Abstract: Disclosed is a polybenzoxazime precursor and a method of preparing the same. The polybenzoxazime precursor is used to prepare a hardened material having improved thermal characteristics, having high thermal and flame-retardant characteristics while maintaining its excellent electrical characteristics, or having high thermal and electrical characteristics, thus being available for use in a copper clad laminate, a semiconductor encapsulate, a printed circuit board, an adhesive, a paint, and a mold.
Type:
Grant
Filed:
June 30, 2015
Date of Patent:
April 23, 2019
Assignee:
KOLON INDUSTRIES, INC.
Inventors:
Hee Jin Cho, Do Kyung Sung, Ki Hyun Park, Sang Hun Park, Hyun Soo Kagn
Abstract: A light emitting device comprising a polymeric charge transfer layer, wherein the polymeric charge transfer layer is formed from a composition comprising a polymer, said polymer comprising one or more polymerized units derived from Structure A, and one or more polymerized units derived from Structure (B), each as follows: A) a monomer having the Structure (A), as defined herein: and B) a monomer that comprises one or more dienophile moieties.
Type:
Grant
Filed:
August 20, 2015
Date of Patent:
April 9, 2019
Assignees:
Dow Global Technologies LLC, Rohm and Haas Electronic Materials LLC
Inventors:
Liam P. Spencer, Liang Hong, Chun Liu, Minrong Zhu, Jichang Feng, Jing Jing Yan, Zhengming Tang, Shaoguang Feng, Peter Trefonas, III, David D. Devore, Nolan T. McDougal
Abstract: This disclosure provides fire retardant materials, including polymers that include at least one pyridinium salt moiety and at least one phosphine oxide moiety.
Type:
Grant
Filed:
August 28, 2015
Date of Patent:
March 26, 2019
Assignees:
THE BOARD OF REGENTS OF THE NEVADA SYSTEM OF HIGHER EDUCATION ON BEHALF OF THE UNIVERSITY OF NEVADA, LAS VEGAS, INNOSENSE LLC
Inventors:
Pradip K. Bhowmik, Kisholoy Goswami, Maksudul M. Alam, Haesook Han
Abstract: The invention relates to a production process for polyamines through condensation of aromatic amines with formaldehyde employing at least one solid zeolite catalyst partially or fully ion-exchanged to the protonic form which has been A) alkaline-treated, wherein the alkaline treatment is in case of BEA zeolites carried out in the presence of a pore-directing agent and in case of zeolites other than BEA zeolites in the presence or absence of a pore-directing agent, or B) acid-treated without any alkaline treatment preceding or following said acid treatment, wherein the acid treatment is effected with an organic acid with chelating function.
Type:
Grant
Filed:
July 2, 2015
Date of Patent:
March 26, 2019
Assignee:
COVESTRO DEUTSCHLAND AG
Inventors:
Jürgen Arras, Stefan Wershofen, Javier Pérez-Ramirez, Tobias Caesar Keller
Abstract: Alkylene oxide polymerizations are performed in the presence of a double metal cyanide polymerization catalyst and certain magnesium, Group 3-Group 15 metal or lanthanide series metal compounds. The presence of the magnesium, Group 3-Group 15 metal or lanthanide series metal compound provides several benefits including more rapid catalyst activation, faster polymerization rates and the reduction in the amount of ultra high molecular weight polymers that are formed. The catalyst mixture is unexpectedly useful in making polyethers having low equivalent weights.
Type:
Grant
Filed:
December 16, 2016
Date of Patent:
March 19, 2019
Assignee:
Dow Global Technologies LLC
Inventors:
David S. Laitar, David A. Babb, Carlos M. Villa, Richard Keaton, Jean-Paul Masy
Abstract: The invention provides a process for preparing bromine-containing polymers, comprising a Friedel-Crafts alkylation reaction of pentabromobenzyl halide with a polymer reactant which contains one or more six-membered aromatic ring(s) in its repeat unit, in the presence of at least one Friedel-Crafts catalyst. The so-formed bromine-containing polymers, having pendent —CH2C6Br5 groups attached to at least a portion of the six-membered aromatic rings of the polymer, with a carbon ring atom of said six-membered aromatic ring being bonded to the aliphatic carbon of said —CH2C6Br5 pendent group, are also provided. These bromine-containing polymers are useful as flame retarding agents.
Type:
Grant
Filed:
July 7, 2015
Date of Patent:
March 12, 2019
Assignee:
Bromine Compounds Ltd.
Inventors:
Mark Gelmont, Michael Yuzefovich, David Yoffe, Renata Yelizarov, Ron Frim, Lior Melamed
Abstract: A process for preparing polymeric, ionic compounds comprising imidazolium groups (polymeric, ionic imidazolium compounds for short) comprising reacting—an ?-dicarbonyl compound,—an aldehyde,—at least one amino compound having at least two primary amino groups (referred to as oligoamine),—if appropriate an amino compound having only one primary amino group (referred to as monoamine) and a—protic acid, wherein the molar ratio of the ?-dicarbonyl compound to the oligoamine is greater than 1.
