Abstract: A novel, heat curable, liquid polymer composition is disclosed which comprises a modified polyurethane oligomer containing terminal ethylenic unsaturation and a free radical generating catalyst. The composition has utility in preparing molded articles and coatings.
Type:
Grant
Filed:
September 29, 1981
Date of Patent:
January 3, 1984
Assignee:
Olin Corporation
Inventors:
James M. O'Connor, Donald L. Lickei, Michael L. Rubin
Abstract: An oxymethylene polymer which is modified with 1,2-polybutadiene is provided which exhibits enhanced physical properties, including tensile impact, elongation, and work to break. The oxymethylene polymer may be a homopolymer, consisting essentially of recurring oxymethylene groups, or a copolymer (as described).
Abstract: A process for preparing aromatic-moiety-containing polymers having modified physical properties is disclosed. Briefly, the process comprises reacting in the presence of a Friedel-Crafts catalyst: (a) a suitable aromatic-moiety containing polymer resin and (b) a homopolymer of .omega.-halo-.alpha.-olefins, or co- or terpolymer of .omega.-halo-.alpha.-olefins with other .alpha.-olefins and/or ethylene.
Abstract: Thermoplastic molding materials based on styrene polymers modified to be impact resistant with EPDM rubbers and polyphenylene ethers wherein the particles of the flexible components of the impact resistant styrene polymer have an average particle diameter range of 0.3 to 0.7 microns.
Type:
Grant
Filed:
May 28, 1982
Date of Patent:
January 3, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Juergen Hambrecht, Franz Brandstetter, Adolf Echte, Karl Gerberding, Walter Heckmann
Abstract: Curable coating compositions of olefinically unsaturated compounds A and an N-vinyl compound B. The N-vinyl compounds carry at least 2 N-vinyl groups and at least one carbonyl group bonded to the nitrogen of the N-vinyl group. The coating compositions can be used for the manufacture of paints, printing inks, printing plates and photoresist materials.
Type:
Grant
Filed:
September 24, 1979
Date of Patent:
January 3, 1984
Assignee:
BASF Aktiengesellschaft
Inventors:
Helmut Barzynski, Heinrich Hartmann, Dieter Lautenbach, Rolf Osterloh, Lutz Goethlich, Guenter Heil
Abstract: A polymer blend capable of being molded to an impact resistant, substantially transparent or translucent article which comprises a vinyl halide homopolymer or copolymer, a conventional impact resistance enhancing polymer agent for polyvinyl halide wherein the monomer units consist essentially of methyl methacrylate, 1,3-butadiene and styrene residues and a thermoplastic block elastomer wherein the essential and predominant monomer units are the residue of a mono-alkenyl aromatic hydrocarbon and the residue of an alkadiene hydrocarbon. The thermoplastic elastomer is normally incompatible with the vinyl halide polymer or copolymer. The vinyl halide polymer or copolymer constitutes the major proportion of said blend and the block and methacrylate polymers together constitute a minor proportion of the composition. The weight ratio of block polymer to methacrylate polymer is about 1:5 to about 5:1.
Abstract: Molding compositions comprising a polyphenylene ether, a polysulfone, and a selectively hydrogenated linear or radial block copolymer comprising vinyl aromatic compound and dienes, optionally further including a plasticizer, possess excellent impact resistance, and heat aging resistance.
Abstract: A method for curing a resinous composition comprising an admixture of a thermosetting resin and dielectrically lossy particles is described wherein the lossy particles have a dielectric constant substantially the same as the dielectric constant of the resin. The method comprises subjecting said admixture to a high frequency alternating electric field for sufficient time to heat the lossy particles and initiate the chemical reaction to cure the resin. Also described are shaped articles of manufacture made by curing resinous compositions in accord with the described method. Such articles have enhanced mechanical properties due to the curing process.
Abstract: The invention relates to thermoplastic molding materials based on impact resistant polystyrene and polyphenylene ethers. The molding materials of this invention contain a flexible component having a glass temperature below -70.degree. C. and a flexible component having a glass temperature in the range of 0.degree. to -70.degree. C.
Type:
Grant
Filed:
March 8, 1982
Date of Patent:
December 27, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz Brandstetter, Adolf Echte, Juergen Hambrecht, Karl H. Illers, Edmund Priebe
Abstract: The invention relates to a process for the manufacture of impact resistant thermoplastic molding materials wherein potassium salts of saturated or unsaturated fatty acids with 10 to 30 carbon atoms are used as emulsifier.
Type:
Grant
Filed:
April 8, 1982
Date of Patent:
December 20, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Graham E. McKee, Franz Brandstetter, Adolf Echte, Juergen Hambrecht, Heinz-Juergen Overhoff, Edmund Priebe, Josef Schwaab, Peter Siebel
Abstract: High impact polystyrene having excellent properties is produced by a continuous process comprising feeding rubber and styrene continuously to a multistage horizontal dissolving tank to dissolve the rubber completely with stirring by increasing the temperature of each stage stepwise along the liquid flow direction, feeding the rubber solution to a first polymerizer to effect phase inversion of the rubber and preliminary polymerization of styrene; feeding the pre-polymerized solution to one or more horizontal type polymerizers to undergo bulk polymerization while removing the heat generated therein; and feeding the polymerized solution to a monomer separator to remove the remaining monomer.
