Abstract: The present invention relates to a pressure-sensitive adhesive composition including a compound having a substituent represented by the general formula (1) described in the specification, in which when each of R1 and R2 in the substituent represented by the general formula (1) represents a hydrogen atom, a distance between an oxygen atom of —OR1 and an oxygen atom of —OR2 is 1.31 ? or more and 4.70 ? or less, a pressure-sensitive adhesive layer formed of the pressure-sensitive adhesive composition, and a pressure-sensitive adhesive sheet comprising the pressure-sensitive adhesive layer.

Abstract: An acrylic alloy composition that can be 3-D printed by a material extrusion additive manufacturing process, an acrylic filament that has a very uniform diameter useful in the extrusion additive manufacturing process, acrylic articles made from the acrylic alloy composition by a material extrusion additive process, and a material extrusion additive manufacturing process for producing the acrylic articles. The acrylic alloy composition is an alloy of an acrylic polymer, and a low melt viscosity polymer, such as polylactic acid. The alloy may optionally be impact modified, preferably with hard core core-shell impact modifiers.

Abstract: Methods for making a supported chromium catalyst are disclosed, and can comprise contacting a silica-coated alumina containing at least 30 wt. % silica with a chromium-containing compound in a liquid, drying, and calcining in an oxidizing atmosphere at a peak temperature of at least 650° C. to form the supported chromium catalyst. The supported chromium catalyst can contain from 0.01 to 20 wt. % chromium, and typically can have a pore volume from 0.5 to 2 mL/g and a BET surface area from 275 to 550 m2/g. The supported chromium catalyst subsequently can be used to polymerize olefins to produce, for example, ethylene-based homopolymers and copolymers having high molecular weights and broad molecular weight distributions.

Abstract: The invention provides a built-in micro-interface oxidation system for preparing terephthalic acid from p-xylene. The oxidation system includes a first reactor, a rectifying tower and a second reactor which are sequentially connected. A first outlet is disposed on a side wall of the first reactor; a first inlet is disposed on a side wall of the second reactor; a material inlet is disposed on a side wall of the rectifying tower; and a material outlet is disposed at a bottom of the rectifying tower. The first outlet is connected with the material inlet of the rectifying tower; the first inlet is connected with the material outlet of the rectifying tower. Micro-interface units are arranged in the first reactor and the second reactor for dispersing and crushing air into bubbles. Through disposing micro-interface units in reactors, problems of high energy consumption, high raw material consumption and low reaction efficiency are solved.

Abstract: Methods for the hydrogenation of aromatic-containing polymers are described. A method includes hydrogenation of polymers by contacting a polymer solution that includes an aromatic-containing polymer and a mixture of a non-polar solvent and a polar solvent having a dielectric constant greater than 7.6 at 25° C. and a non-polar solvent having a dielectric constant of 5 or less at 25° C. with a hydrogenation catalyst to produce polymer composition that includes at least one hydrogenated and/or at least one partially hydrogenated aromatic ring. The polar to non-polar solvent volume ratio ranges from 10:90 to 80:20.

Abstract: The invention is directed to a tissue-adhesive multi-arm polymer comprising a core from which polymeric arms extent, which polymeric arms are substituted with a hydroxyl-substituted aromatic group based on compounds such as dopamine, L-DOPA, D-DOPA, tyramine, noradrenaline and/or serotonin. In addition, the invention is directed to a caprolactam blocked hydroxyl-substituted aromatic compound, suitable for the preparation of the tissue-adhesive multi-arm polymer and to the method for the preparation of the tissue-adhesive multi-arm polymer.

Abstract: The invention discloses a micro-interface strengthening reaction system for preparing poly-?-olefin, which includes: a first polymerization reactor and a second polymerization reactor that are connected with each other in sequence, wherein a first micro-interface generator is disposed outside the first polymerization reactor, and a second micro-interface generator is disposed inside the second polymerization reactor. A bottom of the second polymerization reactor is provided with a discharge port, and the discharge port is connected with a hydrogen halide removal tower. By disposing the first micro-interface generator in the first polymerization reactor while disposing the second micro-interface generator in the second polymerization reactor, on the one hand it increases the mass transfer area between the gas phase and the liquid phase material, improves reaction efficiency and reduces energy consumption, and on the other hand it results in a higher evenness of the poly-?-olefin and improved product quality.

Abstract: The invention relates to a process for production of terpolymers, in particular for the polymerization of propylene, and two other distinct monomers chosen from a group comprising ethylene and a C4-C12 ?-olefin in a horizontal stirred reactor comprising an agitated bed and several reaction zones for forming polymer particles.

Abstract: The present invention provides a paint formulation that has good storage stability and weather resistance, and that is capable of forming a paint film having excellent water resistance, chemical resistance such as gasohol resistance and fuel resistance, and adhesion. The paint formulation comprises an acid-modified polyolefin (A) and a tackifier (B), and satisfies the following (a) and (b): (a) the acid-modified polyolefin (A) has crystallinity; and (b) the tackifier (B) has a double-bond equivalent of 40 or more, as defined by the formula: double-bond equivalent=weight average molecular weight/number of double bonds in a molecule, or contains no double bond.

