Abstract: A method of forming a substrate in a thermal compression bonding process that permit substantially greater amounts of fillers than previously accomplished. The method employs a dispersion of a thermoplastic binder and a filler. The dispersion is then thermally compression bonded to form a substrate. Lightweight fillers are one example of fillers that are ideally suited for the thermal compression bonding through the use of a dispersion. Such lightweight fillers enable the formation of a substrate with a very low and desirable specific gravity.
Abstract: The present invention relates to an olefin polymerization process for producing propylene copolymer composition (P), wherein propylene, C4 to C10 ?-olefin and optionally ethylene are reacted in the presence of a Ziegler-Natta catalyst in a multistage polymerization process comprising at least two polymerization reactors, wherein the copolymer composition is bimodal with respect to the content of C4 to C10 ?-olefin and, if present, to ethylene. Further, the invention is directed to the propylene copolymer composition being bimodal with respect to the content of C4 to C10 ?-olefin and optionally to ethylene, and use of said propylene copolymer compositions for producing articles.
Type:
Grant
Filed:
December 27, 2016
Date of Patent:
September 29, 2020
Assignee:
Borealis AG
Inventors:
Kristin Reichelt, Kauno Alastalo, Klaus Nyfors, Luigi Resconi
Abstract: Apparatuses and processes that produce multimodal polyolefins, and in particular, polyethylene resins, are disclosed herein. This is accomplished by using two reactors in series, where one of the reactors is a multi-zone circulating reactor that can circulate polyolefin particles through two polymerization zones optionally having two different flow regimes so that the final multimodal polyolefin has improved product properties and improved product homogeneity.
Type:
Grant
Filed:
December 27, 2018
Date of Patent:
September 22, 2020
Assignee:
CHEVRON PHILLIPS CHEMICAL COMPANY LP
Inventors:
Joseph A. Curren, Rebecca A. Gonzales, Scott E. Kufeld, Joel A. Mutchler, Eric J. Netemeyer, Jamie N. Sutherland, Paul J. Deslauriers, Jeffrey S. Fodor
Abstract: Described herein are compositions having an eight-membered monocyclic unsaturated hydrocarbon, methods and system to separate the eight-membered monocyclic unsaturated hydrocarbon at from a hydrocarbon mixture including additional nonlinear unsaturated C8H2m hydrocarbons with 4?m?8, by contacting the hydrocarbon mixture with a 10-ring pore molecular sieve having a sieving channel with a 10-ring sieving aperture with a minimum crystallographic free diameter greater than 3 ? and a ratio of the maximum crystallographic free diameter to the minimum crystallographic free diameter between 1 and 2, the molecular sieve having a T1/T2 ratio?20:1 wherein T1 is an element independently selected from Si and Ge, and T2 is an element independently selected from Al, B and Ga, the 10-ring pore molecular sieve further having a counterion selected from NH4+, Li+, Na+, K+ and Ca++.
Type:
Grant
Filed:
August 15, 2019
Date of Patent:
September 22, 2020
Assignee:
CALIFORNIA INSTITUTE TECHNOLOGY
Inventors:
Julia A. Kornfield, Mark E. Davis, Ming-Hsin Wei, Simon C. Jones
Abstract: A process to form an ethylene-based polymer comprising polymerizing a mixture comprising ethylene, in the presence of a free-radical initiator, and in a tubular reactor system comprising at least two ethylene-based feed streams, and a reactor configuration that comprises at least three reaction zones; and the inlet pressure of the first zone is <3200 Bar; and the ethylene conversion >28%, and an m value from 20 mole % to 70 mole %, where m=mol % of ethylene-based feed stream to the first zone, based on total moles of ethylene-based feed streams fed to the reactor configuration; and the ratio (Q) of a “MWDB of a broad polymer polymerized, to a “MWDN of a narrow polymer polymerized, is as follows: {(T)*(?2.3×log(m)+7)}?Q?{(T)*(?13.0×log(m)+29.8)}; at the same melt index; and “T” is the “chain transfer activity ratio” as described herein.
Type:
Grant
Filed:
June 22, 2017
Date of Patent:
September 15, 2020
Assignee:
Dow Global Technologies LLC
Inventors:
Otto J. Berbee, Nhi T. Y. Dang, Cornelis J F Hosman, Joaquin Flores
Abstract: A latex of a synthetic rubber, wherein the content rate of a particle having a particle size of 5 ?m or more in a particle size distribution of a synthetic rubber particle included in the latex, as determined on a number basis, is less than 3,000 ppm by weight. A latex of a synthetic rubber is excellent in mechanical stability and can provide a film molded article such as a dip molded article excellent in tensile strength and elongation.
