Abstract: A vehicle fuel system includes a vapor recovery canister containing at least two carbon beds. Each carbon bed is configured to capture hydrocarbon material associated with fuel vapor discharged from a vehicle fuel tank into the canister.
Type:
Grant
Filed:
August 10, 2015
Date of Patent:
July 4, 2017
Assignee:
Stant USA Corp.
Inventors:
John Brian Anderson, Matthew F Bischoff, John C Long, II, Michael S Brock
Abstract: This invention refers to a microporous crystalline material of zeolitic nature that has, in its calcined state and in the absence of defects in its crystalline matrix manifested by the presence of silanols, the empirical formula x(M1/nXO2):yYO2:gGeO2:(1?g)SiO2 in which M is selected between H+, at least one inorganic cation of charge +n, and a mixture of both, X is at least one chemical element of oxidation state +3, Y is at least one chemical element with oxidation state +4 different from Si, x takes a value between 0 and 0.2, both included, y takes a value between 0 and 0.1, both included, g takes a value between 0 and 0.5, both included that has been denoted ITQ-55, as well as a method for its preparation. This invention also relates to uses of the crystalline material of zeolitic nature for adsorption of fluid components, membrane separation of fluid components, storage of fluid components, and catalysis of various conversion reactions.
Type:
Grant
Filed:
June 19, 2015
Date of Patent:
July 4, 2017
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Edward W. Corcoran, Jr., Pavel Kortunov, Charanjit S. Paur, Peter I. Ravikovitch, Yu Wang, Avelino Corma Canos, Fernando Rey Garcia, Susana Valencia Valencia, Angel Cantin Sanz, Miguel Palomino Roca
Abstract: The present invention relates to a carbon dioxide capture apparatus having a temperature swing adsorption mode for selective separation of carbon dioxide from flue gases. The carbon dioxide capture apparatus comprises: a carbon dioxide sorption column including a carbon dioxide adsorption unit in which adsorption of carbon dioxide from flue gases occurs; a carbon dioxide desorption column connected to the carbon dioxide sorption column and including a carbon dioxide desorption unit in which desorption of the adsorbed carbon dioxide occurs; a carbon dioxide absorbent repeatedly adsorbing and desorbing carbon dioxide while circulating through the carbon dioxide sorption column and the carbon dioxide desorption column; and a heat exchange unit in which heat exchange occurs between the absorbent after carbon dioxide adsorption and the absorbent after carbon dioxide desorption.
Type:
Grant
Filed:
March 12, 2014
Date of Patent:
July 4, 2017
Assignee:
KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
Inventors:
Yong Ki Park, Won Choon Choi, Na Young Kang, Hwi Min Seo
Abstract: Systems, equipment and methods suitable for drying a gas, for example a compressed gas, that utilize a drying cycle during which the gas flows through one or more dryer tanks and a desiccant material therein adsorbs a liquid entrained in the compressed gas to produce a dried compressed gas. A regeneration cycle is employed during which a purge gas flows through a purge gas dryer tank. During one or more phases of the regeneration cycle, a desiccant material within the purge gas dryer tank is employed to adsorb water vapor entrained in the purge gas to produce a dried purge gas, which is then directed through the dryer tank as part of the regeneration cycle performed on the desiccant materials within the dryer tanks.
Type:
Grant
Filed:
April 21, 2016
Date of Patent:
June 27, 2017
Assignee:
The Fischer Group, Inc.
Inventors:
Norman-David Paul Fischer, Julie Ann Fischer
Abstract: The present invention relates to a nitrogen adsorbent having nitrogen selective adsorptivity by including an organic-inorganic hybrid nanoporous material having a coordinatively unsaturated metal site with density of 0.2 mmol/g to 10 mmol/g in a skeleton, surface or pore; and use thereof, such as a device separating nitrogen from a gas mixture containing nitrogen and methane, a pressure swing adsorption separation device and a temperature swing adsorption separation device for separating nitrogen provided, a method for separating nitrogen and methane from a gas mixture containing nitrogen and methane, a device for separating nitrogen, oxygen or argon, a method for separating nitrogen, oxygen or argon from a gas mixture containing nitrogen, oxygen or argon, and a method for preparing nitrogen or high purity inert gas all separated from a gas mixture containing nitrogen and inert gas.
Type:
Grant
Filed:
September 25, 2015
Date of Patent:
June 27, 2017
Assignee:
Korea Research Institute of Chemical Technology
Inventors:
Jong-San Chang, Young Kyu Hwang, Ji Woong Yoon, Do-Young Hong, U-Hwang Lee, Sukyung Lee, Kyung Ho Cho, Dong Won Hwang, Youn-Sang Bae, Seung-Joon Lee
Abstract: This invention concerns a method for recovering carbon monoxide and carbon dioxide from Fischer-Tropsch off-gas by feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed, and discharging effluent, optionally rinsing the column and the adsorbent bed by feeding carbon dioxide and discharging effluent until at least 60% of the carbon monoxide that was present in the bed is discharged, pressurizing the column and adsorbent bed with carbon dioxide, rinsing the column and the adsorbent bed by feeding carbon dioxide, until at least 60% of the methane and optionally an amount equal to at least 50% of the carbon dioxide present at the commencement of this rinsing step is discharged, rinsing the column and adsorbent bed by feeding a mixture of hydrogen and nitrogen, pressurizing the column and adsorbent bed by feeding a mixture of hydrogen and nitrogen. With this method a feed comprising at least 50 vol % carbon monoxide can be produced.
