Abstract: An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises contacting the carbon monoxide and hydrocarbon under polymerization conditions in the presence of a liquid reaction diluent and a supported catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a bidentate ligand chemically bound to support particles having an average particle diameter of at least 500.mu..
Abstract: A composition comprising a 1,2-dialkylidenecyclobutane such as 1,2-dimethylenecyclobutane, a bisbenzocyclobutene and a polyimide such as a bismaleimide can be thermally cured to a tough copolymer having a high glass transition temperature.
Abstract: Polyphenylene ethers are prepared from monohydric phenols by oxidative coupling with oxygen-containing gases in the presence of an oxidation catalyst in an organic solvent by carrying out the polycondensation in the presence of a defoamer.
Type:
Grant
Filed:
April 30, 1992
Date of Patent:
August 17, 1993
Assignee:
BASF Aktiengesellschaft
Inventors:
Doris Zeltner, Peter Steieri, Heike Feldman, Klaus Muehlbach, Carola Hedtmann-Rein, Bernhard Czauderna, Karl Hennig
Abstract: Linear aromatic copolyamides having good processability, superior thermal stability and excellent mechanical properties are provided. They comprise 55-90 mole % of a repearing unit of ##STR1## and 45-10 mole % of a repeating unit of ##STR2## wherein R.sub.1 and R.sub.2 each is a C.sub.4-12 aliphatic alkylene.
Abstract: There is provided a fire retardant polycarbonate resin composition comprising a polycarbonate resin, a specific partially esterified phosphoric acid metal salt and a specific partially esterified phosphoric acid in specific proportions. The polycarbonate resin composition can provide a transparent molded article which are excellent in fire retardance and heat stability.
Abstract: Poly(arylene sulfide/sulfone) polymers are treated in order to increase melt stability and decrease impurities by contacting the poly(arylene sulfide/sulfone) polymer with a soluble zinc compound and an acidic solution. In one embodiment, the polymer is treated first with the soluble zinc compound, followed by treatment with the acidic solution. In another embodiment, the polymer is treated in one step with a solution comprising a water soluble zinc compound in an acidic solution.
Type:
Grant
Filed:
May 6, 1991
Date of Patent:
August 10, 1993
Assignee:
Phillips Petroleum Company
Inventors:
Rex L. Bobsein, Michael C. Yu, Roy F. Wright, David A. Soules
Abstract: There are described copolyamides which are soluble in organic polyamide solvents and contain recurring structural units of the formulae Ia, Ib, Ic and Id or Ia, Ib, Id and Ig or Ia, Ib, Ic, Id and Ig and optionally of the formulae Ie and/or If--OC--Ar.sup.1 --CO-- (Ia),--NH--Ar.sup.2 --NH-- (Ib),--NH--Ar.sup.3 --NH-- (Ic), ##STR1##--OC--R.sup.2 --CO-- (Ie),--NH--R.sup.3 --NH-- (If),--OC--Ar.sup.4 --CO-- (Ig),whereAr.sup.1 and Ar.sup.2 are each independently of the other divalent aromatic radicals whose valence bonds are in the para or a comparable coaxial or parallel position relative to one another,Ar.sup.3 and Ar.sup.4 are each independently of the other divalent radicals whose valence bonds are in the meta or a comparable kinked position relative to one another,R.sup.1 is lower alkyl, lower alkoxy or halogen, andR.sup.2 and R.sup.3 are each independently of the other divalent aliphatic, cycloaliphatic or araliphatic radicals.
Abstract: In reactions to form PBZ polymers such as polybenzoxazole, monomers having an aromatic group bonded to a primary amine group and to a hydroxy, thio or amine group ortho to said primary amine group are contacted with monomers having an "electron-deficient carbon group." In the present invention the electron-deficient carbon group may be an alkali metal carboxylate group or a trihalomethyl group. Useful monomers include, for example, .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.',-hexachloroxylene and disodium terephthalate.
Abstract: An improvement to the continuous process for the production of polycarbonates by interphase polycondensation is described. Accordingly, the organic phase and the aqueous phase are combined in a tube, forming chlorocarbonic acid ester and further alkali hydroxide is added at, or shortly after, the maximum concentration of said ester is reached. The resulting emulsion is then changed to an oil-in-water emulsion which is then separated and worked up in known manner.
