Abstract: A process for preparing an aqueous dispersion of high polymer, characterized by using pullulan as a dispersant.The aqueous high polymer dispersion obtained by the above-mentioned process is not only high in stability but also so excellent in practical properties as to be usable for the processing of fibers or papers.
Type:
Grant
Filed:
March 17, 1975
Date of Patent:
May 4, 1976
Assignees:
Sumitomo Chemical Company, Limited, Hayashibara Biochemical Laboratories, Inc.
Abstract: Process for the preparation of aqueous homogeneous polymer emulsion which comprises mixing, generally with agitation or under shear conditions, water, surfactant, at least one polymer, e.g., cellulosic compounds, and at least one monomer, e.g., acrylics, methacrylics, styrene, etc., the polymer being soluble in said monomer, to form a dispersion of polymer-monomer particles in water; then subjecting said dispersion to conditions such that the monomer within the particles becomes polymerized by free radical polymerization forming a substantially homogeneous blend of at least two polymers within the particles of the emulsion. The particles have on the average a diameter of 5 microns or less. The aqueous emulsions comprise an aqueous continuous phase and dispersed therein particles having an average diameter of up to 5 microns, the particles being substantially a homogeneous blend of a cellulosic compound e.g.
Type:
Grant
Filed:
July 2, 1974
Date of Patent:
April 27, 1976
Assignee:
E. I. Du Pont de Nemours and Company
Inventors:
Charles Vincent Murphy, David William Zunker
Abstract: A biodegradable barrier film is provided which is useful as a barrier layer in absorbent pads such as sanitary napkins and diapers. The film comprises a matrix of a non-biodegradable film-forming material which is resistant to solubility in water having a biodegradable material homogeneously dispersed therein, the biodegradable material being present in said film in an amount from about 40 to about 60 weight percent based on the total weight of said biodegradable and said non-biodegradable film-forming material in said film.
Abstract: A novel adhesive composition for tail control of rolled paper stock, said composition including a modified starch, polyethylene resin and water. The adhesive is applied onto the paper stock so as to form a non-continuous film.
Abstract: Alloy fibers having high fluid-holding capacity being comprised of a matrix of non-derivatized regenerated cellulose having regenerated cyanoethyl cellulose and polyvinylpyrrolidone uniformly dispersed therein.
Abstract: A polymer dispersed liquid is prepared by the following steps: (1) polymerzing at least two different types of monomers of the vinyl series in the presence of a block or graft copolymer of the vinyl series containing a component solvating in a dispersion medium (.alpha.) and a component not solvating in the dispersion medium, but being compatible with a dispersed polymer (.beta.) in an organic liquid in which a copolymer of the vinyl series to be produced is soluble; then at that time, uniformly admixing an alkylated melamine-formaldehyde reaction product before, during or after the polymerization, (2) distilling out a part of the organic liquid, thereby varying the solubility parameter of the organic liquid of said polymer solution by more than about 0.5.
Abstract: Aqueous suspensions of polyolefin fibrids are prepared. To avoid foam formation and improve fiberbonding, small amounts of anionic agents are added to the suspensions. The suspensions are suitable for the manufacture of paper-like or textile-like web structures distinguished by very good fiber bonding and good initial wet strength.
Type:
Grant
Filed:
October 17, 1974
Date of Patent:
April 13, 1976
Assignee:
BASF Aktiengesellschaft
Inventors:
Bruno Sander, Eckhard Bonitz, Heinz Berbner, Manfred Hoffmann
Abstract: The biodegradable polymer having the formula:W--M--Zwherein M is a polyanhydroglucose block which does not contain any ester substituents and wherein W and Z are organic diisocyanates having the formula: ##EQU1## or ##EQU2## wherein R is an divalent organic radical and wherein X is a terminal group, --M--Z, --M--W or --M. The process of preparing the biodegradable polymer wherein M contains at least one ester substituted hydroxyl group which comprises deesterifying M to obtain M as a polyanhydroglucose block which does not contain any ester substituents.
Type:
Grant
Filed:
December 6, 1974
Date of Patent:
April 13, 1976
Inventors:
Richard D. Gilbert, Vivian T. Stannett, Soojaa L. Kim
Abstract: Contact lens having high water content make from polymer of cross-link-polymerized N-vinyl pyrrolidone in the presence of water-insoluble polymer has excellent properties suitable for continuous wearing for a long period of time.
