Abstract: An exhaust cleaning catalyst, with which precious metal sintering is inhibited and which has greater exhaust cleaning abilities, has a substrate and a catalyst coating layer provided on the substrate. The catalyst coating layer has a precious metal that serves as an oxidation and/or reduction catalyst. The precious metal has Rh-containing metal particles in which rhodium (Rh) coexists with a base metal selected among platinum group elements excluding rhodium. The Rh-containing metal particles have an average rhodium content of 0.1% to 5% by mole with the total amount of the base metal and rhodium being 100% by mole.

Abstract: An oxidation catalyst includes a support including particles of an alkaline earth salt, and first particles including a palladium compound on the support. The oxidation catalyst can also include precious metal group (PMG) metal particles in addition to the first particles intermixed together on the support. A gas permeable polymer that provides a continuous phase can completely encapsulate the particles and the support. The oxidation catalyst may be used as a gas sensor, where the first particles are chemochromic particles.

Abstract: In some embodiments, the present invention provides amphiphilic nanosheets that comprise lamellar crystals with at least two regions: a first hydrophilic region, and a second hydrophobic region. In some embodiments, the amphiphilic nanosheets of the present invention also comprise a plurality of functional groups that are appended to the lamellar crystals. In some embodiments, the functional groups are hydrophobic functional groups that are appended to the second region of the lamellar crystals. In some embodiments, the lamellar crystals comprise ?-zirconium phosphates. Additional embodiments of the present invention pertain to methods of making the aforementioned amphiphilic nanosheets. Such methods generally comprise appending one or more functional groups to a stack of lamellar crystals; and exfoliating the stack of lamellar crystals for form the amphiphilic nanosheets.

Abstract: The invention discloses a micron-grade magnetic core coated ferrocyanide adsorbent for removing Cs ions in radioactive wastewater and a preparation method thereof. The adsorbent takes magnetic Fe3O4 as a core, the surface is coated with a dense SiO2 single layer serving as a protective layer, and an active component is metal ion stabilized potassium ferrocyanide coated on the outer layer, wherein stabilized metal ions comprise Ti, Zn, Cu, Ni, Co, and Zr. The particle size of the adsorbent is 0.2-5 ?m, the adsorbent in the outermost layer is conductive to improving the adsorption efficiency for Cs+ ions, and an external magnetic field is adopted for realizing solid-liquid phase separation.

Abstract: A catalytic converter with excellent OSC performance and NOx purification performance. The catalytic converter includes a substrate with a cell structure and catalyst layer. The catalyst layer includes lower and upper catalyst layers. The upper catalyst layer includes a zirconia compound support with rhodium carried thereon that contains zirconia, lanthanum oxide, and yttrium oxide; an alumina compound without rhodium carried thereon that contains alumina and lanthanum oxide; and a ceria-zirconia-based composite oxide containing ceria, zirconia, lanthanum oxide, and neodymium oxide.

Abstract: A catalytic material includes (i) a support material and (ii) a thin film catalyst coating having an inner face adjacent to the support material and an outer face, the thin film catalyst coating having a mean thickness of ?8 nm, and wherein at least 40% of the support material surface area is covered by the thin film catalyst coating; and wherein the thin film catalyst coating includes a first metal and one or more second metals, and wherein the atomic percentage of first metal in the thin film catalyst coating is not uniform through the thickness of the thin film catalyst coating.

Abstract: The invention provides electro-catalyst compositions for an anode electrode of a proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors. Furthermore, a thin film containing the compositions can be deposited onto a substrate to form the anode electrode.

Abstract: The purpose of the present invention is to provide a catalyst for exhaust gas purification, which is capable of effectively processing an exhaust gas, particularly carbon monoxide (CO) and hydrocarbon (HC) in the exhaust gas at a low temperature, and a method for producing the catalyst for exhaust gas purification. The purpose is achieved by a catalyst for exhaust gas purification, which is obtained by having a carrier that contains Al2O3 and one or more metal oxides selected from the group consisting of zirconium oxide (ZrO2), cerium oxide (CeO2), yttrium oxide (Y2O3), neodymium oxide (Nd2O3), silicon oxide (SiO2) and titanium oxide (TiO2) support one or more catalyst components selected from the group consisting of gold (Au), silver (Ag), platinum (Pt), palladium (Pd), rhodium (Rh), iridium (Ir), ruthenium (Ru) and osmium (Os). The metal oxides have particle diameters of less than 10 nm.

Abstract: Provided are catalyst composites useful for the production of vinyl acetate monomer, as well as methods of making using same. The catalyst composites may comprise a support comprising silica and about 1 to about 3 wt-% alumina, wherein the support has a surface area of about 175 to about 300 m2/g; and an eggshell layer on the support comprising Pd and Au.

Abstract: The present invention relate to a methane synthesis catalyst preparation method, comprising a preparation step for a catalytic body and a prereduction step. The prereduction step comprises: calcining the catalytic body to form a nickel aluminate spinel-containing catalyst precursor; and prereducing the catalyst precursor to acquire the methane synthesis catalyst. The catalyst prepared in the preparation method can be used in high-temperature and high liquid-to-gas ratio conditions, shows performance stability, and obviates the need for a further step of high-temperature reduction during vehicle operation. Also provided is the methane synthesis catalyst precursor. The catalyst precursor contains nickel aluminate spinel.

