Abstract: Metallurgical silicon containing impurities of carbon and/or carbon-containing compounds is classified and subsequently used selectively for chlorosilane production. The process comprises the steps of: a) determining the free carbon proportion which reacts with oxygen up to a temperature of 700° C., b) directing metallurgical silicon in which the free carbon proportion is ?150 ppmw to a process for producing chlorosilanes and/or directing metallurgical silicon in which the free carbon proportion is >150 ppmw to a process for producing methylchlorosilanes. As a result of the process, metallurgical silicon having a total carbon content of up to 2500 ppmw can be used for producing chlorosilanes.
Type:
Grant
Filed:
February 8, 2018
Date of Patent:
July 4, 2023
Assignee:
WACKER CHEMIE AG
Inventors:
Karl-Heinz Rimboeck, Uwe Paetzold, Gerhard Traunspurger
Abstract: Methods of synthesis of mesoporous silica are disclosed. The mesoporous silica synthesized herein, like SBA-15, possesses a two-dimensional, hexagonal, through-hole structure with a space group p6mm. An effective quantity of one or more water-soluble oxidized disulfide oil (ODSO) compounds are used during synthesis to impart distinct characteristics.
Type:
Grant
Filed:
June 14, 2021
Date of Patent:
June 27, 2023
Assignee:
Saudi Arabian Oil Company
Inventors:
Robert Peter Hodgkins, Omer Refa Koseoglu
Abstract: Provided is a structured catalyst for hydrodesulfurization that suppresses the decline in catalytic activity and achieves efficient hydrodesulfurization. The structured catalyst for hydrodesulfurization (1) includes a support (10) of a porous structure composed of a zeolite-type compound, and at least one catalytic substance (20) present in the support (10), the support (10) having channels (11) connecting with each other, and the catalytic substance (20) being present at least in the channels (11) of the support (10).
Abstract: The invention relates to a method for preparing core-shell structured particle precursor under a co-precipitation reaction. In this method, by controlling the feeding of different types of anion compositions and/or cation compositions, and adjusting the pH to match with the species, precipitated particles are deposited to form a precipitated particle slurry, filtering, and drying the precipitated particle slurry to yield the particle precursor. The invention also provides a particle precursor which includes a core-shell structure. The shell is made of gradient anions and/or cations. Such particle precursor can be used to prepare cathode of lithium-ion battery.
Abstract: Provided are titanium oxide fine particles which are excellent in transparency and are less photocatalytically active while maintaining a high refractive index, a dispersion of such fine particles, and a method for producing such a dispersion. The method for producing a dispersion of iron-containing rutile titanium oxide fine particles including a step (1) of neutralizing an aqueous metal mineral acid salt solution containing Ti and Fe in Fe2O3/(TiO2+Fe2O3)=0.001 to 0.010 to form an iron-containing hydrous titanic acid; a step (2) of adding an aqueous hydrogen peroxide solution to form an aqueous solution of iron-containing peroxotitanic acid having an average particle size of 15 to 50 nm; a step (3) of adding a tin compound so as to satisfy TiO2/SnO2=6 to 16; a step (4) of adding a sol of silica-based fine particles which contain Si and a metal element M in SiO2/MOx/2=99.9/0.1 to 80/20, the addition being made so as to satisfy SiO2/(oxides of the other elements)=0.08 to 0.
Type:
Grant
Filed:
March 27, 2018
Date of Patent:
June 20, 2023
Assignee:
JGC Catalysts and Chemicals Ltd.
Inventors:
Jun Yamaguchi, Takumi Miyazaki, Ryo Muraguchi, Tatsuya Uehara
Abstract: A hydrated lime product exhibiting superior reactivity towards HCl and SO2 in air pollution control applications. Also disclosed is a method of providing highly reactive hydrated lime and the resultant lime hydrate where an initial lime feed comprising calcium and impurities is first ground to a particle-size distribution with relatively course particles. Smaller particles are then removed from this ground lime and the smaller particles are hydrated and flash dried to form a hydrated lime, which is then milled to a significantly smaller particle size than that of the relatively course particles. The resultant lime hydrate product has available CaOH of greater than 92%, a citric acid reactivity of less than 20 seconds, a BET surface area greater than 18, a D90 less than 10 ?m, a D50 less than 4 ?m, a D90/D50 less than 3, and a large pore volume of greater than 0.2 BJH.
