Patents Examined by Erin M. Higgins
  • Patent number: 5443757
    Abstract: Aqueous liquid dishwashing detergent compositions are prepared that exhibit improved detergency performance and foam stability over a range of water hardness levels. A preferred formulation incorporates a three component mixture: an anionic surfactant, a nonionic surfactant, and an amido amine oxide to provide a detergent having good detergency performance and foam stability over a range of water hardness levels. Another preferred formulation incorporates a three component mixture: an anionic surfactant, a nonionic surfactant, and an alkyl ethoxylated carboxylate to provide a detergent having good detergency performance and foam stability at high hardness levels.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: August 22, 1995
    Assignee: Amway Corporation
    Inventor: Ernest H. Brumbaugh
  • Patent number: 5427707
    Abstract: The physical stability of liquid gel-like compositions based on thixotropic thickener is greatly improved by incorporating in the composition small amounts, such as 0.1 to 0.2 weight percent of long chain fatty acids and salts thereof. The aqueous compositions containing inorganic builder salts and other functional inorganic salts, chlorine bleach, bleach stable detergent, at least one thixotropic thickener and a fatty acid or alkali metal salt of the fatty acid as a physical stabilizer exhibit a significant increase in apparent viscosity and remain stable against phase separation for an extended period of time. The thixotropic properties can be retained or improved using smaller levels of the thixotropic thickener than in the absence of the physical stabilizer. The stability, chlorine-bleach loss and cleaning ability of the compositions is further improved, when the composition pH is at least 11.2, when added to an aqueous wash both at a concentration of about 10 grams per liter.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: June 27, 1995
    Assignee: Colgate Palmolive Co.
    Inventors: Julien Drapier, Chantal Gallant, Leo Laitem, Marta Delsignore, Makarand Shevade, Rhyta Rounds, Divaker Kenkare, Thomas Davan, Nagaraj S. Dixit
  • Patent number: 5415812
    Abstract: A light duty microemulsion liquid detergent composition, useful for removing greasy soils from surfaces with both neat and diluted forms of the detergent composition, includes a moderately water soluble complex of anionic and cationic surfactants, in which complex the anionic and cationic moieties are in essentially equivalent or equimolar proportions, an anionic detergent, a co-surfactant, an organic solvent and water.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: May 16, 1995
    Assignee: Colgate-Palmolive Co.
    Inventors: Patrick Durbut, Ammanuel Mehreteab, Myriam Mondin, Guy Broze
  • Patent number: 5415796
    Abstract: The invention provides a stable, liquid, substantially nonaqueous detergent comprising:at least one imidoperacid with the structure ##STR1## wherein R is C.sub.1-20 alkylene, R.sup.1 and R.sup.2 are individually H or C.sub.1-6 alkyl or alkenyl, or R.sup.1 and R.sup.2 join to form a heterocycle, said imidoperacid being solubilized in a liquid nonionic surfactant. The stable liquid detergent has excellent oxidant and phase stability and, if enzymes are present, maintains proficient enzyme activity.
