Abstract: Provided are polymer particles which can be used at a high flow rate when used as a filler for chromatography, that is, has excellent resistance flow rate appropriate for processing in large quantities, and also has a high binding capacity for target molecules such as proteins when an appropriate ligand is contained in the particles, and a method for producing the polymer particles; specifically, crosslinked polymer particles and a method for producing the crosslinked polymer particles, polysaccharide composite particles and a method for producing the polysaccharide composite particles, a filler for chromatography using the polymer particles, and an adsorbent for antibody purification. Disclosed are: A.

Abstract: A method of hydrothermal processing of highly toxic substances, wastes and metal powders, comprises a batch processing cycle of at least following steps i. to viii: i. preparing a batch of highly toxic waste, substances and metal powders for processing; ii. applying precision dozing to the batch to obtain a mixture of the batch with water and at least one additional reagent in preset proportions; iii. feeding the mixture into a reactor; iv. spraying the mixture inside the reactor with a mechanical spray nozzle; v. supplying an additional oxidizing agent inside the reactor; vi. adjusting a temperature inside the reactor to above 374.2° C.; vii. adjusting a pressure inside the reactor to above 21.8 MPa, thereby driving the water into supercritical condition and initiating a supercritical hydrothermal oxidation process; and viii. keeping the mixture in the reactor for a preset amount of time, and at the same time.

Abstract: The present discloses a process and catalyst therefor to selectively remove acetylenes from gaseous streams in the vapor phase. The process is particularly suitable for high yield recovery of olefinic hydrocarbons from gaseous streams in refinery processes.

Abstract: The present invention relates to a regeneration process for producing a regenerated ionic liquid catalyst from solids formed in an ionic liquid alkylation process wherein a first ionic liquid is used as a catalyst which is a composite ionic liquid comprising ammonium cations, and anions being composite coordinate anions derived from two or more metal salts, the regeneration process comprising (a) removing the solids from the reaction zone of the alkylation process; and (b) subsequently treating the solids with a second ionic liquid made from an ammonium salt as cation, and an aluminum salt as anion which is the same as the aluminum salt present in the first ionic liquid.

Abstract: Reversibly switchable (transformable) surface layer changeable from (super)hydrophobic to (super)hydrophilic surface states are described. Methods of decontamination of surfaces exposed to contaminate are provided. The reversibly switchable properties of the surface layer can be controlled by an external stimulus.

Abstract: Materials and methods of making densified waste forms for temperature sensitive waste material, such as nuclear waste, formed with low temperature processing using metallic powder that forms the matrix that encapsulates the temperature sensitive waste material. The densified waste form includes a temperature sensitive waste material in a physically densified matrix, the matrix is a compacted metallic powder. The method for forming the densified waste form includes mixing a metallic powder and a temperature sensitive waste material to form a waste form precursor. The waste form precursor is compacted with sufficient pressure to densify the waste precursor and encapsulate the temperature sensitive waste material in a physically densified matrix.

Abstract: A radioactive waste (zeolite to which Cs-137 was adsorbed) in a waste tank and a glass raw material (soda lime glass) in a glass raw material tank are supplied into a solidifying vessel. Graphite in a graphite tank is also supplied into the solidifying vessel. The solidifying vessel is filled with a mixture of the radioactive waste, glass raw material, and graphite and is then disposed in an adiabatic vessel. The radioactive waste and glass raw material in the adiabatic vessel are heated by thermal energy generated due to radiation emitted from Cs-137. The heat is transferred to the peripheral portion of the solidifying vessel through the graphite, raising the temperature of the peripheral portion. The glass raw material is melted and enters clearances among the radioactive waste, producing a vitrified radioactive waste. This radioactive waste solidification method can shorten a time taken to produce a vitrified radioactive waste.

Abstract: The invention relates to a process for regenerating a catalyst used in the decarbonylation of an aldehyde, wherein the catalyst is a heterogeneous, supported catalyst containing a metal selected from the group consisting of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt and mixtures thereof, and wherein the catalyst is subjected to a gas stream comprising hydrogen at a temperature of from 200 to 600° C., wherein substantially no oxygen is used in the regeneration process.

Abstract: Disclosed is a method for treating a radioactive organic waste, the radioactive organic waste including a cation exchange resin adsorbing radionuclide ions, the method including the step of bringing the radioactive organic waste into contact with an organic acid salt aqueous solution containing an organic acid salt and whereby desorbing the radionuclide ions from the cation exchange resin, in which the organic acid salt contained in the organic acid salt aqueous solution includes a cation that is more readily adsorbable by the cation exchange resin than hydrogen ion is. This enables reduction in concentration of a radioactive substance in the radioactive organic waste and reduction in amount of a high-dose radioactive waste.

Abstract: A catalytic ink preparation method comprises mixing a first ion conducting body and a catalyst, preparing a first ink, and concentrating the first ink. The method is characterized by further comprising a step of adding a second ion conducting body to the concentrated first ink. With such a catalytic ink preparation method, the quantity of solvent in the first ion conducting body is reduced by concentration. In other words, the first ion conducting body adheres to the catalyst, and re-dissolution is not prone to occurring with the first ion conducting body when the second ion conducting body is added. Thus, it is possible to efficiently manufacture an electrode catalyst in which a significant part of the surface of the catalyst is covered with two ionomer layers, and there is almost no portion which is covered with only one ionomer layer.