Type:
Grant
Filed:
April 7, 1982
Date of Patent:
December 6, 1983
Assignee:
Hitachi, Ltd.
Inventors:
Chihiro Fukumoto, Tokinobu Furukawa, Chikao Oda
Abstract: Thermoplastic molding materials based on impact resistant styrene polymers and polyphenylene ethers, containing an ester of an aliphatic monocarboxylic acid having 8 to 30 carbon atoms and an aliphatic or aromatic hydroxy compound having 1 to 6 hydroxyl groups.
Type:
Grant
Filed:
April 5, 1982
Date of Patent:
December 6, 1983
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz Brandstetter, Adolf Echte, Herbert Naarmann, Edmund Priebe
Abstract: The invention relates to a process for preparing ABS polyblends having small and large grafted rubber particles dispersed therein providing polyblends having greater toughness and chemical resistance. The process includes extracting small grafted rubber particles into a separated monomer phase which is mass polymerized to a first melt, mixing said first melt with a second melt having present larger grafted rubber particles to form a third melt which is devolatilized to an ABS polyblend having a bimodal grafted rubber particle size distribution.
Abstract: Thermoplastic elastomer compositions of the present invention comprise a blend of from about 10 to about 50 parts by weight of a crystalline 1-olefin polymer, from about 80 to about 15 parts by weight of a styrene-butadiene rubber, and from about 5 to about 50 parts by weight of bitumen. The thermoplastic blends have unexpectant increases in properties, especially tear strength, tensile strength, high temperature (100.degree. C.) tear strength, and smooth surfaces when injection molded. Moreover, the bitumen lowers the injection molding pressure, thus enabling larger parts to be molded. The compositions, which may be partially cured, also have excellent aging properties. The compositions are a true thermoplastic in that they can be repeatedly processed and yet maintain their good physical properties.
Type:
Grant
Filed:
April 16, 1980
Date of Patent:
December 6, 1983
Assignee:
The Firestone Tire & Rubber Company
Inventors:
Georg G. A. Bohm, Lee E. Vescelius, Gary R. Hamed
Abstract: Thermoplastic elastomer compositions of the present invention comprise a blend of from about 10 to about 50 parts by weight of a crystalline 1-olefin polymer, from about 80 to about 15 parts by weight of a styrene-butadiene rubber, and from about 5 to about 50 parts by weight of bitumen. The thermoplastic blends have unexpectant increases in properties, especially tear strength, tensile strength, high temperature (100.degree. C.) tear strength, and smooth surfaces when injection molded. Moreover, the bitumen lowers the injection molding pressure, thus enabling larger parts to be molded. The compositions, which may be partially cured, also have excellent aging properties. The compositions are a true thermoplastic in that they can be repeatedly processed and yet maintain their good physical properties.
Type:
Grant
Filed:
September 17, 1981
Date of Patent:
November 29, 1983
Assignee:
The Firestone Tire & Rubber Company
Inventors:
Georg G. A. Bohm, Lee E. Vescelius, Gary R. Hamed
Abstract: Coating compositions capable of liquid application to substrates consist essentially of a curable film forming polyol-containing component and an organic reactive diluent. The reactive diluent is an organic compound containing a primary or secondary hydroxyl group and further characterized by having a retained solids value of greater than about 80 percent, a hydroxyl equivalent weight of from about 180 to about 800, and a liquid viscosity of less than about 10 poise at 60.degree. C. The coating compositions can be formulated to contain little or no volatile organic solvent and/or water.
Type:
Grant
Filed:
April 2, 1982
Date of Patent:
November 22, 1983
Assignee:
PPG Industries, Inc.
Inventors:
Wen-Hsuan Chang, James B. O'Dwyer, John R. Peffer
Abstract: Graft copolymers having a diene rubber core surrounded by at least two different shells improve the impact strength under multi-axial stress of thermoplastic polyester moulding compositions.
Type:
Grant
Filed:
October 9, 1981
Date of Patent:
November 22, 1983
Assignee:
Bayer Aktiengesellschaft
Inventors:
Christian Lindner, Rudolf Binsack, Dieter Rempel, Karl-Heinz Ott
Abstract: Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
Abstract: Flame-retardant thermoplastic molding compositions having improved physical and electrical arc track resistant properties are provided, the compositions comprising an intimate admixture of(a) a high molecular weight poly(1,4-butylene terephthalate) homo- or co-polyester,(b)(i) a copolymer of ethylene and vinyl acetate in combination with an aromatic polycarbonate;(ii) poly(ethylene terephthalate); or(iii) reinforcing glass;(c) a flame retardant agent; and(d) a mineral filler.
Type:
Grant
Filed:
October 15, 1980
Date of Patent:
November 8, 1983
Assignee:
General Electric Company
Inventors:
Stuart C. Cohen, Robert J. Kostelnik, Allen D. Wambach