Abstract: Described herein are polymers comprising a terminus having a structure according to formula (1): wherein R is a fluorinated alkane, alkene or alkyne, a fluorinated aromatic, a fluorinated cycloalkane or cylcoalkene, a fluorinated heteroaromatic, or a fluorinated heterocyclic.

Abstract: The invention relates to a process for producing a polypropylene composition using a first extruder comprising successive zones comprising a first zone, a second zone, a third zone and a fourth zone and a second extruder comprising successive zones comprising a first zone and a second zone, the process comprising the steps of: 1a) introducing a first propylene-based polymer in the first zone of the first extruder, 1b) melt mixing the first propylene-based polymer in the second zone of the first extruder, 1c) adding an additive masterbatch to the mixture of step 1b) in the third zone of the first extruder and 1d) melt-mixing the mixture of step 1c) in the fourth zone of the first extruder to obtain the polypropylene composition, wherein the maximum temperature in the fourth zone of the first extruder is lower than the maximum temperature in the second zone of the first extruder and is lower than 240° C.

Abstract: Apparatus for carrying out a catalytic gas-phase olefin polymerization having a first polymerization zone for growing polymer particles to flow upward under fast fluidization or transport conditions, a second polymerization zone for the growing polymer particles to flow downward, and a gas/solid separation zone; wherein the second polymerization zone has an upper part being connected to the separation zone and a lower part being connected to the upper part; wherein the ratio of the height H01 of the separation zone to the diameter D01 of the separation zone is 2.5 to 4.5.

Abstract: A process (and a related system) for collecting samples of a polymerization catalyst or of a catalyst-containing polymer from an operation unit, having an upper end and a lower end, of a polymerization plant, including the steps of: a) extracting a prefixed amount of product from the lower end of the operation unit through a discharge valve; b) directing the product towards a filtering unit through an inlet valve; c) flushing an inert gas through the filtering unit; d) outgassing the filtering unit, through the outlet valve; and e) displacing the filtering unit, for collecting the sample.

Abstract: The electrochemical energy conversion system of the present disclosure includes an anode, a cathode, and an ion exchange membrane including a polymer having an aromatic polymer chain and an alkylated substrate including an alkyl chain, and at least one ionic group. The alkylated substrate is bound to at least one aromatic group in the polymer chain via Friedel-Crafts alkylation of the at least one aromatic group. The alkylation reaction utilizes a haloalkylated tertiary alcohol or a haloalkylated alkene as a precursor. In the presence of an acid catalyst, a carbocation is generated in the precursor which reacts with the aromatic rings of the polymer chain. The at least one ionic group is then replaced with a desired cationic or anionic group using a substitution reaction. The membranes exhibit advantageous stability achieved through a simplified and scalable reaction scheme.

Abstract: Provided are a cycloolefin polymer simultaneously having a high refractive index, a low Abbe number, and low birefringence and also a method of producing this cycloolefin polymer and an optical element in which this cycloolefin polymer is used. The cycloolefin polymer is a polymer, or hydrogenated product thereof, said polymer comprising a structural unit derived from a naphthyl group-containing alicyclic compound (A) represented by following formula (1), in a specific proportion. In formula (1), one of R2a to R5a is a naphthyl group and remaining groups among R2a to R5a and R1a are as defined in the specification.

Abstract: The present invention provides compounds, especially polymeric compounds, having preferably at least one spiro or piperidine structural unit, a process for preparation thereof and the use thereof as anion conducting membrane.

Abstract: A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

Abstract: Disclosed herein is a buckling actuator, comprising: a first electrode; a second electrode; and a film of a dielectric elastomeric material having a first surface and a second surface sandwiched between the first and second electrodes, wherein the material is formed by the random block copolymerisation of a polymeric material comprising silicon or nitrogen atoms that has two or more acrylate or vinyl end groups, and a polar polymeric material having two or more acrylate or vinyl end groups. Also disclosed herein is a method of forming said dielectric elastomeric material.

Abstract: Disclosed are a proton exchange membrane made of a crystalline sulfonated polyimide block copolymer, a preparation method and use thereof. The crystalline sulfonated polyimide block copolymer has a chemical structure as shown in Formula (I), in which Ar1 group is an aromatic group containing a naphthyl group, Ar2 group is an aromatic group containing at least one sulfonate group, and x is in the range of 5-100, m is in the range of 1-200, and n is in the range of 5-500.

Abstract: The invention pertains to a process for the manufacture of a polymer electrolyte membrane based on a fluoropolymer hybrid organic/inorganic composite, to a polymer electrolyte obtained thereof and to uses of said polymer electrolyte and membranes obtained therefrom in various applications, especially in electrochemical and in photo-electrochemical applications.