    Type: Grant
    Filed: October 9, 1992
    Date of Patent: May 16, 1995
    Assignee: The Clorox Company
    Inventors: Gregory van Buskirk, Donna L. Tavares, Thomas B. Ottoboni
  • Patent number: 5409640
    Abstract: A personal cleansing product comprising:(a) from about 0.1% to about 20% of anionic surfactant,(b) from about 0.1% to about 20% of amphoteric surfactant,(c) from about 0.5% to about 25% of a vegetable oil adduct and,(d) water.The vegetable oil adduct can be made by Dies-Alder addition of a conjugated, elaidinized form of the vegetable oil with acrylic acid, fumaric acid or maleic anhydride. The preferred adduct is maleated soybean oil. The compositions provide excellent in-use and efficacy benefits including cleansing and lathering as well as improved mildness and skin conditioning.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: April 25, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Michel J. Giret, Anne Langlois, Roland P. Duke
  • Patent number: 5399280
    Abstract: Detergent compositions comprising a surfactant system that is either (1) a mixture of zwitterionic detergent surfactant and/or amphoteric (non-zwitterionic) detergent surfactant with nonionic detergent surfactant; or (2) short chain nonionic detergent surfactant; a suds reducing amount of a suds controlling alkoxylated material of the formula: C.sub.n (PO).sub.x (EO).sub.y (PO).sub.z in which C.sub.n is a hydrocarbon group containing, n carbon atoms, n is a number from about 6 to about 12, x is a number from about 1 to about 6, y is a number from about 4 to about 15, and z is a number from about 4 to about 25; optional, but preferred, hydrophobic cleaning solvent; and polycarboxylate, especially dicarboxylate, detergent builder, provide superior cleaning of all of the soils commonly found in the bathroom while maintaining a desirable low suds profile and good rinsing properties. The compositions have a pH of from about 1 to about 5.5, preferably from about 2 to about 4 when the dicarboxylate builder is used.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: March 21, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Ricky A. Woo, James E. Gray
  • Patent number: 5399296
    Abstract: Disclosed are solid, concentrated, amine oxide surfactant compositions containing amine oxide- maleic acid salts. The molar ratio of maleic acid to amine oxide in such salts is about a 1:1. The salts are soluble in water at 25.degree. C. at a pH of above the pKa of the amine oxide. Also disclosed is a process for preparing such solid amine oxide surfactant compositions, which process comprises admixing maleic acid and amine oxide surfactants in at least about a 1:1 molar ratio, at a pH of at least about 1 units less than the pKa of the amine oxide, to thereby form a visible precipitate therein. The precipitate is separated from the mixture, preferably by mechanical means, and dried. The dried precipitate is a maleic acid-amine oxide salt which can be incorporated into cleaning products, especially solid or granular cleaning products, as a solid, concentrated source of amine oxide surfactant.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: March 21, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Thomas J. Wierenga, Raymond D. Young
  • Patent number: 5393449
    Abstract: This invention comprises a personal cleansing stamped synbar with improved processing based on an ultra mild, good foaming, alkyl glyceryl ether sulfonate and a co-surfactant acyl isethionate processing aid.
    Type: Grant
    Filed: February 11, 1992
    Date of Patent: February 28, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Neil W. Jordan, Wayne E. Eccard, James R. Schwartz
  • Patent number: 5391326
    Abstract: A phosphate-free granular laundry detergent having a cleaning performance comparable to that of a premium phosphate-containing laundry detergent has a surfactant content of 1-30% and a detergent builder content of at least 50% by weight and contains:(A) as its sole surfactant, a mixture of 20-98% by weight of an ethoxylated fatty alcohol corresponding to the formula Z(OCH.sub.2 CH.sub.2).sub.
    Type: Grant
    Filed: July 26, 1993
    Date of Patent: February 21, 1995
    Assignee: Albemarle Corporation
    Inventors: Kim R. Smith, James E. Borland, Terry Crutcher, Joe D. Sauer
  • Patent number: 5389306
    Abstract: Disclosed is a process for making solid formulations containing amine oxide surfactants. Maleic acid, or a water soluble salt thereof, is admixed with an aqueous liquid amine oxide formulation, which formulation preferably contains from about 20% to about 40% by weight of an amine oxide surfactant. The molar ratio of maleic acid to amine oxide surfactant is at least about 1:1. Admixture pH is maintained at or below, or reduced to at least, about 1 unit below the pKa of the amine oxide to form a visible precipitate therein. The precipitate is separated from the mixture, preferably by mechanical means, and dried. The dried precipitate is a maleic acid-amine oxide salt which can be incorporated into cleaning products, especially solid or granular cleaning products, as a source of amine oxide surfactant.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: February 14, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Thomas J. Wierenga, Raymond D. Young
  • Patent number: 5387373
    Abstract: A stable aqueous detergent composition is provided in liquid or gel form containing from 10 to 80% by weight of an active detergent mixture comprising primary alkyl sulphate in an amount of 15 to 75% by weight of the active detergent plus betaine and/or amine oxide in an amount of 10 to 40% by weight of the active detergent mixture. Primary alkyl sulphate having chains of 10 or 11 carbon atoms provides at least 25% by weight of the primary alkyl sulphate present. The betaine and/or amine oxide is at least two thirds of the amount by weight of any primary alkyl sulphate having carbon atom chains of 12 carbon atoms or longer. The C.sub.10 and/or C.sub.11 alkyl sulphate is surprisingly effective as a detergent in such compositions despite higher water solubility than longer chain alkyl sulphate. It can enhance mildness compared to longer chain alkyl sulphate, and can replace or partially replace alkyl ether sulphate. Nonionic detergent may be included to enhance mildness further.
