Abstract: The present invention relates to a process to produce high purity strontium sulfate and strontium carbonate from subterranean brines. The present disclosure also relates to chemical precipitations of subterranean brines to isolate strontium from divalent cations, such as calcium and barium. Such precipitations include the use of sulfate and subsequent solids separations and washing of the precipitate. In a latter step in the strontium carbonate process, a metathesis reaction with a carbonate is performed upon the strontium sulfate to produce strontium carbonate while allowing optional recycling of the sulfate. An additional rinse with acid or water of the strontium sulfate may be performed prior to metathesis to increase the purity of the resulting strontium carbonate.
Abstract: The invention provides a method of producing a metal oxyhydride, capable of synthesizing the metal oxyhydride under reaction conditions close to atmospheric pressure, and excellent in productivity and cost. The method of producing a metal oxyhydride of the present invention includes reacting an oxide with a metal hydride in a hydrogen atmosphere. A non-oxygen element constituting the oxide comprises only one kind of non-oxygen element. A pressure condition of the reaction is 0.1 to 0.9 MPa, and a temperature of the reaction is 500 to 1000° C.
Abstract: There are provided processes for preparing a metal hydroxide comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium, copper, magnesium and aluminum, the process comprising: reacting a metal sulfate comprising (i) and optionally (ii) with lithium hydroxide, sodium hydroxide and/or potassium hydroxide and optionally a chelating agent to obtain a solid comprising the metal hydroxide and a liquid comprising lithium sulfate, sodium sulfate and/or potassium sulfate; separating the liquid and the solid from one another to obtain the metal hydroxide; submitting the liquid to an electromembrane process for converting the lithium sulfate, sodium sulfate and/or potassium sulfate into lithium hydroxide, sodium hydroxide and/or potassium hydroxide respectively; reusing the sodium hydroxide for reacting with the metal sulfate; and reusing the lithium hydroxide for reacting with the metal sulfate and/or with the metal hydroxide.
Type:
Grant
Filed:
May 22, 2020
Date of Patent:
April 15, 2025
Assignee:
NEMASKA LITHIUM INC.
Inventors:
Thomas Bibienne, Nicolas Laroche, Jean-François Magnan, Guy Bourassa, Mathieu Charbonneau, Mickaël Dollé, David Deak
Abstract: A method for preparing a supercritical fluid by deep-sea pressure is provided and belongs to the technical field of supercritical fluid preparation. The method includes the following steps of: placing a low-pressure fluid in a closed flexible container, sending the closed flexible container down to a location of a sea at a depth where a seawater pressure meets a requirement by using a powered or unpowered traction device, leaving the flexible container standing still until a volume of the flexible container does not change, wrapping the closed flexible container with a rigid pressure-bearing container, transferring the closed flexible container to the sea surface by the powered or unpowered traction device, and taking out the fluid in the flexible container as supercritical fluid. Then the supercritical fluid is produced. Therefore, the process of preparing supercritical (high pressure) liquid in the deep-sea is safer and more stable than the preparation way on land.
Type:
Grant
Filed:
December 14, 2021
Date of Patent:
January 28, 2025
Assignees:
Tianjin University of Commerce, Tianjin University
Inventors:
Guanyi Chen, Junyu Tao, Yadong Ge, Beibei Yan, Yunan Sun, Zhanjun Cheng, Jian Li, Lan Mu, Yongjie Hu
Abstract: A method of producing purified bis(fluorosulfonyl) imide includes providing a liquid mixture including bis(fluorosulfonyl) imide and fluorosulfonic acid and then contacting the liquid mixture with gaseous ammonia. The gaseous ammonia reacts with the fluorosulfonic acid to produce ammonium fluorosulfate. The method further includes separating the liquid mixture from the ammonium fluorosulfate.