Abstract: The present invention relates to a method for producing a shell catalyst that is suitable for producing vinyl acetate monomer (VAM). The present invention also relates to a shell catalyst that can be obtained by the method according to the invention as well as the use of the shell catalyst according to the invention for producing VAM.

Abstract: Rapid, reversible redox activity may be accomplished at significantly reduced temperatures, as low as about 200° C., from epitaxially stabilized, oxygen vacancy ordered SrCoO2.5 and thermodynamically unfavorable perovskite SrCoO3-?. The fast, low temperature redox activity in SrCoO3-? may be attributed to a small Gibbs free energy difference between the two topotactic phases. Epitaxially stabilized thin films of strontium cobaltite provide a catalyst adapted to rapidly transition between oxidation states at substantially low temperatures. Methods of transitioning a strontium cobaltite catalyst from a first oxidation state to a second oxidation state are described.

Abstract: The present disclosure refers to a plurality of process employed for optimization of Zero-PGM washcoat and overcoat loadings on metallic substrates. According to an embodiment a substantial increase in conversion of HC and CO may be achieved by optimizing the total washcoat and overcoat loadings of the catalyst. According to another embodiment, the present disclosure may provide solutions to determine the optimum total washcoat and overcoat loadings for minimizing washcoat adhesion loss. As a result, may increase the conversion of HC and CO from discharge of exhaust gases from internal combustion engines, optimizing performance of Zero-PGM catalyst systems.

Abstract: The present invention pertains to novel core-shell particles comprising a core of iron oxide and a shell of cobalt oxide, characterized in that they are spherical with a number average diameter, as measured by TEM, of between 1 and 20 nm. This invention is also directed to their uses in the manufacture of a catalyst, and to the method for preparing these particles, by precipitating cobalt oxide onto magnetite or hematite particles which are themselves precipitated from Fe(III) and optionally Fe(II) salts.

Abstract: The present invention relates to a composition including a ?-type iron silicate, which includes all or part of iron in a ?-type framework structure, and a solid acidic porous inorganic oxide. The present invention is characterized in that the ?-type iron silicate is compounded with the porous inorganic oxide having solid acidic properties so that the solid acidic function derived from aluminum of the ?-type iron silicate, is reinforced or complemented by the porous inorganic oxide, the individual particles of which are physically isolated from each other. It is preferred that the fluorine content relative to the dry weight of the ?-type iron silicate is 400 ppm or less and the crystal particles of the ?-type iron silicate have a truncated square bipyramidal morphology. According to the present invention, a composition that is useful as a high-performance catalyst, adsorbent, or the like, can be provided.

Abstract: A process for preparing a catalyst precursor includes forming a slurry of particles of an insoluble metal compound, where the metal of the insoluble metal compound is an active catalyst component, with particles and/or one or more bodies of a pre-shaped catalyst support in a carrier liquid. The particles of the insoluble metal compound are thus contacted with the particles and/or the one or more bodies of the pre-shaped catalyst support. A treated catalyst support is thereby produced. Carrier liquid is removed from the slurry to obtain a dried treated catalyst support, which either directly constitutes the catalyst precursor, or is optionally calcined to obtain the catalyst precursor.

Abstract: The object of the present invention is to provide a novel exhaust gas purifying catalyst having excellent NOx purification performance. The object can be achieved by an exhaust gas purifying catalyst comprising: a substrate; and a catalyst layer disposed on the substrate which comprises a first carrier, and platinum and a first palladium supported on the first carrier; in which the weight ratio of the platinum to the first palladium is 3:1 to 8:1.

Abstract: A nanoparticle comprises a nano-active material and a nano-support. In some embodiments, the nano-active material is platinum and the nano-support is alumina. Pinning and affixing the nano-active material to the nano-support is achieved by using a high temperature condensation technology. In some embodiments, the high temperature condensation technology is plasma. Typically, a quantity of platinum and a quantity of alumina are loaded into a plasma gun. When the nano-active material bonds with the nano-support, an interface between the nano-active material and the nano-support forms. The interface is a platinum alumina metallic compound, which dramatically changes an ability for the nano-active material to move around on the surface of the nano-support, providing a better bond than that of a wet catalyst. Alternatively, a quantity of carbon is also loaded into the plasma gun.

Abstract: Acicular mullite bodies are made in two-step firing process in which a green body is converted first to a fluorotopaz and then to acicular mullite. The bodies are contained within an enclosed region of the furnace. A flow of process gas is provided through the enclosed region during the fluorotopaz-forming step. The process gas is introduced into the enclosed region through multiple openings on at least one side of the enclosed region, and withdrawn through multiple openings on another side of the enclosed region. During the acicular mullite-forming step, a flow of purge gas is maintained in the exterior portion of the furnace. This purge gas may be removed by flowing it into the enclosed region of the furnace and out of the furnace from the enclosed region without re-entering the exterior portion for the furnace.

Abstract: Solutions to the problem of washcoat and/or overcoat adhesion loss of ZPGM catalyst on metallic substrates are disclosed. Present disclosure provides a novel process for improving WCA to metallic substrates of ZPGM catalyst systems. Reduction of WCA loss and improved catalyst activity may be enabled by the selection of processing parameters determined from variations of pH and addition of binder to overcoat slurry, and particle size of washcoat. Processing parameters may be applied to a plurality of metallic substrates of different geometries and cell densities.