Abstract: Sour syngas treatment apparatuses and processes for treating a sour syngas stream are provided herein. In an embodiment, a process for treating a sour syngas stream that includes sulfur components and carbon dioxide includes absorbing the sulfur components and carbon dioxide from the sour syngas stream in a primary liquid/vapor phase absorption stage with a solvent to produce a liquid absorbent stream. The liquid absorbent stream includes the solvent, the sulfur components, and carbon dioxide. A portion of the sulfur components from the liquid absorbent stream is directly oxidized in the presence of a direct oxidation catalyst to produce elemental sulfur and a recycle stream. The recycle stream includes an unconverted portion of the sulfur components and carbon dioxide. The recycle stream is recycled for further absorption of the unconverted portion of the sulfur components and carbon dioxide through liquid/vapor phase absorption.
Type:
Grant
Filed:
April 9, 2015
Date of Patent:
June 20, 2017
Assignee:
UOP LLC
Inventors:
Lubo Zhou, Bart Beuckels, Ernest James Boehm
Abstract: Embodiments of the present disclosure provide for multi-component metal-organic materials (MOMs), systems including the MOM, systems for separating components in a gas, methods of separating polarizable gases from a gas mixture, and the like.
Type:
Grant
Filed:
October 31, 2013
Date of Patent:
June 13, 2017
Assignee:
University of South Florida
Inventors:
Michael Zaworotko, Mona H. Mohamed, Sameh Elsaidi
Abstract: A method for hydrogen production by pressure swing adsorption that can increase the recovery efficiency of an adsorption target component while enabling an off-gas to be appropriately supplied to a combustion device is provided that can achieve a cost reduction and an increase in the efficiency of the combustion operation.
Abstract: The present invention generally relates to a method to enhance heat transfer in the temperature swing adsorption process (TSA) and to an intensified TSA process for gas/liquid purification or bulk separation. Helium is designed as the heat carrier media to directly bring heat/cool to the adsorbent bed during the TSA cycling process. With helium's superior heat conductivity, the time consuming regeneration steps (warming, regeneration and precooling) of TSA process can be significantly reduced and allowing for the TSA process to be intensified.
Type:
Grant
Filed:
June 9, 2015
Date of Patent:
June 13, 2017
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Hai Du, Scot E. Jaynes, Steven R. Falta, Neil A. Stephenson
Abstract: An oxygen concentrating apparatus includes: at least one adsorption bed which is filled with absorbent capable of selectively adsorbing nitrogen relative to oxygen; an air supplier which supplies pressurized air to the adsorption bed; a flow channel regulating valve unit which regulates flow channels by allowing the pressurized air to be supplied to the adsorption bed from the air supplier and by allowing the air to be discharged from the adsorption bed to be depressurized such that a nitrogen adsorption process and a nitrogen desorption process are alternately performed; and a water removing unit which separates water from the pressurized air supplied from the air supplier and removes the separated water. The flow channel regulating unit and the water removing unit are at least partially housed within a single housing.
Type:
Grant
Filed:
September 9, 2015
Date of Patent:
June 13, 2017
Assignee:
OXUS CO., LTD.
Inventors:
Tae Soo Lee, Hyun Seong Kim, Shin Kyu Han, Seung Kwon Oh, Kang Han Lee
Abstract: Disclosed is a metal-organic framework composite including a host metal-organic framework, and nano metal-organic frameworks embedded in the host metal-organic framework. The host metal-organic framework and the nana metal-organic frameworks include different metals and organic ligands. The metal-organic framework composite has a structure in which the nano metal-organic frameworks are embedded in the host metal-organic framework. Due to this structure, defects are formed at the interfaces between the host metal-organic framework and the nano metal-organic frameworks, enabling the application of the metal-organic framework composite to gas storages with greatly improved gas storage efficiency. The metal-organic framework composite can be used as a gas adsorbent with very high efficiency due to its very large specific surface area. Also disclosed are a method for producing the metal-organic framework composite and a gas storage using the metal-organic framework composite.
Type:
Grant
Filed:
January 28, 2016
Date of Patent:
June 13, 2017
Assignee:
KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY
Inventors:
Jeung Ku Kang, Kyung Min Choi, Jung Hyo Park
Abstract: Provided are apparatus and systems having a lessened pulsation through the use of a pulse flow control mechanism. In performing a cyclical swing adsorption process, various streams are passed through adsorbent bed units during various steps in the swing adsorption process. The pulse flow control mechanism is utilized within a manifold of one of the streams to lessen pulsation within the manifold that results from performing the various steps.
