Abstract: Metal additives to hydrocarbon feed streams give improved hydrocarbon liquid yield during thermal cracking thereof. Suitable additives include metal over-bases and metal dispersions and the metals suitable include, but are not necessarily limited to, magnesium, calcium, aluminum, zinc, silicon, barium, cerium, and strontium overbases and dispersions. Particularly useful metals include magnesium alone or magnesium together with calcium, barium, strontium, boron, zinc, silicon, cerium, titanium, zirconium, chromium, molybdenum, tungsten, and/or platinum. In one non-limiting embodiment, no added hydrogen is employed. Coker feedstocks are a particular hydrocarbon feed stream to which the method can be advantageously applied, but the technique may be used on any hydrocarbon feed that is thermally cracked.
Abstract: The present invention provides a grease composition which prevents frictional wear of a lubricating surface in a high load-applied state or in a state in which sliding motion is generated and is durable for a long time, a method of manufacturing capable of easily determining an addition ratio of an extreme-pressure agent of the grease composition, and a rolling bearing in which the grease composition is enclosed. A grease composition is composed by adding a thickener and an extreme-pressure agent containing sulfur in a molecular structure thereof to base oil. The extreme-pressure agent is added to the base oil so that a product of an amount (mgS/g) of active sulfur contained in the extreme-pressure agent and an addition amount (wt %) of the extreme-pressure agent with respect to an entire amount of the grease composition is in a range of 3 to 13.
Abstract: A gear oil composition is provided. The composition comprises a synergistic amount of an isomerized base oil having consecutive numbers of carbon atoms and less than 10 wt % naphthenic carbon by n-d-M for the gear oil composition to have a traction coefficient at 15 mm2/s. of less than 0.030 and a pressure viscosity coefficient of at least 15.0 at 80° C., 20 Newton load, and 1.1 m/s rolling speed. In one embodiment, the sufficient amount of isomerized base oil ranges from 20 to 80 wt. % based on the total weight of the gear oil composition.
Abstract: Disclosed is a catalyst composition based on an indium salt and an organic ionic liquid, a process for making the catalyst composition, and uses thereof. The catalyst composition is particularly suitable for Lewis acid catalysed electrophilic aromatic substitution reactions, such as Friedel-Crafts alkylation reactions an Friedel-Crafts acylation reactions.
Type:
Grant
Filed:
October 2, 2002
Date of Patent:
April 19, 2011
Assignee:
The Queen's University of Belfast
Inventors:
Kenneth Richard Seddon, Christopher Hardacre, Barry Joseph McAuley
Abstract: A catalyst for converting hydrocarbons includes, based on the weight of the catalyst, 1-60% by weight of a zeolite, 0.1-10% by weight of an assistant catalytic component, 5-98% by weight of a thermotolerant inorganic oxide, and 0-70% by weight of a clay in terms of the oxide. The zeolite is a MFI-structured zeolite-containing phosphor and transition metal(s) or a mixture of the zeolite and a macroporous zeolite, which comprises, based on the weight of the mixture, 75-100% by weight of said MFI-structured zeolite containing phosphor and transition metal(s) and 0-25% by weight of the macroporous zeolite. In terms of the mass of the oxide, the MFI-structured zeolite containing phosphor and transition metal(s) has the following anhydrous chemical formula: (0-0.3)Na2O.(0.3-5.5)Al2O3.(1.0-10)P2O5.(0.7-15)M1xOy.(0.01-5)M2mOn(0-10)RE2O3.(70-97)SiO2??I or (0-0.3)Na2O.(0.3-5)Al2O3.(1.0-10)P2O5.(0.7-15)MpOq.(0-10)RE2O3.
Type:
Grant
Filed:
March 31, 2005
Date of Patent:
April 12, 2011
Assignees:
China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing Sinopec
Inventors:
Jun Long, Zhijian Da, Huiping Tian, Zhenyu Chen, Weilin Zhang, Xingtian Shu, Jiushun Zhang, Yuxia Zhu, Yujian Liu
Abstract: A universal, wireless, nano-optical voltmeter comprises an organic core having at least one voltage-sensitive dye and at least one polymeric shell substantially surrounding the organic core. The nano-optical voltmeter can detect electric fields in cells. The nano-optical voltmeter allows three-dimensional E field profiling throughout the entire volume of living cells. The nano-optical voltmeter may be calibrated externally and then applied for E field determinations inside any live cell or cellular compartment, with no further calibration steps.
