide catalyst according to the present invention has a structure in which Ni2+, Co2+, Fe2+, Co3+ or Fe3+ is substituted in the perovskite lattice structure.

Abstract: The present disclosure provides compositions including method of producing H2, variable volume reactors, methods of using variable volume reactors, and the like.

Abstract: Methods of converting a variety of fluorinated materials into anhydrous hydrogen fluoride are described. The methods include thermally decomposing the fluorinated materials into a gaseous effluent comprising hydrogen fluoride and carbon dioxide. This gaseous effluent is then treated with carbon at a temperature of at least 830° C., converting the carbon dioxide to carbon monoxide (CO) and producing a gaseous product comprising the hydrogen fluoride, which can be condensed to generate anhydrous hydrogen fluoride. These methods can also be used to convert water contained in the gaseous effluent into hydrogen.

Abstract: The present invention provides a catalyst composition comprising different metal oxides wherein the catalyst composition comprising Ce, Cr and Ni oxides and a process for preparation thereof. The catalyst composition is used for different reforming techniques for the production of syn gas (CO+H2) at the same time this material can be used in fuel cell as a anode for power generation as this synthesized material is having good thermal stability and can sustain various redox reaction cycles also.

Abstract: A novel NiFeAl-based catalytic material was developed for the conversion of methane, the main constituent of natural gas, to synthesis gas, which is a mixture of H2 and CO in a H2/CO molar ratio of 2, through partial oxidation by air at reasonable temperatures.

Abstract: The object of the present invention is to provide a silicone composition which provides a release coating having excellent adhesion to a substrate, in particular a plastic film substrate, such as a polyester film. Further, an object of the present invention is to provide a release sheet having a cured coating of the silicon composition. It is also an object of the present invention to provide a silicone composition which has improved storage stability and does not cause separation of the functional compound during long-term storage or transportation. The present invention provides a silicone composition comprising the following components (A) to (C): (A) an organopolysiloxane having at least two alkenyl groups each bonded to a silicon atom in a molecule, having a viscosity at 25 degrees C.

Abstract: A method for determining the lignin or lignin by-product content of a process stream includes measuring the fluorescence parameter of a fluorescence spectra of the process stream, comparing the measured fluorescence parameter with predetermined a fluorescence parameter of lignin or lignin by-product reference samples, determining the amount of lignin or lignin by-product based on the comparison with the reference samples. Lignin or lignin by-products can then be removed from a process stream by adding a sufficient amount of a compound suitable for precipitating the lignin or lignin by-product to the process stream, and removing the precipitated lignin or lignin by-product from the process stream.

Abstract: Systems and methods are provided for using a high heat capacity gas as at least a portion of the diluent during the regeneration step of a reverse flow reactor process. Instead of using nitrogen or air as the primary diluent gas, CO2 and/or H2O can be added as diluent gas for the regeneration step in the reaction cycle. Increasing the heat capacity of the diluent gas provides a reduction in the peak temperature within the reactor relative to the amount of fuel combusted during regeneration. This can allow for a reduction in the volume of diluent used during regeneration and/or an increase in the amount of fuel used. Reducing the volume of diluent can reduce the pressure drop during regeneration, which can provide a corresponding reduction in the amount of compression required for recycle of the diluent. Increasing the amount of fuel can allow for a corresponding increase in the amount of endothermic reaction performed during the reaction step.

Abstract: Chemical looping reform methods comprising heating an oxygen carrier in the presence of a catalyst and plasma radicals to react the oxygen carrier with a fuel to provide a reduced oxygen carrier; and contacting the reduced oxygen carrier with water or carbon dioxide to produce hydrogen or carbon monoxide, respectively, and regenerate the oxygen carrier. The chemical looping reform methods are carried out at low temperatures such as from 150° C. to 1000° C., preferably from 150° C. to 500° C. Catalyst used in the chemical looping reform methods include a sintered rare earth metal oxide oxygen carrier and perovskite. Methods of preparing the catalyst are also provided.

Abstract: The invention relates to a device for producing a dihydrogen gas including an enclosure, means for conveying the product into the enclosure, which comprise a screw mounted so as to rotate in the enclosure about a geometric axis of rotation, means for heating the screw by the Joule effect, and a unit for removing impurities present in the gas. The invention also relates to a method for manufacturing dihydrogen using such a device as well as to a use of the device for the treatment of a product such as CSR material or polymer material.

Abstract: Provided are a continuous crystal transformation and ion exchange device and process, belonging to the technical field of molecular sieve manufacturing. The continuous crystal transformation and ion exchange device comprises M+N reaction tanks which are in serial connection, wherein a feed opening of a latter reaction tank communicates with a discharge opening of a former reaction tank by means of a reaction solution circulation pipeline, and a discharge opening of an M+Nth reaction tank communicates with a feed opening of a first reaction tank by means of a reaction solution circulation pipeline. No more than M reaction tanks are used for a crystal transformation process, and no more than N reaction tanks are used for an ion exchange process. The method is used for preparing a finished zeolite molecular sieve product, and has the advantages of high exchange capacity, simple process, low cost and the like.

Abstract: Materials, kits, and methods are directed to controlling reactability of activated aluminum to produce hydrogen when exposed to water. For example, a moisture-stabilized material may be treatable with one or more additives to form a water-reactive source of hydrogen. The moisture-stabilized material may include a bulk volume including aluminum, at least one activation metal disposed along the aluminum within the bulk volume, the at least one activation metal more noble than the aluminum, and a salt along at least an outer surface of the bulk volume, the salt dissolvable in water to form an ion-containing solution at a rate faster than a reaction rate of water with the aluminum of the bulk volume.

Abstract: The present invention relates, in general, to systems and methods for generating hydrogen from ammonia on-board vehicles, where the produced hydrogen is used as fuel source for an internal combustion engine. The present invention utilizes an electric catalyst unit to initiate an ammonia cracking process on-board during a cold start of the internal combustion engine, where a heat exchange catalyst unit is utilized once exhaust gas from the internal combustion engine has been heated to a threshold temperature suitable to perform the ammonia cracking process.