Patents Examined by H. A. Feeley
  • Patent number: 4048384
    Abstract: The invention concerns the regulation of an electrochemical system of the Redox type. It consists in immersing three electrodes in a stream to or from a cell in the said Redox system. Two of the electrodes, referred to as measuring electrodes, are connected by two resistors defining a junction point therebetween. A direct current is applied across these electrodes. The potential of the other electrode, called the reference electrode, is compared with the potential of said junction point. The ratio between the resistors is determined so that the potentials of the said junction point and of the said reference electrode is equal, this being so for a determined power supplied by the said electrochemical system. Variation of the potential are used to regulate the flow of fuel and/or of oxidizing agent to the said electrochemical system. The invention is more particularly implemented in fuel cells using the Redox system containing anthraquinone 2-7 sodium disulphonate.
    Type: Grant
    Filed: April 14, 1976
    Date of Patent: September 13, 1977
    Assignee: Societe Generale de Constructions Electriques et Mecaniques "Alsthom et Cie"
    Inventors: Nicole Chillier-Duchatel, Bernard Verger
  • Patent number: 4048385
    Abstract: The component plates stacked in a filter press type structure in a repeated sequence of cathode, separator, anode and conductive plate are of cylindrical shape with an outer frame carrying the channels for supplying and withdrawing the reagents. Hollowed-out inlet and outlet portions communicating with appropriate channels pressing through the frames are provided for passing the reagents across the active portions of the components at a desired cross-feed angle between adjacent units, 30.degree. in one case and 60.degree. in another.
    Type: Grant
    Filed: February 2, 1976
    Date of Patent: September 13, 1977
    Assignee: Societe Generale de Constructions Electriques et Mecaniques "Alsthom et Cie"
    Inventor: Bernard Regnaut
  • Patent number: 4048383
    Abstract: A combination water electrolyzer and fuel cell for selectively storing and supplying energy while in a substantially fixed position, typically comprising a pan held in a substantially horizontal position, an aqueous alkaline electrolyte (e.g., NaOH) held within the pan at elevated temperature, means communicating with a supply of hydrogen and forming a container for the hydrogen within the pan, a thin nonporous corrosion resistant hydrogen diffusion negative electrode (e.g., PdAg) having a porous support positioned within the pan and having one surface on contact with the electrolyte and an opposite surface communicating with the hydrogen, means communicating with a supply of oxygen and furnishing the oxygen to a region contiguous with the exposed surface of the electrolyte, a thin porous corrosion resistant positive electrode (e.g.
    Type: Grant
    Filed: February 9, 1976
    Date of Patent: September 13, 1977
    Assignee: Battelle Memorial Institute
    Inventor: John E. Clifford
  • Patent number: 4048386
    Abstract: An electrochemical cell or battery in a monolithic form is produced, in which a series of planar sheet electrodes are disposed in a framework of a fibrous material which contains a thermosetting resin. The process for forming the cell or battery is also disclosed.
    Type: Grant
    Filed: August 11, 1976
    Date of Patent: September 13, 1977
    Assignee: Stamicarbon B.V.
    Inventors: Marinus Alfenaar, Rene L. E. Van Gasse
  • Patent number: 4048395
    Abstract: An improved lithium electrode structure comprises an alloy of lithium, silicon, and iron in specified proportions and a supporting current-collecting matrix in intimate contact with said alloy. The lithium electrode of the present invention is utilized as the negative electrode in a rechargeable electrochemical cell.
    Type: Grant
    Filed: August 18, 1976
    Date of Patent: September 13, 1977
    Assignee: Rockwell International Corporation
    Inventor: San-Cheng Lai
  • Patent number: 4048027
    Abstract: A process for producing electrolytic manganese dioxide by electrolyzing molten manganese nitrate hexahydrate at a temperature between about 115.degree. C. and 126.degree. C. and with an anodic current density of from about 140 to about 300 mA/cm.sup.2.
    Type: Grant
    Filed: March 30, 1976
    Date of Patent: September 13, 1977
    Assignee: Union Carbide Corporation
    Inventor: Seymour Senderoff
  • Patent number: 4046956
    Abstract: The output from a selective oxidizer is controlled by modifying the rate of oxidant input in accordance with the operating temperature of the selective oxidizer. In a preferred embodiment, wherein the selective oxidizer has a slow temperature response, gross adjustments to the oxidant feed flow rate are made as a function of the fuel feed flow rate into the selective oxidizer, in addition to the fine adjustments made as a function of temperature.