Type:
Grant
Filed:
July 27, 2015
Date of Patent:
March 5, 2019
Assignee:
BASF SE
Inventors:
Jean-Pierre Berkan Lindner, Rupert Konradi, Till Gruendling, Sunghee Son, Sebastian Koltzenburg
Abstract: The present disclosure is directed, in part, to methods of synthesizing a poly(ethylene carbonate) polymer from the reaction of ethylene oxide (EO) and carbon dioxide (CO2) in the presence of a metal complex. The present disclosure also provides novel metal complexes. In one aspect, the metal complex is of the formula (I), wherein R1, R2, R3, M, X and Ring A are as defined herein.
Type:
Grant
Filed:
February 20, 2015
Date of Patent:
February 26, 2019
Assignee:
Cornell University
Inventors:
Geoffrey W. Coates, Scott Allen, Tsuyoshi Ando
Abstract: A photosensitive resin composition comprises a polymer having a repeating structural unit of the following Formula (1): (wherein R1 and R2 are each independently a single bond, a methylene group, or an ethylene group, Y is an alkylene group of Formula (2) or a combination of the alkylene group of Formula (2) with an alkylene group of Formula (3), n is an integer of 1 to 110, and X is a divalent aliphatic hydrocarbon group, a divalent alicyclic hydrocarbon group, or a divalent aromatic hydrocarbon group) and a (meth)acryloyl group at both ends, a bifunctional (meth)acrylate compound, a polyfunctional thiol compound, a photo-radical generator and an organic solvent, and then the bifunctional (meth)acrylate compound contained in an amount of 5% to 50% by mass and the polyfunctional thiol compound is contained in an amount of 0.1% to 10% by mass, relative to the content of the polymer.
Abstract: A method for producing polycarbamate comprising: contacting at least one carbamylating agent with a polyol in the presence of a carbamylation catalyst to form a reaction mixture having an acid value from 3 to 50 mg KOH/g dry polyol is provided. Further provided are a polycarbamate produced by the method and a coating comprising the polycarbamate.
Type:
Grant
Filed:
September 18, 2014
Date of Patent:
February 5, 2019
Assignee:
Dow Global Technologies LLC
Inventors:
Gary E. Spilman, Congcong Lu, Daryoosh Beigzadeh, Jr., Yiyong He, Paul J. Popa, John N. Argyropoulos
Abstract: The present invention provides an LCP derivative/soft magnetic ferrite composite material, which is prepared by complexing and assembling an LCP derivative as a host and soft magnetic ferrite particles as a guest. The present invention also provides a method for preparing the composite material. The composite material of the present invention has high stability and is not easily dissociated, and has high customized magnestic permeability, dielectricity, thermal stability, environmental resistance, and chemical resistance; and the preparation process of the composite material meets the energy-saving and emission reduction requirements. Therefore, the composite material has a wide industrial application prospect. The composite material of the present invention can be widely applied to the wireless communication field, the aviation, spaceflight and military fields, the microwave and radio frequency component application field, the automotive electronic component field, and the like.
Abstract: Described is the use of a hardening composition for epoxide-amine-based, multicomponent mortar compositions, particularly the use of one of these epoxide-amine-based, multicomponent mortar compositions for chemical fastening purposes. The multicomponent mortar composition contains (A) a resin component, which comprises as a curable compound at least an epoxide resin and optionally at least one reactive diluent, and (B) a hardener component, which comprises a hybrid hardener, wherein the resin component (A) and/or the hardener component (B) optionally comprises other ingredients selected from among inorganic and/or organic compounds. The hybrid hardener is a mixture of (a) at least one amine, selected from among aliphatic, alicyclic, or aromatic amines, as a hardener, and (b) a novolac resin as catalyst, wherein the novolac resin is contained in a quantity of 30 to 45 percent by weight, relative to the total weight of the hybrid hardener.
Type:
Grant
Filed:
July 18, 2014
Date of Patent:
January 29, 2019
Assignee:
Hilti Aktiengesellschaft
Inventors:
Alex Dureault, Stephen Jewitt, Christian Kloninger
Abstract: This invention relates to products H made by reaction of a cyclic alkyleneurea U, at least one multifunctional aldehyde A2, and at least one of (a) an aminoplast former M that is not the same as the cyclic alkyleneurea U, and (b) a monofunctional aldehyde A1, which product H is optionally etherified by reaction of at least a part of the hydroxyl groups formed by addition reaction of N—H groups and aldehyde groups, with an alcohol having from one to ten carbon atoms, and wherein glyoxal is present in the at least one multifunctional aldehyde A2, to processes for their preparation, and to a method of use thereof in coating compositions.