Type:
Grant
Filed:
March 22, 2021
Date of Patent:
June 13, 2023
Assignee:
Mississippi Lime Company
Inventors:
Randy J. Griffard, Gerald K. Bequette, William S. Allebach, Sr., Paul J. Ramer
Abstract: Provided is a transparent spinel sintered body which is formed from an Mg—Al spinel powder having an Al/Mg ratio of from 1.97 to 2.03 or a mixed powder of an Mg oxide and an Al oxide, and wherein the total content of metal impurities excluding Al and Mg is less than 100 ppm. A sample of this transparent spinel sintered body having a thickness of 3 mm has a total light transmittance of 80% or more in the thickness direction for the wavelength range of from 190 nm to 400 nm; and this transparent spinel sintered body is usable as a medium that transmits light from an ultraviolet light emitting element.
Abstract: A method for obtaining aluminum-containing nanoparticles is provided. The method includes exposing at least one surface comprising aluminum to an alkaline aqueous solution. The method further includes exposing the at least one surface to electro-hydraulic shock waves and an electron flux. The at least one surface undergoes electro-erosion which creates alumina-hydrated nanoparticles having a negative surface electrical charge. The method further includes transforming the alumina-hydrated nanoparticles into aquachelate nanoparticles by attaching water molecules to the alumina-hydrated nanoparticles.
Abstract: There is provided a method for preparation of oxide support-nanoparticle composites, in which metal nanoparticles decorate with uniform size and distribution on the surface of an oxide support, and thus, high performance oxide support-nanoparticle composites that can be applied in the fields of heterogeneous catalysis can be provided.
Type:
Grant
Filed:
November 13, 2020
Date of Patent:
June 6, 2023
Assignee:
KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY
Abstract: A method includes the following steps: a first step: the material containing heteroatom and graphite powder are mixed for a preset time by grinding, and the molar ratio of heteroatom to carbon atom is 1%-10%, then the heteroatom precursors are obtained; a second contact step: the heteroatom precursor is filled into a graphite rod with holes and compacted, then the graphite rod is dried for a preset time to obtain a plasma anode and using a DC arc plasma device to prepare the graphite anode into heteroatom-doped CNHs; a third contact step: the heteroatom-doped CNHs are dispersed in a reducing solution, a platinum salt is added to stir evenly, the reduction reaction is carried out by heating and stirring, and after centrifugation, washing and drying, a catalyst with platinum loading is obtained.
Type:
Grant
Filed:
October 12, 2022
Date of Patent:
June 6, 2023
Assignee:
KUNMING UNIVERSITY OF SCIENCE AND TECHNOLOGY
Abstract: A material of Formula (I) is provided MyTxQvW1-vOz-tJt??(I) where: T represents one of tin, lead, antimony and germanium, T being present in the interstitial spaces or voids of the lattice, M represents one or more species, each selected from the group consisting of (i) metals other than T, and (ii) polyatomic ionic species, said polyatomic species having an ionic radius of no more than 2 ?, M being present in the interstitial spaces or voids of the lattice, W is tungsten, O is oxygen, Q represents one or more element having an oxidation state of at least +4, Q, if present, occupying a lattice point of W, J represents one or more non-metallic element anion of chemical valence ?1, J, if present, occupying a lattice point of O, v is from 0 to 1.0, t is from 0 to 3.0, y is non-zero and up to and including 0.32, x is non-zero and up to and including 0.32, and z is from 2.5 to 4, provided that x+y?0.33.
