Patents Examined by Fred M Teskin
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Patent number: 11643572Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.Type: GrantFiled: December 11, 2020Date of Patent: May 9, 2023Assignee: AGC Inc.Inventors: Taiki Hoshino, Kiyotaka Takao, Kazue Toda, Kenji Ishizeki, Akira Isobe
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Patent number: 11646433Abstract: A continuous automated process and production line for preparing an acid doped polybenzimidazole, PBI, polymer membrane film for use in a fuel cell, the process having a washing stage, a drying procedure, and a doping stage.Type: GrantFiled: January 12, 2021Date of Patent: May 9, 2023Assignee: BLUE WORLD TECHNOLOGIES HOLDING APSInventors: Mads Bang, Denys Gromadskyi, Jakob Bork, Larysa Hromadska
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Patent number: 11633729Abstract: A polymeric bead having radius R wherein the polymer comprises 0.3% to 20% by weight, based on the weight of the polymer, of polymerized units of one or more multifunctional vinyl monomer and 80% to 99.7% by weight, based on the weight of the polymer, of polymerized units of one or more monofunctional vinyl monomer, (a) wherein the polymerized units of multifunctional vinyl monomer have radial distribution factor MR of 0.9 to 1.1, and (b) wherein some of the vinyl groups in the polymerized units of multivinyl monomer are unreacted, and the unreacted vinyl groups have a radial distribution factor VR of 2.5 or higher.Type: GrantFiled: September 25, 2018Date of Patent: April 25, 2023Assignee: DDP SPECIALTY ELECTRONIC MATERIALS US 5, LLCInventors: Kenneth Laughlin, Alfred K. Schultz, John Reffner, Oscar David Redwine, Robert L. Sammler, Andrew M. Savo
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Patent number: 11629222Abstract: The present invention is directed to devices and methods for monitoring the purity of monomers, adjusting the polymerization conditions, and consequently improving a polymerization reaction process. In one method, monomer purity is estimated using an on-line evaluation by raising the temperature of the monomer formulation having a defined melting point to a first elevated temperature at least 20° C. above a preset melting point for a selected monomer formulation; cooling the monomer formulation at a controlled cooling rate in the range from about 0.5 to 50° C. per minute; measuring at least one critical property selected from the group consisting of a) crystallization peak temperature at the onset of crystallization, b) an area under the crystallization peak, which represents the heat or enthalpy of crystallization, ?Hc and combinations thereof, comparing the at least one of the selected critical properties measures relative to such properties for standard setting monomer formulations.Type: GrantFiled: July 1, 2019Date of Patent: April 18, 2023Assignee: Ethicon, Inc.Inventor: Sasa Andjelic
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Patent number: 11618840Abstract: In an additive for an epoxy adhesive and an epoxy adhesive composition for construction including same, the additive for an epoxy adhesive is formed by atomic transfer radical polymerization (ATRP) of a polyacrylate of which one terminal is halogenated, as an arm-polymer, and a diacrylate-based compound or a dimethacrylate-based compound, as a cross-linker, and comprises a star polymer of a star-shape having a core/shell structure including a core formed by the polymerization of the cross-linker and a shell formed by a portion of the arm-polymer.Type: GrantFiled: May 9, 2018Date of Patent: April 4, 2023Assignees: PUSAN NATIONAL UNIERSITY INDUSTRY-UNIVERSITY COOPERRATION FOUNDATION, KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATIONInventors: Young Sun Choe, Joona Bang, Jun Soo Moon
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Patent number: 11613614Abstract: The present disclosure provides Lazarev reactor that sustains reaction of two dimensional polymerization on the interface of two immiscible solutions A and B carrying components of reaction to the interface where reaction takes place and produces film of two dimensional polymer layers that are pulled out of reactor and rolled up on roll after drying excess of solvent out.Type: GrantFiled: March 19, 2020Date of Patent: March 28, 2023Assignee: 86 SOLAR INC.Inventors: Pavel Ivan Lazarev, Alexander P. Lazarev
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Patent number: 11608392Abstract: The present invention relates to a process for polymerization of a monomer, and in particular whereby polymer particles are transferred from an upstream polymerization reactor, which process comprises: (a) discharging a mixture comprising polymer particles and reactive gases, which reactive gases comprise hydrogen, from the upstream reactor, (b) transferring the polymer particles and reactive gases into a first chamber which is in open communication with a second chamber during the transfer such that the polymer particles pass through the first chamber into the second chamber, (c) keeping the first and second chamber in open communication for a time period, t, after completing transfer of the polymer particles to the second chamber, and (d) subsequently isolating the second chamber from the first chamber and transferring the polymer particles from the second chamber into a downstream vessel.Type: GrantFiled: November 17, 2020Date of Patent: March 21, 2023Assignee: INEOS USA LLCInventor: Robert Norman Mohn