    Type: Grant
    Filed: January 25, 1993
    Date of Patent: February 7, 1995
    Assignee: Unilever Patent Holdings B.V.
    Inventor: Appaya R. Naik
  • Patent number: 5384063
    Abstract: Detergent compositions comprising a surfactant system that is either (1) a mixture nonionic and zwitterionic detergent surfactants; (2) a mixture of nonionic and amphoteric (non-zwitterionic) detergent surfactants; or (3) short chain nonionic detergent surfactant; optional hydrophobic cleaning solvent; and polycarboxylate, especially dicarboxylate, detergent builder provide superior cleaning of all of the soils commonly found in the bathroom. The compositions have a pH of from about 1 to about 5.5, preferably from about 2 to about 4 when the dicarboxylate builder is used. The compositions are in the form of aqueous liquids.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: January 24, 1995
    Assignee: The Procter & Gamble Company
    Inventors: Ricky Ah-Man Woo, Michel J. Carrie, William A. Cilley, Ronald A. Masters, Daniel W. Michael, Eddy Vos
  • Patent number: 5374370
    Abstract: Aluminosilicates in the form of P type zeolites are used as detergency builders and have a silicon to aluminium ratio not greater than 1.33, preferably above 0.9. These zeolites will usually have a calcium binding capacity of at least 150 mg CaO per gram of anhydrous aluminosilicate. A preferred form of the zeolite P has a silicon to aluminium ratio up to 1.15, and preferably above 0.9, with a tetragonally distorted cubic crystal structure. A process of the preparation of these zeolite P builders is described.
    Type: Grant
    Filed: February 2, 1993
    Date of Patent: December 20, 1994
    Assignee: Unilever Patent Holdings B.V.
    Inventors: Graham T. Brown, Theo J. Osinga, Michael J. Parkingston, Andrew T. Steel
  • Patent number: 5362413
    Abstract: The invention provides novel low temperature detergent mull compositions comprising:A detergent composition which comprises (a) solid builder, (b) liquid surfactant and, optionally, (c) one or more adjuncts, in the form of a low-temperature wash water dispersible, phase stable mull whose solid phase consists essentially of particulate solid builder having an average particle size greater than 10 microns and whose liquid phase consists essentially of at least one non-ionic surfactant, wherein said liquid phase has a pour point of less than 75.degree. F., thereby rendering said mull readily dispersible in cold wash water, and wherein said mull is rendered phase stable by the presence thereby of (i) a weight percent amount of said particulate builder which exceeds the weight percent of said liquid nonionic surfactant, or (ii) 0.1% to 5% by weight of the mull of added water, or (iii) both.