Abstract: The present invention relates to a polyamide molding compound comprising the following components or consisting of these components: (A) 50 to 95 wt % of a mixture comprising the specific polyamides (A1) and (A2); (B) 5 to 50 wt % of at least one glass filler having a refractive index in the range from 1.510 to 1.539; (C) 0 to 10 wt % of at least one additive; wherein the weight proportions of the components (A) to (C) add up to 100% by weight; wherein the content of (A1) in the mixture (A) is >50 wt %, if the ratio is ?2/?1>1 and the content of (A2) in the mixture (A) is >50 wt %, if the ratio is ?2/?1?1, where ?1=n(A1)?n(B) applies and ?2=n(B)?n(A2) applies; wherein the transparent polyamides (A1) and (A2) have a transparency of at least 90% and a haze of at most 3%; and wherein the mixture (A) has a transparency of at least 88% and a haze of at most 5%. The present invention furthermore relates to molded bodies composed of these polyamide molding compounds.
Abstract: The present invention relates to a method of preparing a vinyl chloride-based polymer, which includes inducing the nucleation of particles by adding a mercaptan-based chain transfer agent to a monomer composition including a vinyl chloride-based monomer and a preliminary polymerization initiator (preliminary polymerization); and preparing a polymer by mixing a vinyl chloride-based monomer and the particle nuclei and adding a main polymerization initiator (main polymerization). In the preparation method, a vinyl chloride-based polymer having a uniform molecular weight distribution and a desired number average molecular weight may be provided by controlling a degree of polymerization of a vinyl chloride-based polymer prepared in such a way that dispersibility is ensured by adjusting the point of time to add the mercaptan-based chain transfer agent to the point of time to reach a specific conversion rate of the preliminary polymerization.
Type:
Grant
Filed:
September 19, 2017
Date of Patent:
September 8, 2020
Assignee:
LG CHEM, LTD.
Inventors:
Se Woong Lee, Seong Yong Ahn, Kun Ji Kim, Hyun Kyou Ha
Abstract: An adhesive mass consisting of (a) at least one elastomer component, of a polybutadiene-polyvinyl aromatic block copolymer type, having a proportion with respect to the total adhesive mass of 42 to 55 wt. % and having a diblock proportion with respect to the total block copolymer content of 32 to 55 wt. %, (b) at least one adhesive resin, which is a hydrocarbon resin having a DACP value of at least +50° C. and at most +85° c, (c) optionally at least one soft resin having a proportion of 0 to 15 wt. % with respect to the total adhesive mass, and (d) optionally further additives, which adhesive mass is particularly suitable for adhering on rough substrates such as plaster or woodchip wallpaper.
Type:
Grant
Filed:
October 13, 2016
Date of Patent:
September 1, 2020
Assignee:
TESA SE
Inventors:
Thilo Dollase, Tanja Altenwegner, Julia Garbers
Abstract: (Meth)acrylate polymers are provided which have a narrow molecular weight distribution on a higher molecular weight side and can impart high shear viscosity stability to lubricating oils. A (meth)acrylate polymer (A) includes specific structural units and is such that in a differential molecular weight distribution curve obtained by gel permeation chromatography (GPC) measurement which shows the polystyrene-equivalent molecular weight of the (meth)acrylate polymer (A) normalized so that the intensity of the peak-top polystyrene-equivalent molecular weight M (t) is 1, the value a represented by a=Log Mh (t1/2)?Log M (t) is not more than 0.12 wherein Mh (t1/2) is the polystyrene-equivalent molecular weight at a point on a higher molecular weight side where the intensity is 0.5.
Abstract: Described herein are methods for increasing strength of blown films, by forming the films using a film blowing apparatus where the film is formed from a blend of a first polymeric material and a renewable carbohydrate-based polymeric material having particular characteristics. By using such a blend, and ensuring that the film blowing apparatus is operated at a high blow up ratio of at least 2.0, and/or using a narrow die gap of no more than 500 microns, Applicant has discovered that increased strength in the film can be obtained, as compared to where (i) the renewable carbohydrate-based polymeric material is not included or (ii) where the film is blown at lower blow up ratios and/or wider die gaps.
Abstract: Provided is a latex-based composition capable of being applied to a surface to form a strippable coating on the surface that can encapsulate substances. The composition may include a latex polymer component and an anti-freeze component, and have a viscosity of less than or equal to about 90 cP. The composition may be delivered as an aerosol spray or a misting agent.
Abstract: The present invention relates to a plasticizer composition, a resin composition and a method of preparing the same, particularly, provides an environmentally-friendly plasticizer composition, which is suitable for use as an application to resins for food packaging, has excellent transparency, color and pressure-sensitive adhesion, and is capable of maintaining/improving mechanical properties such as tensile strength, an elongation rate and hardness when used as a plasticizer of the resin composition, and a resin composition including the same.