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Patent number: 11610698Abstract: An electrical wire includes a conductor and an insulating layer that covers the conductor and that is cross-linked. The insulating layer is a cross-linked product of a resin composition including (a) a base polymer containing polyolefin and a compatibilizer, (b) a photoradical generator of 0.5 parts by mass or more and 3 parts by mass or less relative to the 100 parts by mass of the base polymer, and (c) a reactive monomer of 1 part by mass or more and 5 parts by mass or less relative to the 100 parts by mass of the base polymer. A relative dielectric constant of the insulating layer is less than 2.5.Type: GrantFiled: June 3, 2020Date of Patent: March 21, 2023Assignee: HITACHI METALS, LTD.Inventors: Hideyuki Suzuki, Katsuya Iikai, Takuya Oriuchi
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Patent number: 11608390Abstract: Disclosed herein is a system for solution polymerization comprising a reactor system that is operative to receive a monomer and to react the monomer to form a polymer; a plurality of devolatilization vessels located downstream of the reactor system, where each devolatilization vessel operates at a lower pressure than the preceding devolatilization vessel; and a heat exchanger disposed between two devolatilization vessels and in fluid communication with them, where the heat exchanger has an inlet port temperature of 100° C. to 230° C., an outlet port temperature of 200° C. to 300° C., an inlet port pressure of 35 to 250 kgf/cm2 and an outlet port pressure of 20 to 200 kgf/cm2; and wherein the polymer solution remains in a single phase during its residence in the heat exchanger.Type: GrantFiled: May 30, 2019Date of Patent: March 21, 2023Assignee: DOW GLOBAL TECHNOLOGIES LLCInventors: Maria Pollard, Robert D. Swindoll, Pradeep Jain, Alec Y. Wang, Jorge Rubalcaba, Shrikant Dhodapkar, Sean W. Ewart, Bradley K. Blanchard, George W. Haun, Jr., Michael J. Zogg, Jr.
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Patent number: 11603418Abstract: The present invention relates to a process for reducing the volatile organic compound (VOC) content of plastomers the process comprising the steps of subjecting the plastomer in granular form containing VOCs which is contained in an aeration vessel to a gasflow, and withdrawing granular plastomer from the aeration vessel which has a lower content of VOCs, wherein the average particle size of the granular plastomer is greater than 2.5 mm, preferably greater than 2.7 mm, more preferably greater than 3.0 mm, wherein the gas has a minimum temperature of at least 26° C. measured at a gas inlet of the aeration vessel, and a maximum temperature of 4° C. below the Vicat temperature (10N, ISO 306) of the granular plastomer or 35° C. measured at the gas inlet of the aeration vessel, whatever value is lower, and wherein at least a part of the withdrawn granular plastomer is recirculated to the aeration vessel.Type: GrantFiled: May 28, 2019Date of Patent: March 14, 2023Assignee: Borealis AGInventors: Mohammad Al-Haj Ali, Michiel Bergstra, Charlotta Weber, Gert Stijnen
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Patent number: 11603420Abstract: The present invention relates to a method for preparing ethylene vinylacetate copolymer that can improve the mechanical strength of copolymer by controlling the polymerization conditions using an autoclave reactor.Type: GrantFiled: October 30, 2018Date of Patent: March 14, 2023Inventors: Dae Young Shin, Eun Jung Joo, Jin Ho Jung, Choong Hoon Lee, Kyung Soo Park, Yutaek Sung
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Patent number: 11597783Abstract: The invention relates to a process for the preparation of a multimodal polyolefin polymer in a first polymerization reactor and a second polymerization reactor connected in series, wherein a first polyolefin polymer is prepared in the first polymerization reactor in suspension in the presence of hydrogen and a second polyolefin polymer is prepared in the second polymerization reactor in the presence of a lower concentration of hydrogen than in the first polymerization reactor, the process comprising: a) withdrawing a suspension of solid polyolefin particles in a suspension medium from the first polymerization reactor, wherein the suspension medium comprises hydrogen and a hydrocarbon mixture having an initial boiling point of at least 50° C. and a final boiling point of at most 120° C.; b) feeding the suspension to a flash drum having a pressure controlled by a vacuum pump, wherein the pressure of the flash drum is less than 0.Type: GrantFiled: May 14, 2019Date of Patent: March 7, 2023Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Job Daniel Guzman-Carrazco, Peter Groefsema, Maryam Tammadoni, Victor Mattheij
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Patent number: 11591503Abstract: A composition includes an epoxy-based curable adhesive having at least one an epoxy resin modified acrylonitrile-butadiene copolymer and at least one thermoplastic elastomer. The at least one thermoplastic elastomer is present in the curable adhesive as a penetrating polymer network. Further, an expandable article is composed of the composition, a reinforcing element includes a support and an expandable article, a method for reinforces cavities of structural components, and the composition is used as a shape memory material.Type: GrantFiled: January 25, 2019Date of Patent: February 28, 2023Assignee: SIKA TECHNOLOGY AGInventors: Karsten Frick, Alina Keller