    Type: Grant
    Filed: May 27, 1976
    Date of Patent: September 6, 1977
    Assignee: United Technologies Corporation
    Inventor: Salvatore Fanciullo
  • Patent number: 4046652
    Abstract: P-Benzoquinone diketals of the formula ##STR1## wherein R is H, an alkyl group having from 1 to 4 carbon atoms or a halogen atom, preferably H, CH.sub.3, Cl or F,are prepared by anodic oxidation of benzene or alkoxybenzenes of the formula ##STR2## wherein R has the aforesaid meaning and R.sup.1 is an alkyl radical having of from 1 to 4 carbon atomsIn CH.sub.3 OH containingA. less than about 5% by weight of H.sub.2 O as well asB. about 0.2 to 15% by weight, calculated on the electrolyte, of at least a conducting salt selected from the group of ammonium and alkali fluorides, perchlorates, nitrates, tetrafluoroborates, hexafluorosilicates, hexafluorophosphates, benzene sulfonates, p-toluene sulfonates, quartenary ammonium and phosphonium fluorides as well as methylsulfates and additionallyC. optionally about 0.5 to 10% by weight, calculated on the electrolyte, of a base to be oxidized with difficulty, preferably 2,6-lutidine,At a known anode made of a conventinal material, at a temperature of from about -20.
    Type: Grant
    Filed: December 19, 1975
    Date of Patent: September 6, 1977
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rudolf Pistorius, Hans Millauer
  • Patent number: 4045307
    Abstract: A structure for switching electrical current, the structure comprising a switch having two pairs of terminals and two modes of operation. The structure, in addition, includes a first electrically conductive means for connecting the terminals of one pair together, and, a second electrically conductive means for connecting the terminals of the other pair together. Means are included for disconnecting the terminals of the above pairs, and a third electrically conductive means is provided for connecting one of the terminals of one pair to one of the terminals of the other pair.
    Type: Grant
    Filed: January 14, 1976
    Date of Patent: August 30, 1977
    Assignee: Aluminum Company of America
    Inventor: Bernard C. Turley
  • Patent number: 4045309
    Abstract: The energy balance in an aluminum reduction cell is controlled by measuring the temperature of the side lining of the cell, preferably at the level of the surface of the electrolyte, comparing the measured temperature with a reference temperature, and when the difference between the measured and reference temperatures exceeds a given value adjusting the depth of immersion of the cell anodes within the electrolyte.
    Type: Grant
    Filed: April 9, 1976
    Date of Patent: August 30, 1977
    Assignee: Norsk Hydro a.s
    Inventor: Jens Arvid Andersen
  • Patent number: 4045308
    Abstract: A method and apparatus for controlling the rate at which material is fed to a molten salt bath in a process utilizing the material to produce molten metal. The apparatus includes means for generating a signal that represents the actual level of the salt bath, means for generating a signal representing the density of the salt bath, and means for generating a signal representing the volume of the metal beneath the salt bath. A circuit is provided for receiving and storing an initial datum representing a desired concentration of the material in the molten bath, and for receiving the above signals, the circuit being further capable of calculating a bath level in response to said signals that will maintain the initial percent concentration of the material during the time molten metal is being produced and when molten metal is removed from the bath.
    Type: Grant
    Filed: November 4, 1976
    Date of Patent: August 30, 1977
    Assignee: Aluminum Company of America
    Inventors: Russell L. White, Kenneth L. Edwards
  • Patent number: 4043933
    Abstract: A method of fabricating a fuel cell electrode comprising an electrocatalyst and binder wherein the colloidal chemistry of the aqueous catalyst and the binder suspension are controlled during the deposition of the catalyst/binder onto an electrode substrate. Control is by addition of acids, bases, or salts to an aqueous suspension of binder and catalyst to adjust the pH to within certain ranges to form a flocculate. The flocculate is then fabricated into an electrode. The catalyst/binder distribution within the electrode and electrochemical performance, including decay characteristics, of the electrode are improved.
    Type: Grant
    Filed: June 15, 1976
    Date of Patent: August 23, 1977
    Assignee: United Technologies Corporation
    Inventors: Richard D. Breault, Richard P. Harding, Fred S. Kemp
  • Patent number: 4044193
    Abstract: This disclosure deals with novel very fine, particulated colloidal platinum of the 15-25 Angstrom size range of unusual catalytic activity and particularly adapted for adsorption or other deposition upon carbon for use as fuel cell catalytic electrodes and the like and produced from platinum colloids and sols including complex platinum sulfite compounds and sols derived therefrom.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: August 23, 1977
    Assignee: Prototech Company
    Inventors: Henry G. Petrow, Robert J. Allen
  • Patent number: 4042755
    Abstract: Method and apparatus for the pollution-free generation of electrical power from hydrogen in which molten lead is electrochemically oxidized to produce lead oxide and electricity in a single cell in which the resulting lead oxide is simultaneously converted back to lead metal by thermochemical reduction with hydrogen fuel, the entire process being carried out in a single cell using a molten salt as electrolyte in a temperature range of 500.degree. to 900.degree. C. The entire cycle consumes only hydrogen and oxygen, while producing electricity.