Type:
Grant
Filed:
June 30, 2017
Date of Patent:
August 25, 2020
Assignee:
LG CHEM, LTD.
Inventors:
Hyun Kyu Kim, Mi Yeon Lee, Yun Ki Cho, Jeong Ju Moon, Joo Ho Kim, Seok Ho Jeong
Abstract: A curable composition capable of manufacturing a cured product having a high refractive index is provided. The curable composition contains a polymerizable compound represented by formula (1) and inorganic particles. In formula (1), La represents a divalent linking group, and the divalent linking group includes at least one of a divalent aromatic group, a divalent polycyclic aliphatic group and an alkylene group having an aromatic group, Ar represents an aromatic group, and R represents an aromatic group optionally having one or more substituents or a polycyclic aliphatic group optionally having one or more substituents.
Type:
Grant
Filed:
September 28, 2018
Date of Patent:
August 25, 2020
Assignees:
NIKON CORPORATION, ESSILOR INTERNATIONAL
Abstract: The present disclosure relates to a preparation method for an acrylic acid-based polymer. According to the preparation method for an acrylic acid-based polymer of the present disclosure, unreacted monomers may be reduced and a high quality acrylic acid-based polymer can be prepared. In addition, it is not necessary to increase the time or the temperature in the polymerization step or the aging step, thereby maintaining the high productivity.
Type:
Grant
Filed:
January 12, 2017
Date of Patent:
August 18, 2020
Assignee:
LG Chem, Ltd.
Inventors:
Jung Sup Han, Young Sam Kim, Chang Bum Ko, Dong Jo Ryu, Im Gyu Kim, Hyo Min Kim
Abstract: The present invention relates to a plasticizer composition and a resin composition including the same, and can provide a plasticizer composition in which three types of terephthalate-based materials and three types of cyclohexane 1,4-diester-based materials are mixed, and by which environmental friendliness can be secured, mechanical properties such as tensile strength and an elongation rate, physical properties such as migration properties and volatile loss can be improved to levels equal to or higher than those of existing products, and effects of improving processability and plasticizing efficiency can be expected, and a resin composition including the same.
Type:
Grant
Filed:
September 5, 2017
Date of Patent:
August 4, 2020
Assignee:
LG CHEM, LTD.
Inventors:
Hyun Kyu Kim, Mi Yeon Lee, Yun Ki Cho, Jeong Ju Moon, Joo Ho Kim, Seok Ho Jeong
Abstract: Ethylene-based polymers comprising the following properties: (A) a density less than 0.9190 g/cc; (B) a hexane extractable level that meets the following equation: hexane extractable level ?A+B [log(12)], where A=2.65 wt %, and B—0.25 wt %[log (dg/min)]; based on total weight of the ethylene-based polymer; (C) a G? (at G?=500 Pa, 1 70° C.) that meets the following equation: G??C+D [log(12)], where C=150 Pa, and D=?60 Pa/[log(dg/min)]; and (D) a melt index (12) from 0.7 to 20 dg/min; are made in high pressure tubular process that comprises at least three reaction zones with the peak polymerization temperature of the first reaction zone ?320° C. and the peak polymerization temperature of the last reaction zone ?290° C.
Type:
Grant
Filed:
June 16, 2016
Date of Patent:
August 4, 2020
Assignee:
Dow Global Technologies LLC
Inventors:
Otto J. Berbee, Cornelis F. J. Den Doelder, Stefan Hinrichs, Teresa P. Karjala, John O. Osby
Abstract: The present invention relates to a process for determining a set of one or more operating conditions of an olefin polymerization reactor for the synthesis of a polyolefin in slurry condition, comprising the steps of: a1) introducing a polyolefin into a volume of at least one diluent, said diluent being agitated by a powered agitator at a first temperature T1; b1) monitoring the power consumed by the agitator as a function of the concentration, for at least three concentrations C1, C2, and Cn, which are different from each other; c1) repeating steps a1) and b1) at two or more subsequent temperatures T2 and Tn, which are different from each other and from T1; d1) determining from the power consumed by the agitator as a function of concentration, said set of one or more stable operating conditions for the synthesis of the polyolefin in the olefin polymerization reactor.
Abstract: A method for producing a material, in which method the following products are incorporated so as to produce a mixture: a polymer; and particles including silicon and carbon. A feature of the method is that during the incorporation of the particles, the particles have an apparent density of more than 0.3 grams per cubic centimeter. Also, in embodiments, the particles have an average diameter which is less than or equal to 100 nanometers, preferably with a standard deviation which is less than 50% of the average diameter.