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Patent number: 11578147Abstract: In a process for producing an olefin polymer, at least one olefin monomer is polymerized in a polymerization reactor to produce a particulate polymer product containing hydrocarbon impurities including unreacted monomer and other C1 to C8 hydrocarbons. The polymer product is contacted with a gas-containing stream in a stripping vessel under conditions effective to strip hydrocarbon impurities from the polymer product and produce a stripped particulate polymer product and a gaseous first effluent stream containing inert gas and hydrocarbon impurities. The stripped particulate polymer product is recovered and the atmosphere adjacent the stripped particulate polymer product is sensed with a photoionization detector configured to ionize C4 to C8 hydrocarbons. The amount of the gas-containing stream supplied to the stripping vessel is then adjusted based upon such sensing.Type: GrantFiled: March 8, 2021Date of Patent: February 14, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Michael D. Lucas, Philip W. Livanec, Christian T. Lund
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Patent number: 11578145Abstract: A method of operating a dump tank of a polymer production process by transferring all or a portion of a content of a polymerization reactor into the dump tank, wherein the reactor contents comprise solid polymer, and liquid and gaseous non-product components, and removing at least a portion of the liquid and gaseous non-product components from the dump tank by: reducing a pressure of the dump tank, subjecting the solid polymer to a first cleaning stage comprising heating the solid polymer by introducing a first heated treatment gas into the dump tank, and subjecting the solid polymer to a second cleaning stage comprising purging the solid polymer by introducing a second heated treatment gas into the dump tank.Type: GrantFiled: May 7, 2021Date of Patent: February 14, 2023Assignee: Chevron Phillips Chemical Company LPInventors: Joseph A. Curren, James E. Hein, Ralph W. Romig, Ai-Fu Chang
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Patent number: 11578157Abstract: The invention relates to an efficient process for the preparation of isoolefin polymers such as polyisobutene or butyl rubber by polymerization of isobutene and optionally further monomers in the presence of an initiator system prepared by continuously contacting at least one boron or aluminium compound and at least one initiator.Type: GrantFiled: July 6, 2018Date of Patent: February 14, 2023Assignee: ARLANXEO DEUTSCHLAND GMBHInventors: Hanns-Ingolf Paul, Rolf Feller, Udo Wiesner, Carsten Kreuder, Adam Gronowski, Ricarda Leiberich, Joachim Ritter
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Patent number: 11578144Abstract: Compositions for removing contaminants from plastics processing equipment are described herein. The compositions may include a polymeric carrier component, an oxidizing agent, an abrasive and/or a gas agent. Methods of preparing the compositions described herein and methods of removing contaminants from plastics processing equipment are also described.Type: GrantFiled: May 23, 2019Date of Patent: February 14, 2023Assignee: 2569924 Ontario Inc.Inventors: Joseph Albert Turner, Bryon Wolff
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Patent number: 11572423Abstract: The present disclosure provides methods and systems for introducing an activator to a polymerization reactor. The methods may include introducing liquid activator to a mixing vessel or an inline mixer and mixing aliphatic hydrocarbon solvent to form an activator solution which is introduced to a polymerization reactor. The systems may include a storage vessel, a mixing vessel or inline mixer configured to mix a liquid activator with a hydrocarbon solvent, and a polymerization reactor. The present disclosure also provides a process for producing a polyolefin. The process may include introducing liquid activator to an inline mixer and mixing an aliphatic hydrocarbon solvent with the liquid activator to form an activator solution. The process may include introducing the activator solution, a catalyst, and an olefin feed to a polymerization reactor.Type: GrantFiled: December 1, 2020Date of Patent: February 7, 2023Assignee: EXXONMOBIL CHEMICALS PATENTS INC.Inventors: Aaron H. Reed, Rong Ma, Catherine A. Faler
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Patent number: 11559776Abstract: The present invention relates to a method for improving the cooling capacity of a gas solids olefin polymerization reactor by splitting the fluidization gas and returning part of the fluidization gas to the reactor into the bottom zone of the reactor and another part of the fluidization gas directly into the dense phase formed by particles of a polymer of the at least one olefin suspended in an upwards flowing stream of the fluidization gas in the middle zone of the reactor.Type: GrantFiled: October 25, 2018Date of Patent: January 24, 2023Assignee: BOREALIS AGInventors: Günter Weickert, Eric-Jan Prinsen, Klaus Nyfors, Erno Elovainio, Vasileios Kanellopoulos
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Patent number: 11555116Abstract: Provided herein is a copolymer of ethylene and acrylate(s) having a melt flow index (MFI) greater than or equal to 50 g/10 minutes, obtained by free-radical copolymerisation under high pressure carried out in a tubular reactor, and methods of using the same. Also provided herein is a thermoplastic composition, particularly intended to be extruded or injection moulded, having one or more copolymers of ethylene and acrylate(s) at a content ranging from 0.1 to 20 wt. %, and one or more thermoplastic polymers.Type: GrantFiled: March 26, 2019Date of Patent: January 17, 2023Assignee: SK Global Chemical Co., Ltd.Inventors: Paul Coupillaud, Sebastien Quinebeche, Alain Bouilloux