Type:
Grant
Filed:
May 29, 1992
Date of Patent:
August 10, 1993
Assignee:
Bayer Aktiengesellschaft
Inventors:
Claus Wulff, Hermann Kauth, Gunther Weymans, Zoltan Kricsfalussy, Wolfgang Alewelt, Jurgen Heuser
Abstract: A composition comprising a 1,2-dialkylidenecyclobutane such as 1,2-dimethylenecyclobutane, a diallyl compound and a polyimide such as a bismaleimide can be thermally cured to a tough copolymer having a high glass transition temperature.
Abstract: A composition comprising a 1,2-dialkylidenecyclobutane such as 1,2-dimethylenecyclobutane, a triene such as myrcene and a polyimide such as a bismaleimide can be thermally cured to a tough copolymer having a high glass transition temperature.
Abstract: Disclosed herein are chromium carbonyl complexes of polyamides containing units derived from aromatic diamines in which about 10 to about 90% of those units are complexed with a chromium carbonyl compound, and a process for making them. When aramids are used, the solubility of the polymer in organic solvents is enhanced, and in the case of certain aramids lyotropic solutions are formed. These solutions can be used to make anisotropic films and fibers.
Abstract: Catalyst residue (e.g., trace Group VIII metal) is removed from a polyketone solution, and from the polyketone resin itself, by passing the solution through a column comprising a metal oxide (e.g., silica gel) which is effective in removing the residue therefrom or by mixing the polyketone solution with particulate metal oxide.
Abstract: The cyclized carbonate of an amino aromatic acid, such as isatoic anhydride, or an acrylic acid halide, such as acryloyl chloride have been found useful in functionalizing hydroxy terminated polycarbonates.
Abstract: A polyarylene sulfide has an inherent viscosity [.eta..sub.i n h ] of 0.1 to 0.5 dl/g, a weight-average molecular weight of 1.times.10.sup.4 to 2.times.10.sup.5 ; a ratio of the inherent viscosity [.eta..sub.i n h ] to a calculated viscosity [.eta.].sub.calc ([.eta..sub.i n h /[.eta.].sub.calc) of 0.4/1 to 0.8/1; and a degree of whiteness of 50 or higher when measured in accordance with whiteness testing procedures (JIS P8123). The polyarylene sulfide is prepared by reaction by contacting at least one member of a metallic sulfide (A) selected from an alkali metal sulfide and an alkali metal hydrosulfide with a dihalogen aromatic compound (B) and an aromatic compound (C) having three or more than three functional groups in a polar solvent in a molar ratio of the dihalogen aromatic compound (B) to the metallic sulfide (A) [(B)/(A)] ranging from 1.035/1 to 1.300/1 and in a molar ratio of the aromatic compound (C) to the dihalogen aromatic compound (B) [(C)/(B)] ranging from 0.003/1 to 0.05/1.
Abstract: A novel catalyst composition containing a palladium salt, an anion of a non-hydrohalogenic acid with a pk.sub.a of less than 2, a phosphorus bidentate ligand and an acid with a pk.sub.a of at least 4 but less than 6. The catalyst composition effectively polymerizes carbon monoxide and at least one ethylenically unsaturated hydrocarbon to produce linear, alternating polymers.
Abstract: The invention relates to biologically degradable polymers, in particular polyaminodicarboxylic acid-co-anhydroaminodicarboxylic acid derivatives, to a process for their preparation and to the use thereof for depot preparations having controlled delivery of active compound.
Abstract: An N-substituted polyamide-imide essentially composed of identical or different repeating units of the formula I ##STR1## where R.sup.1 is one of the following tetravalent aromatic radicals ##STR2## and X is a bond or one of the following linkers ##STR3## where R.sup.2 and R.sup.4 are each, independently of one another, one of the following divalent aromatic radicals ##STR4## and where X has the abovementioned meanings and where R.sup.3 is hydrogen or a monovalent radical such as C.sub.1 -C.sub.6 -alkyl or phenyl, and the C.sub.1 -C.sub.6 -alkyl-, C.sub.1 -C.sub.6 -alkoxy-, aryl- or halogen-substituted derivatives thereof, and precursors (monomers) therefor, are described.
Abstract: An improved gas-phase process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel supported catalyst wherein the physical properties and dimensions of the catalyst support exhibit a defined mathematical relationship. Specifically, the value obtained when the average particle size of the particulate catalyst support is raised to the power of the relative bulk density of the support should be less than 30.
Abstract: A process is provided for the production of functional group containing resins wherein an alkyl-dithiol is added to the polymerizing mixture of styrene and divinyl benzene part way through the polymerization. On completion of the polymerization, the product is a thiol functionalized styrene-divinyl benzene resin.