Abstract: A method and apparatus for separation of radioactive particulates from liquids by filtration to remove or recover the particulates, that reduces the surfaces forces associated with electrostatic attraction between the particles and the filter medium by modifying or coating the surface of the filter medium with a material that exhibits a surface charge closer to or the same as that of the particulates in a given aqueous liquid. The method and apparatus can be used to filter radioactive particulates and contaminants from aqueous liquid or liquid process streams with a radiation resistant filter medium. The filters can exhibit a surface charge different from that of the particulates targeted for separation by mechanical filtration. The filtration medium can be modified to increase its resistance to erosion to permit use of more powerful backwashing regeneration methods and prevent attachment of the particulates to the filtration medium by coating the medium with a hydrophobic layer.

Abstract: A method for preparing phosphorus-doped graphene using phosphorus-containing sludge and biomass, belonging to the field of solid waste resource utilization and environmental protection technologies, includes: performing a hydrothermal reaction with the phosphorus-containing sludge and the biomass to obtain a product, washing and drying the product to obtain phosphorus-doped hydrochar, and subjecting the phosphorus-doped hydrochar to a flash Joule heating treatment to obtain the phosphorus-doped graphene. The method for preparing the phosphorus-doped graphene by flash Joule heating is based on cheap and easily available phosphorus containing sludge and corn cobs as precursors. The high-quality phosphorus-doped graphene can be obtained by the flash Joule heating after in-situ phosphorus doping by a hydrothermal carbonization method. The method for preparing the phosphorus-doped graphene is controllable, fast, simple and efficient, which is beneficial to large-scale production and application.

Abstract: A method of hydrogen generation may include contacting sodium borohydride (NaBH4) and a nanocomposite comprising graphitic C3N4, MnO2, and MgAl2O4 in a mass relationship to each other in a range of from 5 to 15:2 to 7:75 to 95, at a temperature in a range of from 10 to 80° C., thereby catalyzing the hydrogen generation at a hydrogen generation rate in a range of from 2000 to 5000 mL/(min·g).

Abstract: A method for synthesizing a zirconium complex includes: mixing a solvent containing an organic substance having a dipole moment of 3.0 D or more, a chelating agent solution in which a chelating agent containing a structure represented by General Formula (1) or General Formula (2) is dissolved, and zirconium dissolved in an acidic solution, to obtain a mixed solution; and setting the mixed solution at a predetermined temperature or more to synthesize a zirconium complex.

Abstract: The present disclosure discloses a catalyst composition comprising: (a) at least one steamed biochar; and (b) at least one tri-metallic catalyst, comprising metals selected from the group consisting of nickel, copper, zinc, and combinations thereof, wherein nickel loading is in the range of 20-60 wt %, the copper loading is in the range of 0.5-5.0 wt %, and the zinc loading is in the range of 0.5-5.0 wt with respect to the at least one steamed biochar. The instant disclosure further relates to a process of preparation of the catalyst composition and a process for production of hydrogen gas and carbon nanotubes.

Abstract: A boehmite structure includes a plurality of boehmite particles where adjacent boehmite particles are bonded to each other. The boehmite structure has a porosity of 30% or less. A method of producing a boehmite structure includes obtaining a mixture by mixing hydraulic alumina with a solvent including water, and pressurizing and heating the mixture under a condition of a pressure of 10 to 600 MPa and a temperature of 50 to 300° C.

Abstract: A sodium borate, aluminum powder and fluoride powder are mixed together in a hermetic vessel filled with hydrogen gas, and the mixture is reacted at not less than 410° C. and not more than 560° C. to produce sodium borohydride.

Abstract: Open pit mine (OPM) structures are modified or built new for use in disposing of low-level radioactive/nuclear waste (LLW). A drainage system is added to the OPM to drain water, such as, but not limited to, rain water, out of a volume of the OPM and to a particular geologic zone located far below the OPM that is isolated away from the local water table. Cells are formed within the volume of the OPM that are configured to receive the LLW. Cells are added to the OPM from a bottom towards a top of the OPM. Void spaces around the LLW materials within the cells are filled in with a protective-medium to mitigate against radionuclide migration away from the LLW materials within the cells. The protective-medium may be a blend of carbon nanotubes and a foam cement slurry. The carbon nanotubes may be made from reacting ethylene with vermiculite.

Abstract: An apparatus for saturating a buffer material includes a jig for fixing and supporting a buffer material to prevent an increase of a volume of the buffer material. The jig is provided to surround at least a portion of the buffer material. The apparatus further includes a case having a space in which the jig supporting the buffer material is accommodated, a supply unit configured to supply water vapor into the case to adjust a saturation level of the buffer material, and a control unit configured to control the supply unit to stop the supply of water vapor when the saturation level of the buffer material reaches a preset critical saturation level.

Abstract: A heterostructured catalyst includes a 2-dimensional (2D) array of titanium including nanocavities that are all directly attached to a substrate. Each of the titanium including nanocavities have a pore with a nanopore size and a wall with a nanowall thickness. The titanium including nanocavities can be titania nanocavities with a metal layer or a metal compound layer on the titania nanocavities including inside the pores, or the titanium including nanocavities can include SrTiO3 or consist of SrTiO3, each with a surface layer of reduced SrTiO3.

