Abstract: High surface area, wide-pore-containing porous alumina are prepared by mulling together alumina hydrogel and alpha alumina monohydrate, extruding, drying and calcining at 500.degree.-700.degree. C.

Abstract: The invention relates to a process for manufacturing coarse, crystalline alumina which, after preparation in a generally known manner, is suitable for use as grinding, lapping and polishing materials. The process comprises the calcining of alumina from dry absorption scrubbing units employed in connection with fused salt reduction cells producing aluminum.

Abstract: In the manufacture of nuclear fuel tubes spent etching solutions containing nitric acid, zirconium, and hydrofluoric acid are produced as waste. A serial treatment process is employed to recover the zirconium and to restore the solution to the desired acid concentration. These processes include solvent extraction for zirconium removal and aqueous removal using evaporation or distillation.

Abstract: A method is disclosed for the recovery of iron, aluminum and titanium from coal ash. The method comprises magnetically extracting magnetite from the ash, leaching the ash with a solution of a mineral acid, precipitating and removing titanium and iron hydroxides from the leach solution by adding thereto a solution of a strong base, and precipitating and removing aluminum hydroxide by contacting the remaining solution with carbon dioxide or aluminum hydroxide seeding.

Abstract: A process for preparing a mixed metal oxide, usable as the cathode or intercalation electrode in high energy density primary and secondary batteries, having the formula Li.sub.x M.sub.y O.sub.z where M is at least one metal selected from the group consisting of titanium, chromium, manganese, iron, cobalt and nickel, x is a number from about 0.1 to about 1.1, preferably from about 0.9 to about 1.1, y is a total number from about 1.1 to about 0.1, preferably from about 1.1 to about 0.9, respectively, and z is a number from about 1.9 to about 2.1, such as LiCoO.sub.2 or [Li(Co.sub.0.5 Ni.sub.0.5) O.sub.

Abstract: Titanium is extracted from perovskite ores or concentrates by reaction of e perovskite ores or concentrates with sulfuric acid to form a sulfated residue, dissolving the sulfated residue in water or dilute acid, removing the precipitated calcium sulfate, and recovering the titanium in an aqueous solution.

Abstract: In the hydrometallurgical treatment of metal-bearing ores and particularly the beneficiation of iron-containing titaniferous ores wherein the ore is subjected to leaching with a dilute aqueous acid solution in a digestion zone, there is provided an improvement which comprises initiating and maintaining the mixture of ore and acid in a state of boiling. Initiation and maintenance of the mixture in a state of boiling is accomplished through the venting of the digestion zone to remove process vapors substantially in the form of water vapor. Initiation of the boiling of the mixture of ore and acid solution in the digestion zone is commenced when the temperature of the mixture and consumption of the free acid solution in said mixture have reached predetermined values. The initiation and maintenance of the mixture in a state of boiling results in an increased rate of dissolution of the contaminant values in the metal-bearing ore.

Abstract: A process is disclosed for removing ammonia from a sodium tungstate solution. The process involves heating the solution at from about 80.degree. C. to about 95.degree. C., while at the same time maintaining the pH above about 9.4 by addition of sodium hydroxide to the sodium tungstate solution. The heating is carried out for a period of time sufficient to allow the essentially complete removal of the ammonia.

Abstract: A process is described for the formation of high purity alumina from aluminas such as Bayer Process alumina trihydrate (gibbsite) which contain both acid-soluble and -insoluble impurities, notably soda and silica. The solid hydrated alumina is reacted with a stoichiometric quantity of concentrated HCl to form a reaction product comprising of dissolved aluminum chloride and solid aluminum chloride hexahydrate (ACH). The acid and/or aluminum chloride concentration of the solution is then adjusted (as by water addition) to dissolve the solid ACH and form a solution at or near saturation in aluminum chloride, but with the remaining solid materials undissolved. The solution is then subjected to solid/liquid separation to eliminate the insoluble impurities, such as silica.

Abstract: Gallium values are extracted and recovered from basic aqueous solutions thereof, notably from sodium aluminate solutions of Bayer process origin, by liquid/liquid extraction thereof with a water immiscible organic phase comprising an organic solvent having dissolved therein an organic-soluble substituted hydroxyquinoline and at least one organic-soluble organophosphorus compound comprising at least one acid function.

Abstract: A method is disclosed for producing crystalline ammonium metatungstate from ammonium paratungstate. The method involves heating the ammonium paratungstate at from about 130.degree. to about 400.degree. C. for from about 1 to about 8 hours to remove some ammonia and water, and heating a slurry of the resulting heated ammonium paratungstate in water at from about 80.degree. to about 100.degree. C. at relatively constant volume until the pH of the slurry becomes stabilized at from about 5.8 to about 6.0. The pH of the resulting pH stabilized slurry is then adjusted to from about 4.2 to about 3.0 by introducing a porous container containing a strongly acidic cation exchange resin into the slurry, the amount of resin being essentially sufficient to accomplish the pH adjustment. Thereafter the container and resin are removed from the resulting pH adjusted slurry which is then digested at from about 80.degree. to about 100.degree. C.