Abstract: Wood materials are prepared, characterised by improved resistance to hot water and by high weather resistance, by combining wood products with a phenol-aldehyde resin and alkylene carbonate hardener, the latter being incorporated in said resin as an aqueous formaldehyde solution.
Abstract: Polysaccharide matrices, e.g., agarose, for use in certain affinity chromatography procedures, are activated with sodium metaperiodate, derivatized with a symmetrical dihydrazide and thence reductively stabilized, preferably with sodium cyanoborohydride. Moreover, intermediate Schiff bases formed from the NaIO.sub.4 -oxidized polysaccharide are selectively, reductively stabilized with said sodium cyanoborohydride.
Abstract: A release paper which is particularly useful in platen press applications and in the casting of self-supporting films which comprises a fibrous base having a coating thereon derived from an aqueous coating composition containing a release agent, a monomeric polyhydric alcohol and a cross-linkable, thermosetting resin.
Abstract: A soil treating composition for mixing with water to form an aqueous solution for treating soil is characterized by including a synthetic latex material in a mixture including hydroxy ethyl cellulose, metal salts and powdered citric acid. For compacting earthen type soils, the mixture also includes fermented wort, non-ionic surfactants and vanilla extract. For erosion control, the fermented wort, non-ionic surfactants and vanilla extract are not essential.
Abstract: Disclosed is a process for preparation of copolymers which have an inherent viscosity of at least 0.4 and are formed from polyesters and aliphatic polyformals. The process comprises contacting within a temperature range of 220.degree. to 280.degree.C. a poly(tetramethylene terephthalate) type polyester and selected aliphatic polyformals.
Type:
Grant
Filed:
November 29, 1974
Date of Patent:
March 9, 1976
Assignee:
Eastman Kodak Company
Inventors:
Harry Robert Musser, Winston Jerome Jackson, Jr.
Abstract: Compositions suitable for coating leather or textile materials are provided which compositions are the reaction product of (a) solubilized casein (b) water-dispersible polyurethane and (c) formaldehyde.
Type:
Grant
Filed:
February 25, 1974
Date of Patent:
March 9, 1976
Assignee:
Bayer Aktiengesellschaft
Inventors:
Walter Schroer, Helmut Reiff, Dieter Dieterich, Karl Berger
Abstract: Discontinuous cellulose fiber is treated with both plastic polymer and lubricant to produce improved treated fiber for reinforcing a plastic matrix.
Abstract: Polymeric particles are homogeneously dispersed in aqueous medium by a process which comprises dissolving a water-insoluble film-forming polymer in a water-insoluble, ethylenically unsaturated monomer which is liquid at room temperature. The solution formed is dispersed by stirring in an aqueous solution of a hydrophilic colloid and of a dispersing agent, stirring being continued until a stable dispersing of polymer-in-monomer solution droplets having a diameter between 1 and 10 microns, preferably between 1 and 6 micron, in said aqueous solution is obtained. While continuously stirring the dispersion in the presence of a free-radical forming polymerisation initiator, the dispersion is heated at the decomposition temperature of said polymerisation initiator to effect polymerisation of the water-insoluble, liquid monomer and to form an aqueous dispersion of solvent-free polymer particles.
Type:
Grant
Filed:
October 23, 1973
Date of Patent:
March 2, 1976
Assignee:
AGFA-GEVAERT N.V.
Inventors:
Daniel Maurice Timmerman, Victor Jan Thijs, Walter Frans De Winter, Frans Henri Claes, Hubert Vandenabeele
Abstract: An aqueous suspending agent solution or vehicle useful for suspension polymerization of a styrene-monomer such as styrene as well as derivatives of it and also mixtures with it to produce styrene-polymers. Also included is a suspension polymerization batch, as well as an improvement in the method, for the suspension polymerization of a styrene-monomer.
Abstract: An improved process is used to prepare encased powdered elastomers which replace slab rubber in injection molding formulations and thereby eliminates the need for milling and high shear mixing. A composition is obtained which is easily blended and is capable of being automatically fed to injection molding machines, and which contains less encasement compound than prior art powdered elastomers having similar nonagglomerating and free-flowing properties.
Type:
Grant
Filed:
May 5, 1975
Date of Patent:
March 2, 1976
Assignee:
The United States of America as represented by the Secretary of Agriculture