Abstract: A process of obtaining powdered sodium silicate from sand tailings generated from iron ore processing addresses the production of raw materials used in the manufacturing of geopolymers to be employed mainly by the construction industry and in road paving. The utilization of this tailing reduces environmental impact generated by the disposal in large dams, as well as enabling addition of value to a tailing by obtaining a commercially applicable product.

Abstract: A nanocomposite having ionic conductivity and having the general formula CuO·MgAl2O4 wherein: copper oxide (CuO) is present in an amount of from about 5 to about 15 weight percent (wt. %) of the total weight of the nanocomposite; and, CuO is present as a monoclinic crystal phase within the nanocomposite, as determined by X-ray diffraction (XRD).

Abstract: The present invention relates to a method for producing lithium carbonate by mixing lithium sulfate with a carbon material and heat-treating same in a carbon dioxide or carbon monoxide atmosphere.

Abstract: A disposal method for waste fabric containing polyester and nylon includes: step (a): providing a waste fabric containing polyester and nylon; step (b): performing a first-stage treatment including acid treatment on the material to obtain a first liquid material and a first solid material; step (c): performing a second-stage treatment on the first liquid material to obtain a second liquid material and a second solid material; step (d): performing a third-stage treatment including acid treatment on the first solid material to obtain a third liquid material and a third solid material; step (e): performing a fourth-stage treatment on the third liquid material to obtain a fourth liquid material and a fourth solid material, wherein the acid concentration of the second liquid material is lower than the acid concentration of the first liquid material, and the acid concentration of the fourth liquid material is lower than the acid concentration of the third liquid material.

Abstract: A tungsten hexafluoride manufacturing method of the present invention includes a reaction step of reacting tungsten with a gas of a fluorine element-containing compound so as to obtain a mixture that contains tungsten hexafluoride and hydrogen fluoride-containing impurities, and a discharge step of performing distillation of the mixture while performing a discharge operation at least two or more times during the distillation so as to obtain tungsten hexafluoride, the discharge operation being an operation in which a storage operation and a purge operation are alternately performed.

Abstract: Radioactive nuclides (radionuclides) are separate from an aqueous radioactive liquid by feeding the liquid into a chamber between a porous anode and a porous cathode of a shock electrodialysis device. Meanwhile, an anolyte is fed through the porous anode, and a catholyte is fed through the porous cathode. A voltage is applied to the porous anode and to the porous cathode to create a voltage differential across the chamber. The liquid is passed through the chamber, and cations are selectively driven from the liquid into the cathode by the voltage differential. The voltage differential creates a desalination shock that produces an ion-enriched zone on one side of the desalination shock and a deionized zone on an opposite side. A brine including the radioactive cations is extracted from the ion-enriched zone through a brine outlet, and fresh water is extracted from the deionized zone through a fresh-water outlet.

Abstract: A method for granulating a slurry in a fluidized bed granulator having a main longitudinal direction from a seed end where granulation is initiated, to a product discharge end where granules are discharged from the fluidized bed granulator, including at least one fluidized bed compartment, an injection section and a granulation section, separated by a bottom plate including one or more injection nozzles, wherein a feed slurry is provided to the injection section, wherein a first fraction of the feed slurry provided to the injection section is injected into the granulation section through the one or more injection nozzles and a second fraction of the feed slurry, being the remainder of the feed slurry, is passed through the injection section without being injected into the granulation section. A fluidized bed granulator for the granulation of slurries for fertilizer products such as UAS according to the method of the invention.

Abstract: The invention provides a system for pyrolysing organic waste. The system comprises a conical housing (4) configured to temporarily, substantially hermetically, enclose the waste and a mixing device provided with a drive shaft rotatably mounted relative to the housing and a conical mixing body (25) configured inside the housing to fluidise the waste, which mixing body fixedly attached substantially does not touch the housing. The system further comprises heating means (24) for heating the side wall of the housing. This system makes it possible to carry out the processing of organic waste in a batch process. The mixing body prevents a portion of the waste from sticking together by fluidising the waste and keeping it fluidised, whereby the heat generated by the heating means can gradually spread through the waste inside the housing.

Abstract: A solution comprising at least one protic solvent, at least one monomer comprising an (alkyl)acrylic, (alkyl)acrylate or (alkyl)acrylamide group, at least one crosslinking agent comprising at least two groups chosen from (alkyl)acrylic, (alkyl)acrylate or (alkyl)acrylamide groups, at least one photopolymerization initiator and at least one agent chosen from alkali metal halides, alkali metal phosphates, alkali metal sulfates and mixtures thereof; or—of a polymer material capable of being obtained by polymerization of the solution defined above comprising a polymer resulting from the polymerization of the monomer(s) and of the crosslinking agent(s) as defined above and trapping, at the center thereof, a liquid phase comprising at least one agent as defined above; for the trapping of at least one toxic chemical agent.

Abstract: Systems and methods for reducing the volume of construction and demolition (C&D) debris waste are described. The systems include a torrefaction unit that reduces the hardness of the waste while degrading it into volatiles and particles having a range of sizes. The variation in particle size allows for a more efficient compaction due to minimal void space and the imparted softness allows for increased compressibility. This results in the processed debris having a much smaller volume than had it not undergone the presently described methods, which reduces landfill tipping fees and extends the life of the landfill.