Type:
Grant
Filed:
November 18, 2016
Date of Patent:
January 15, 2019
Assignee:
Allnex Netherlands B.V.
Inventors:
Ram B. Gupta, Urvee Y. Treasurer, Lawrence A. Flood, Barry A. Lawless
Abstract: The invention relates to a process for modifying isocyanates where at least one organic isocyanate with NCO functionality >1 is oligomerized in the presence of at least one catalyst, characterized in that the catalyst comprises, as isocyanatemodification catalysts, at least one cyclic ammonium salt having a cation of the formula (I) (formula I), where the N-containing substituents R1 and R2 are mutually independently identical or different aliphatic, cycloaliphatic, aromatic or araliphatic C, to C20 moieties which are saturated or unsaturated, linear or branched, optionally substituted and/or interrupted by heteroatoms from the group of oxygen, sulphur and nitrogen, and Y is a substituted or unsubstituted, linear or branched C2 to C20 segment optionally interrupted by heteroatoms from the group of oxygen, sulphur and nitrogen or else intempted by aromatic rings, and optionally containing other rings. The invention further relates to the use of such a catalyst.
Abstract: This invention describes resins with phosphate cores and a simple, three-step process for their synthesis. Preferred resins are cyanate ester resins with bridging phosphate groups. These resins can be cured to produce thermoset polymers having Tgs of between 131 and >360° C. depending on the number of cyanate ester groups per phosphate and the substitution pattern of the aromatic rings. The high char yields of these resins, up to about 67%, coupled with the phosphate core means that these materials will have applications as fire-resistant polymers. Additionally, these materials can potentially be blended with conventional cyanate esters or other compatible thermosetting resins to improve the fire resistance of composite materials. Other applications may include use in fire-resistant circuit boards, or as surface coatings to reduce flammability of conventional composite materials or thermoplastics.
Type:
Grant
Filed:
September 6, 2016
Date of Patent:
December 18, 2018
Assignee:
The United States of America as Represented by the Secretary of the Navy
Inventors:
Benjamin G. Harvey, Andrew P. Chafin, Michael D. Garrison
Abstract: A cross-linkable flame retardant material includes a terminal furan-containing flame retardant moiety. The terminal furan-containing flame retardant moiety includes a furan moiety bonded to a phosphorus moiety via a phosphoryl linkage or via a phosphinyl linkage.
Type:
Grant
Filed:
December 12, 2016
Date of Patent:
December 18, 2018
Assignee:
International Business Machines Corporation
Inventors:
Brandon M. Kobilka, Joseph Kuczynski, Jacob T. Porter, Jason T. Wertz
Abstract: A composition based on poly(ether ether ketone) (PEEK) including poly(ether ketone ketone) (PEKK), characterized in that the poly(ether ketone ketone) (PEKK) includes a mixture of terephthalic and isophthalic units, the percentage by weight of terephthalic units, with respect to the sum of the terephthalic and isophthalic units, being between 55 and 85%, limits included, and preferably between 55 and 70%, the composition including between 1 and 40%, limits included, preferably between 5 and 40% and more preferably still between 10 and 30% by weight of PEKK, with respect to the total weight of the composition.
Type:
Grant
Filed:
October 9, 2015
Date of Patent:
December 11, 2018
Assignee:
ARKEMA FRANCE
Inventors:
Benoît Brule, Richard Audry, Jerome Pascal
Abstract: The present teachings relate to curable linear polymers that can be used as active and/or passive organic materials in various electronic, optical, and optoelectronic devices. In some embodiments, the device can include an organic semiconductor layer and a dielectric layer prepared from such curable linear polymers. In some embodiments, the device can include a passivation layer prepared from the linear polymers described herein. The present linear polymers can be solution-processed, then cured thermally (particularly, at relatively low temperatures) and/or photochemically into various thin film materials with desirable properties.
Type:
Grant
Filed:
July 13, 2016
Date of Patent:
December 4, 2018
Assignee:
Flexterra, Inc.
Inventors:
Shaofeng Lu, Antonio Facchetti, Xiang Yu, Darwin Scott Bull, Karen K. Chan
Abstract: Methods, compounds, and compositions described herein generally relate to polyalkylamines and syntheses thereof. In some embodiments, a chemical compound has the formula: Each instance of R is independently selected from the group consisting of aryl, alkyl, and polyether. Each instance of R? is independently selected from the group consisting of hydrogen, alkyl, aryl, cycloalkyl, polyether, and alcohol. Each instance of Q and Z is independently a covalent bond or selected from the group consisting of alkyl and aralkyl.
Type:
Grant
Filed:
November 16, 2016
Date of Patent:
November 27, 2018
Assignee:
International Business Machines Corporation
Inventors:
Dylan J. Boday, Jeannette M. Garcia, James L. Hedrick, Robert J. Ono, Rudy J. Wojtecki