Type:
Grant
Filed:
January 17, 2008
Date of Patent:
April 12, 2011
Assignee:
The Regents of the University Of Michigan
Inventors:
Martin A. Philbert, Katherine M. Tyner, Raoul Kopelman
Abstract: A lubricating oil composition having a total base number of more than 15 mg KOH/g including oil of lubricating viscosity; detergent; and at least one compound of the formula (I) and/or formula (II): wherein Ar and Ar? represent substituted or unsubstituted aromatic moieties; L and L? are linking moieties; each Y is independently —ORI?or H(O(CR12)n)yX—, wherein X is (CR1?2)z, O or S; R1 and R1? are H, alkyl or aryl; R1? is alkyl or aryl; each Y? is independently Z(O(CR22)n?)y?X?—, wherein X? is (CR2?2)z?, O or S; R2 and R2? are H, alkyl or aryl; Z is H, acyl, alkyl or aryl; z and z? are 1 to 10; n is 0 to 10 when X is (CR1?2)z and 2 to 10 when X is O or S; n? is 0 to 10 when X? is (CR2?2)z?, and 2 to 10 when X? is O or S; y and y? are 1 to 30; a and a? are 0 to 3; and m and m? are 1 to 100, with the proviso that in compounds of formula (I), at least one Ar moiety bears at least one group Y and that in compounds of formula (II), at least one Ar? moiety bears at least one group Y? in wherein Z is not H.
Type:
Grant
Filed:
July 3, 2007
Date of Patent:
April 12, 2011
Assignee:
Infineum International Limited
Inventors:
James Christian Dodd, Frederick Wein Girshick, Michael Dennis Hoey, Jeremy Roger Spencer, Jacob Emert, Tushar kanti Bera
Abstract: With a powdered lubricant composition by the invention, in addition to the blending of one of anhydrous, pentahydrate or decahydrate salt in sodium borate and one of sodium or calcium salt of fat acid, mixing calcium or lithium carbonate as an auxiliary lubricant can prevent sodium borate (Na2B4O7), solidified as amorphous after a tube-making process, from moisture absorbance, drying and crystallization to thereby suppress the formation of Na2B4O7.5H2O on inside surfaces of finished-product tubes, thus enabling to circumvent occurrence of the white scales. Concurrently, they provide good diffusivity toward the working surface of workpiece, thus enabling to prolong a life of the mandrel bar and to widely be adopted as the most suitable powdered lubricant for manufacturing seamless tubes by Mandrel Mill rolling.
Type:
Grant
Filed:
May 18, 2007
Date of Patent:
April 5, 2011
Assignee:
Sumitomo Metal Industries, Ltd.
Inventors:
Kenichi Sasaki, Sumio Iida, Shizuo Mori, Atsushi Ito
Abstract: The invention relates to a thermal conversion process for continuously producing hydrocarbon vapor and continuously removing a free-flowing coke. The coke, such as a shot coke, can be withdrawn continuously via, e.g., a staged lock hopper system.
Type:
Grant
Filed:
November 14, 2005
Date of Patent:
March 29, 2011
Assignee:
ExxonMobil Research & Engineering Company
Inventors:
Michael Siskin, Christopher P. Eppig, Glen E. Phillips, Te-Hung Chen, Charles J. Mart
Abstract: An FCC process producing lower NOx emissions during regeneration by using excess oxygen levels at less than or equal to about 0.5 mol-% and a plenum temperature above about 730° C. (about 1350° F.). The process may further include limiting the Pt content in the catalyst to less than or equal to about 0.5 ppm. NOx emissions, NO to NO2, produced through this process may be equal to or less than 25 ppmv. The process may also include adjusting the metal content of the feedstock for such metals as antimony, nickel, or vanadium. Additional variables for reducing NOx emissions that may be used in conjunction with this process may include increasing the flue gas residence time, injecting NH3 into the flue gas, adding or using NOx-reducing catalysts, increasing stripping of the catalyst, and increasing the catalyst zeolite to matrix ratio.
Type:
Grant
Filed:
September 29, 2006
Date of Patent:
March 29, 2011
Assignee:
UOP LLC
Inventors:
Robert Mehlberg, Frank Rosser, Jr., Zhihao Fei, Carl Stevens
Abstract: Suppression or enhancement of various properties of a liquid fluid is aimed by improving uniform dispersion of nanoparticles by means of making a state in which no oxidized film exists on the surfaces of the nanoparticles to be dispersed in the liquid fluid. The location of the liquid fluid is confirmed with ease by enhancing the brightness of light emission of the fluid through uniform dispersion of the nanoparticles in the liquid fluid containing a material having a flame reaction. In this way, as to liquid fluids utilized in various industries, it is possible to offer a technology to desirably enhance or suppress a property desired to be enhanced and a property desired to be suppressed among various properties that its constituents have.