Abstract: A process is disclosed for an improved catalyst regeneration process to improve catalyst stability and hence increase overall catalyst life. The process includes passing a spent catalyst stream to a first, or upper, combustion zone to partially regenerate the catalyst through controlled combustion of the carbon on the catalyst. The first combustion zone will burn off a high fraction of hydrogen at lower temperatures generating a large fraction of H2O. The partially regenerated catalyst is passed to a second, or lower, combustion zone to burn off the remaining coke at the needed high severity operation. The second combustion zone will burn off the remaining coke at a higher temperature and higher oxygen gas inlet concentration.

Abstract: Described herein is a selective catalytic reduction (SCR) catalyst treatment system that includes a vanadium-based SCR catalyst contaminated with a water-soluble contaminant. The SCR catalyst treatment system also includes a water delivery system that is configured to apply water to the vanadium-based SCR catalyst to remove the water-soluble contaminant from the vanadium-based SCR catalyst.

Abstract: A reinforced absorbent polymer is provided for improving mechanical properties without degrading their absorption performance. The reinforced polymer includes an absorbent polymer; and at least one fiber for reinforcement disposed in the polymer.

Abstract: The present invention provides a method for manufacturing a water-absorbing resin which (i) is made of acrylic acid that is suitable for mass production of water-absorbing resin and (ii) has an excellent water-absorbing property. In the method, a polyacrylic acid (salt)-based water-absorbing resin is manufactured by sequentially carrying out predetermined monomer preparing step, polymerization step, drying step, and surface crosslinking step. An acetic acid concentration in acrylic acid or the like supplied in the monomer preparing step is in a range of 300 ppm to 10000 ppm on the acrylic acid basis, and an acetic acid concentration lowering rate defined by a predetermined formula is 35% or higher.

Abstract: Method and system is described to enhance operations for managing the hydrocarbon release. The system utilizes remote controlled devices equipped with herder delivery components. The system may utilize herders to perform in-situ burning of the oil slick. This method may provide dedicated remote control device for each response vessel to further enhance the response to oil slicks.

Abstract: Processes for fatty acid ketonization and alcohol dehydration, wherein an alumina catalyst disposed in, or removed from, a reaction zone may be regenerated by contacting the catalyst with steam during or after a coke oxidizing step. In an embodiment, such processes may provide C2-C43 alkenes. In another embodiment, such processes may provide C11-C43 ketones, which can be deoxygenated to give saturated hydrocarbons, unsaturated hydrocarbons, and mixtures thereof. Base oils and transportation fuels may be produced via such processes.

Abstract: An aspect of the present invention relates to a method of manufacturing magnetic powder, which comprises adding an alkali metal salt compound comprising a substituent selected from the group consisting of an alkali metal salt of a carboxyl group and an alkali metal salt of a hydroxyl group to a water-based magnetic liquid comprising magnetic particles dispersed in an acidic water-based solvent to cause the magnetic particles to aggregate in the water-based magnetic liquid; and collecting the aggregated magnetic particles to obtain the magnetic powder.

Abstract: A method of immobilizing a radioisotope and vitrified chemically bonded phosphate ceramic (CBPC) articles formed by the method are described. The method comprises combining a radioisotope-containing material, MgO, a source of phosphate, and optionally, a reducing agent, in water at a temperature of less than 100° C. to form a slurry; curing the slurry to form a solid intermediate CBPC article comprising the radioisotope therefrom; comminuting the intermediate CBPC article, mixing the comminuted material with glass frits, and heating the mixture at a temperature in the range of about 900 to about 1500° C. to form a vitrified CBPC article comprising the radioisotope immobilized therein.

Abstract: A series of MOF-based hierarchical porous material, namely IPD-mesoMOF-1˜9, based on nanoscale MOFs of MIL-100(Al, Fe, Cr, Sc and In), MIL-53(Al), HKUST-1, DUT-5, DUT-4, MIL-101(Cr), MIL-101NDC(Cr), MIL-101BPDC(Cr) and MIL-110 respectively, forming the permanent interparticle porosities by using close (or relatively close) packing, and preparation methods thereof. Modulated or functionalized IPD-mesoMOFs can be applied for gas adsorption and molecule separation (such as CH4- and CO2-adsorption, gasoline/diesel desulfurization and purification), catalyst loadings and molecular recognition/immobilization of biological macromolecules and enzymes.

Abstract: In this invention, we disclose a method as well as silica and/or organosilica mesoporous materials obtained by templating using nanocrystalline cellulose and removal of the latter using acidic conditions. The resultant mesoporous silica materials are characterized by having high surface area with tunable iridescence resulting from the long-range chiral nematic organization. This invention is an improvement over the formation of composite materials formed with nanocrystalline cellulose (NCC) and silica, where the calcination of the materials led to removal of the cellulose and formation of a mesoporous silica material. Characteristically, the removal of the NCC template using acidic conditions differentiates the silica materials thus obtained in two ways: (1) It does not lead to as significant contraction of the materials as from calcination thereby giving access to materials with larger mesopores; and (2) it allows the formation of mesoporous chiral nematic compositions that include heat-sensitive components.