Abstract: A method is disclosed for producing ammonium metatungstate from ammonium paratungstate. The method involves first roasting the ammonium paratungstate at from about 275.degree. C. to about 300.degree. C. for from about 10 hours to about 20 hours to remove some ammonia and some water. The roasted ammonium paratungstate is then added to dilute solution of an ammonium metatungstate which is at a pH of from about 3.6 to about 4.2, the rate of addition being such that a slurry is produced having a pH of from about 3.6 to about 4.2. The pH of the resulting slurry is then adjusted to stabilize it at from about 3.6 to about 4.2 followed by evaporation to form a relatively concentrated solution of ammonium metatungstate which is then separated from any insolubles. Ammonium metatungstate is then crystallized from the relatively concentrated ammonium metatungstate solution.

Abstract: In a preferred embodiment, carbon dioxide and hydrogen sulfide are removed from a gaseous stream also containing a recoverable hydrocarbon product by CO.sub.2 sweetening, bulk CO.sub.2 removal, and hydrocarbon sweetening absorption steps, each absorption utilizing the same alkanolamine as absorbent. According to another aspect, each amine can be selected from the group consisting of tertiary amines and sterically hindered amines. According to yet another aspect, a feed gas comprising hydrogen sulfide and carbon dioxide can be introduced successively into a carbon dioxide sweetening absorption zone, then into a bulk CO.sub.2 removal absorption zone, then into a hydrocarbon sweetening absorption zone. Alternatively, a feed gas comprising hydrogen sulfide and carbon dioxide can be introduced first into a bulk CO.sub.2 removal absorption zone and then streams from the bulk CO.sub.2 removal zone can be provided respectively to the hydrocarbon sweetening absorption zone and the CO.sub.2 sweetening absorption zone.

Abstract: A process for hydrothermally disintegrating wastes or residues having a high content of calcined aluminum oxides by reacting said wastes or residues with an aqueous sodium hydroxide solution having a concentration of sodium hydroxide of from about 20 to about 50% by weight at a temperature in the range of from about 180.degree. to about 250.degree. C. under a saturated steam pressure corresponding to said temperature. The sodium aluminate solution obtained is separated off and optionally filtered.

Abstract: In a process for recovering rhenium, a starting material containing tungsten and rhenium is reacted with sodium hydroxide and an oxidizing reactant to form a fused solid. The fused solid is dissolved in water to solubilize the tungsten and rhenium values and then pass through an anion exchange resin to remove the rhenium values and form a solution containing the tungsten values. The resin is stripped to obtain the rhenium values from the resin.

Abstract: A process and system are provided for flash-roasting molybdenum sulfide containing slag-forming constituents. The process comprises feeding a pneumatically suspended stream of particulate molybdenum sulfide and a mixture of fuel and oxidizing gases through a nozzle into a confined furnace chamber, the fuel gas-oxidizing gas mixture exiting from the nozzle being ignited to provide a flame thereof, the flame being maintained at a condition to provide a temperature in the furnace chamber sufficient to oxidize the molybdenum sulfide and form a volatile gas comprising molybdenum trioxide. The temperature is at least sufficient to melt the slag-forming constituents such that the slag formed is sufficiently liquid to separate from the gaseous mixture and collect at a selected portion of said chamber for removal therefrom.

Abstract: Processes are described for preparing pure ammonium molybdate from impure roasted molybdenum concentrates. An aqueous solution of nitric acid, ammmonium sulfate, and ammonium nitrate is contacted with impure molybdenum concentrate to solubilize a major portion of the impurities. The resulting molybdenum concentrate is digested in ammonium hydroxide under conditions that maximize iron precipitation and removal. The resulting ammonium molybdate solution is separated from the sludge and further purified by chelating cation exchange resin in the ammonium form.

Abstract: A method of preparing an active magnesium-hydride or magnesium hydrogen-storer system which can reversibly take up H.sub.2, comprising contacting finely divided magnesium hydride or metallic magnesium with a solution of a metal complex or of a metal-organic compound of a transition metal of Subgroups IV-VIII of the periodic table, and then removing the solution. The product performs better with regard to speed and efficiency upon repeated hydrogenation and dehydrogenation, as in hydrogen storage and evolution.

Abstract: A process for the production of hydrides of magnesium, comprising reacting magnesium with hydrogen in the presence of magnesium.

Abstract: Process for the reaction of carbon monoxide with steam, with formation of carbon dioxide and hydrogen at elevated temperature in the presence of iron-containing catalysts (shift reaction), in which a catalyst is used, which contains finely divided iron oxide on an inert, thermostable carrier having a high specific surface.