Type:
Grant
Filed:
June 16, 2005
Date of Patent:
March 22, 2011
Assignee:
Japan Nuclear Cycle Development Institute
Abstract: The present invention provides a grease composition for use in constant velocity joints, which comprises the following components (a) to (g) and a constant velocity joint comprising the grease composition sealed or encapsulated therein: (a) a base oil; (b) a diurea thickener represented by the following general formula: R1NH—CO—NH—C6H4-p-CH2—C6H4-p-NH—CO—NHR2 wherein R1 and R2 each independently represents an alkyl group having 8 to 20 carbon atoms, an aryl group having 6 to 12 carbon atoms or a cycloalkyl group having 6 to 12 carbon atoms; (c) a molybdenum dialkyl dithiocarbamate insoluble in the base oil; (d) a molybdenum dialkyl dithiocarbamate soluble in the base oil; (e) molybdenum disulfide; (f) at least one member selected from the group consisting of calcium phenate and calcium sulfonate; and (g) a sulfur-containing extreme-pressure agent free of phosphorus.
Abstract: For manufacturing micro-structured reactors with passageways loaded with catalyst using the pre-coat method, a method is provided which comprises the following method steps: a) producing reactor layers having bonding areas as well as passageway areas in which the passageways are formed, b) applying at least one bonding layer onto the reactor layers in the bonding areas, c) loading the reactor layers in the passageway areas with the catalyst and d) bonding the reactor layers, the bonding layer being applied and masked before the reactor layers are loaded with the catalyst. As a result, it is ensured that the efficiency of the catalyst will not be affected during manufacturing. The reactor may be used as a methane and methanol reformer in particular.
Type:
Grant
Filed:
February 22, 2007
Date of Patent:
March 22, 2011
Assignee:
Atotech Deutschland GmbH
Inventors:
Olaf Kurtz, Ralph Herber, Christian Madry, Gerd Schäfer
Abstract: Provided are compounds of formula wherein R1 is t-octyl, AR is phenyl, R2 is an alkyl substituted carboxyl and m is 0, 1, or 2. Lubricating oils and hydraulic fluids comprising a polyol ester lubricant in combination with one or more compounds of formula I and methods for their use are also provided.
Abstract: The present invention relates to acrylic block copolymers synthesized by a controlled free-radical process, and their use as low temperature flow modifiers in oil-based compositions. They are especially useful in modifying the low temperature flow behavior in lubricating oils. The acrylic copolymers are especially useful as pour point depressants in lubricating oil.
Type:
Grant
Filed:
February 3, 2006
Date of Patent:
March 15, 2011
Assignee:
Arkema Inc.
Inventors:
Scott Schmidt, Peter Callais, Noah Macy
Abstract: Lubrication substrates are disclosed that have been treated with or that carry a lubricant for maintaining a paper shredder. The lubrication substrate is fed through the shredding mechanism of a paper shredder. Rather than requiring disassembly of the paper shredder, maintenance and lubrication can be performed by passing the lubrication substrate through the shredding mechanism. The lubrication substrates can take any of a variety of forms, and can be substantially rigid and/or stiff. The lubrication substrates can also include scented lubricants and decomposing agents. Paper shredders are also disclosed for use with the lubrication substrates. The paper shredders can have various means for identifying when lubrication is needed and/or when the cutting mechanism of the paper shredder is lubricated by a lubrication sheet. Paper shredders having a reservoir of lubricant for delivery to the cutting mechanism of the paper shredder are also disclosed.
Abstract: Urea grease composition for constant velocity joints is provided containing base oil, one or more urea thickener compounds, (A) one or more molybdenum sulphurized dialkyldithiocarbamates represented by general formula (I) wherein R1 and R2 are independently chosen from alkyl groups of from 1 to 24 carbons, m+n=4, m is from 0 to 3 and n is from 4 to 1, (B) triphenylphosphorothionate represented by formula (II) and (C) one or more stearic acid metal salts.
Abstract: A lubricated surface, a method for reducing wear between moving parts, and lubricants, and lubricant additive concentrates containing a wear reducing agent. The lubricated surface contains a base oil of lubricating viscosity, a hydrocarbon soluble titanium compound, a metal-free friction modifier and an amount of at least one hydrocarbon soluble magnesium compound effective to provide a reduction in surface wear greater than a reduction surface wear for a lubricant composition devoid of the titanium compound, metal-free friction modifier, and magnesium compound. The lubricant composition contains no more than about 800 ppm phosphorus and is devoid of calcium detergents and organic molybdenum compound.
Abstract: There is provided a process for selective isomerisation of C4+ paraffins using a catalyst comprising mixed aluminium, tungsten and zirconium oxides, and a hydrogenation/dehydrogenation component, such as palladium or other Group VIII metals. The feed may optionally also include shorter paraffins, aromatics or cycloparaffins.
Abstract: A lubricant composition for providing friction reducing properties and VI and solvency improving properties in a lubricant system is disclosed. The lubricant composition comprises a major amount of at least one base oil and an effective amount of a high viscosity polyester additive having a kinematic viscosity at 100° C. of at least about 2,500 mm2/s.
Type:
Grant
Filed:
March 20, 2007
Date of Patent:
February 15, 2011
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Marc-Andre Poirier, Kevin L. Crouthamel