    Type: Grant
    Filed: January 14, 1991
    Date of Patent: November 8, 1994
    Assignee: The Clorox Company
    Inventors: Edward J. Kaufmann, James R. Wiersig, James F. Wilts
  • Patent number: 5346642
    Abstract: A fiber conditioning composition, which is preferably a shampoo for human hair, in stable and pearlescent liquid or semi-liquid or gel condition, is an emulsion or dispersion which includes a surfactant, a water insoluble fiber conditioning agent, a long chain saturated primary alcohol or derivative thereof, which stabilizes the emulsion or suspension and makes it pearlescent, and an aqueous medium, which may also contain other components of such fiber conditioning and shampoo compositions. In the preferred shampoos an anionic detergent is present, which is preferably a mixture of higher fatty alcohol sulfate and higher fatty alcohol ethoxylate sulfate, the long chain saturated primary alcohol (or derivative) is of an average of 30 to 40 carbon atoms (ethoxylated such alcohols may also be employed, at least in part) and the water insoluble conditioning agent is a silicone (very preferably a certain type of aminosilicone), a polyethylene, a paraffin, an isoparaffin, a microcrystalline wax, a C.sub.
    Type: Grant
    Filed: December 3, 1992
    Date of Patent: September 13, 1994
    Assignee: Colgate-Palmolive Company
    Inventors: Amrit M. Patel, Clarence R. Robbins
  • Patent number: 5342549
    Abstract: Detergent compositions comprising a hydrocarbyl-amidoalkyl enebetaine synthetic detergent surfactant; cleaning solvent; and buffer provide superior filming/streaking and good cleaning of hard to remove grease soils. Preferred compositions contain at least one cosurfactant. The compositions can be used to clean glass as well as for general cleaning purposes.
    Type: Grant
    Filed: June 7, 1993
    Date of Patent: August 30, 1994
    Assignee: The Procter & Gamble Company
    Inventor: Daniel W. Michael
  • Patent number: 5318728
    Abstract: Low-sudsing detergent compositions comprise an N-alkyl polyhydroxy fatty acid amide surfactant, wherein the N-alkyl substituent is at least C.sub.2, preferably C.sub.3 -C.sub.8. Such compositions are useful under cleaning conditions where excessive sudsing may be problematic.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: June 7, 1994
    Assignee: The Procter & Gamble Company
    Inventors: Athanasios Surutzidis, Jean-Pol Boutique, Yi-Chang Fu, Bruce P. Murch, Daniel S. Connor, Jeffrey J. Scheibel
  • Patent number: 5302314
    Abstract: This invention relates to aqueous suspensions of water-insoluble inorganic materials on a silica basis and insoluble in water, which are in finely subdivided form, stabilized with at least one organic polymeric material constituted by a partially crosslinked acrylic polymer or copolymer.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: April 12, 1994
    Assignee: Enimont Augusta Industriale
    Inventors: Claudio Troglia, Giancarlo Barbero
  • Patent number: 5288431
    Abstract: This invention relates to homogeneous liquid laundry detergent compositions containing polyhydroxy fatty acid amide, silicone antifoam composition, and anionic, nonionic or amphoteric surfactant. The silicone antifoam composition includes polyethylene glycol or a copolymer of polyethylene-polypropylene glycol having a solubility in water at room temperature of more than about 2 weight %.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: February 22, 1994
    Assignee: The Procter & Gamble Company
    Inventors: Alan C. Huber, Rajan K. Panandiker
  • Patent number: RE35000
    Abstract: A liquid bleaching composition is acidic with a .[.PH.]. .Iadd.pH .Iaddend.value of 1.5 to 6 and improved in stability. It comprises:(a) 0.5 to 10% by weight of hydrogen peroxide,(b) 0.1 to 20% by weight of an anionic surfactant,(c) 0.1 to 20% by weight of a nonionic surfactant,(d) 0.05 to 5% by weight of a polyacrylic acid having an average molecular weight of 1,000 to 100,000 or a salt thereof and/or a maleic polymer having an average molecular weight of 500 to 100,000, and(e) 0.0001 to 1% by weight of a polyphosphoric acid, a salt thereof, an amino phosphonic acid, a salt thereof, or a diphosphonic acid or a salt thereof.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: July 25, 1995
    Inventors: Muneo Aoyagi, Kazuhiro Takanashi