    Type: Grant
    Filed: November 10, 1975
    Date of Patent: August 16, 1977
    Inventor: Michael Anbar
  • Patent number: 4042762
    Abstract: Straps are molded integrally with and hinged to opposite sides of a plastic battery case and may be swung upwardly to form a handle for enabling easy carrying of the battery. In one embodiment, the straps are formed with hand holes and are grabbed individually when the battery is carried. In another embodiment, the straps are secured together at their ends and define a bail-type handle for the battery.
    Type: Grant
    Filed: November 11, 1975
    Date of Patent: August 16, 1977
    Assignee: Gould Inc.
    Inventor: Duane D. Hakarine
  • Patent number: 4041211
    Abstract: An improved substantially leak-proof button cell, particularly adapted for use in hearing aids, comprising an outer cathode can and an inner anode can containing a zinc electrode material, preferably a zinc paste, the inner can being positioned within the outer can, with the outer wall of the inner can spaced from the inner wall of the outer can, a polymeric seal, preferably a polypropylene seal, positioned between the outer wall of the inner can and the inner wall of the outer can, the outer wall of the inner can having a coating of an alkali resistant elastomer or elastomeric adhesive, e.g.
    Type: Grant
    Filed: October 6, 1975
    Date of Patent: August 9, 1977
    Assignee: Unican Electrochemical Products Ltd.
    Inventor: Marian Wiacek
  • Patent number: 4041210
    Abstract: A power plant for the generation of electricity utilizes high temperature fuel cells, such as molten carbonate fuel cells, as its main power supply. Part of the oxidant exhaust stream from the fuel cell is recycled through the fuel cell. Waste energy from the fuel cell in the form of exhaust gases, such as part of the oxidant exhaust, drives a turbocharger for compressing the oxidant used in the fuel cell. In a preferred embodiment the oxidant exhaust also is the source of energy for powering a bottoming cycle, such as a steam driven turbogenerator. Power plant efficiency is improved by making maximum use of the energy and heat generated within the system.
    Type: Grant
    Filed: August 30, 1976
    Date of Patent: August 9, 1977
    Assignee: United Technologies Corporation
    Inventor: Leslie L. Van Dine
  • Patent number: 4040435
    Abstract: A fuel cell wherein the electrolyte comprises a volatilizable solvent and a solute whose solubility in the solvent varies with electrolyte temperature can be operated by increasing or decreasing the amount of solvent relative to the amount of solute as the solubility of the latter in the solvent respectively decreases or increases due to variations in the temperatures of the electrolyte in the cell or cell system.
    Type: Grant
    Filed: October 28, 1975
    Date of Patent: August 9, 1977
    Assignee: Exxon Research and Engineering Company
    Inventor: Eugene Robert Elzinga
  • Patent number: 4039728
    Abstract: An automatic device for a fuel cell including inlet and outlet ports connected to an electrolyte feeding circuit provided with a pump for electrolyte circulation and inlet and outlet ports for a comburent, this device comprising in combination obturation means for closing and opening said inlet and outlet ports for the comburent, and control means connected to said obturation means, said control means actuating said obturation means in response to a parameter which depends on the circulation of electrolyte through the fuel cell.
    Type: Grant
    Filed: September 19, 1975
    Date of Patent: August 2, 1977
    Assignee: Institut Francais du Petrole
    Inventor: Jacques Cheron
  • Patent number: 4038463
    Abstract: An electrolyte reservoir layer disposed behind and adjacent one of the catalyst layers of a fuel cell is porous and hydrophilic to the electrolyte. In one embodiment the reservoir layer includes impregnations of hydrophobic material to provide reactant gas passages through the reservoir layer to the catalyst layer. Additionally the reservoir layer includes impregnations of a material similar to the fuel cell electrolyte retaining matrix material to improve electrolyte transfer from the matrix into the reservoir. The impregnations of hydrophobic material are designed to provide good distribution of the reactant gas into the catalyst layer without consuming a large volume of the reservoir. In a preferred embodiment the reservoir is also the electrode substrate whereby the catalyst layer is bonded to the surface thereof.
    Type: Grant
    Filed: September 1, 1976
    Date of Patent: July 26, 1977
    Assignee: United Technologies Corporation
    Inventors: John H. Lamarine, Robert C. Stewart, Jr., Raymond W. Vine