Type:
Grant
Filed:
July 2, 2015
Date of Patent:
June 13, 2017
Assignee:
ExxonMobil Upstream Research Company
Inventors:
Shwetha Ramkumar, Robert A. Johnson, Eduardo Mon, John W. Fulton
Abstract: A method of separating oxygen from an oxygen-containing fluid stream is disclosed, the method including the step of contacting the oxygen-containing fluid stream with an oxygen-selective zeolite adsorbent comprising at least 90% chabazite, wherein the chabazite is a single phase chabazite having an Si/Al ratio of 1.2 to 1.8. The single phase chabazite may comprise a mixture of at least two types of cations.
Type:
Grant
Filed:
February 22, 2016
Date of Patent:
June 6, 2017
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Garret Chi-Ho Lau, Qiao Zhao, Roger Dean Whitley, Erin Marie Sorensen, Charles Gardner Coe, William Jack Casteel, Jr., Geoffrey John Ochs, Christopher Robert Bongo, Marissa Ann Bonanno
Abstract: The vertical shaft fuel tank cap with a charcoal canister includes a fuel tank inner cap and a fuel tank outer cap. A hollow room or cavity with an upper opening is disposed in the center of the fuel tank inner cap. The fuel tank outer cap is above the fuel tank inner cap. The ventilating cap or vent cap is disposed in the cavity and divides the cavity into a filling cavity and a containing cavity. The air outlet leading the fuel vapor to the containing cavity is on the bottom of the containing room. The air passageway is between the outer walls of the vent cap and an inner wall of the containing cavity. The fuel-absorption substrate is disposed in the filling cavity. The filtering performance of charcoal powder can be enhanced since it is exempted from long-time fuel soaking.
Abstract: Pressure shift adsorption (PSA) process for producing a gas stream enriched with compound X from a feed gas stream, using N adsorbers with N?5, each adsorber being subjected to a pressure cycle having a phase time corresponding to the duration of the pressure cycle divided by the number of adsorbers, and a series of active steps, characterized in that each adsorber n follows the pressure cycle with an offset of one phase time with respect to the pressure cycle of the adsorber n?1 with n?N, and during each phase time, only one active step or a part of active step takes place.
Type:
Grant
Filed:
November 24, 2014
Date of Patent:
June 6, 2017
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Inventors:
Elise Renou, Christian Monereau, Celine Carriere
Abstract: An apparatus for recovering volatile liquid vapor from an air-volatile liquid vapor mixture includes a vapor blower unit having a first inlet and a first outlet. In addition the apparatus includes a vapor adsorption unit including a second inlet and a second outlet and a solid adsorbent adsorption unit including a third inlet and a third outlet. Further the apparatus includes a vapor regeneration unit including an intake port and a discharge port as well as a conduit system. The conduit system connects the first outlet to the second inlet, the second outlet to the third inlet, the third outlet to the intake port and the discharge port to the first inlet.
Abstract: A method including exposing a gas mixture comprising a noble gas to a metal organic framework (MOF), including an organic electron donor and an adsorbent bed operable to adsorb a noble gas from a mixture of gases, the adsorbent bed including a metal organic framework (MOF) including an organic electron donor.
Type:
Grant
Filed:
March 18, 2015
Date of Patent:
May 30, 2017
Assignee:
Sandia Corporation
Inventors:
Mark D. Allendorf, Jeffery A. Greathouse, Chad Staiger
Abstract: The purpose of/problem to be addressed by the present invention is to provide: an Fe(II)-substituted beta-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO2/Al2O3 ratio in this Fe(II)-substituted beta-type zeolite is equal to or more than 7 but less than 10. This Fe(II)-substituted beta-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4 mmol/g of the Fe(II)-substituted beta-type zeolite. It is preferable that the Fe(II)-substituted beta-type zeolite be produced using a method in which a beta-type zeolite having an SiO2/Al2O3 ratio of equal to or more than 7 but less than 10 is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the beta-type zeolite to carry Fe(II) ions.
Type:
Grant
Filed:
July 16, 2013
Date of Patent:
May 23, 2017
Assignee:
UniZeo Co., Ltd.
Inventors:
Masaru Ogura, Keiji Itabashi, Tatsuya Okubo, Shanmugam Palani Elangovan
Abstract: A canister has a housing whose one end is provided with a charge port and a purge port and whose other end is provided with a drain port and a heater. The housing is divided into a no-heat-application section on a charge port and purge port side and a heat-application section on a drain port side. The heat-application section is further divided into at least two spaces of a first space located on the drain port side and a second space located on a no-heat-application section side. The first space is filled with an activated carbon whose BWC is equal to or greater than 6 g/dL and less than 10 g/dL, and the second space is filled with an activated carbon whose BWC is 13 g/dL or greater. The heater heats whole of the heat-application section including the first space and the second space.