Type:
Grant
Filed:
February 2, 2018
Date of Patent:
May 23, 2023
Assignee:
WILLIAM BLYTHE LIMITED
Inventors:
Mark Carter, Jack Carroll, David Crossley
Abstract: The present disclosure relates to a novel staged-synthesis method for introduction of various metals in the structure of zeolite frameworks by isomorphous substitution. This new method is based on a hydrothermal synthesis in which the metal addition to the precursor suspensions (gel) is delayed. This so-called “staged-synthesis method” allows to obtain nanosized silanol highly homo-geneous crystalline zeolite structures with a control of the metal location.
Type:
Grant
Filed:
October 13, 2020
Date of Patent:
May 23, 2023
Assignees:
TOTALENERGIES ONETECH, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)
Abstract: The copper oxide nanoparticles synthesized using Rhatany root extract involves preparing the Rhatany root extract by adding powdered Rhatany roots to boiling water, allowing the mixture to soak overnight, and removing any solid residue by filtering to obtain the aqueous extract. The copper oxide nanoparticles are prepared by mixing equal volumes of the aqueous Rhatany root extract and 0.1 M aqueous copper sulfate, heating the mixture at 80° C. for 40 minutes, and adding 1 M sodium hydroxide dropwise to the mixture to precipitate CuO. The precipitate is removed by centrifuge, washed with ethanol, dried, and calcined at 400° C. for 4 hours to obtain the copper oxide nanoparticles. The resulting nanoparticles proved effective in degrading wastewater dyes, showed anticancer activity against human cervical cancer by cell viability assay, and showed antibacterial activity against various strains of bacteria by agar diffusion.
Type:
Grant
Filed:
April 12, 2021
Date of Patent:
May 9, 2023
Assignee:
KING SAUD UNIVERSITY
Inventors:
Ali Aldalbahi, Bushra Ibarahim Alabdullah, Manal Ahmed Gasmelseed Awad, Shaykha Mohammed Alzahly, Zainah Ali Alqahtani, Shorouq Mohsen Alsaggaf, Hessa Abdullah Aljasser, Hind Ali Abdullah Alshehri
Abstract: The present disclosure relates to mesoporous metal titanate materials composition. Specifically, the present disclosure relates to a mesoporous metal titanate material composition that is active for multiple reactions, including aromatic alkylation, alkene coupling, alkene cyclization, alkyne oxidation, alcohol dehydrogenation reactions.
Type:
Grant
Filed:
February 18, 2020
Date of Patent:
May 2, 2023
Assignee:
UNIVERSITY OF CONNECTICUT
Inventors:
Steven L. Suib, Wimalika Rasangi Kumari Thalgaspitiya, Tharindu M. P. K. Kapuge
Abstract: A thermal method of forming ferric oxide nano/microparticles with predominant morphology is described using different solvents. Methods of using the Fe3O4 nano/microparticles as catalysts in the reduction of nitro compounds with sodium borohydride to the corresponding amines and decomposition of ammonium salts.
Type:
Grant
Filed:
May 30, 2018
Date of Patent:
April 18, 2023
Assignee:
King Fahd University of Petroleum and Minerals
Inventors:
Muhammad Ramzan Saeed Ashraf Janjua, Saba Jamil, Shanza Rauf Khan
Abstract: Manganese-cobalt (Mn—Co) spinel oxide nanowire arrays are synthesized at low pressure and low temperature by a hydrothermal method. The method can include contacting a substrate with a solvent, such as water, that includes Mn04- and Co2 ions at a temperature from about 60° C. to about 120° C. The method preferably includes dissolving potassium permanganate (KMn04) in the solvent to yield the Mn04- ions. the substrate is The nanoarrays are useful for reducing a concentration of an impurity, such as a hydrocarbon, in a gas, such as an emission source. The resulting material with high surface area and high materials utilization efficiency can be directly used for environment and energy applications including emission control systems, air/water purifying systems and lithium-ion batteries.
Abstract: The present invention relates to a dry reforming catalyst in which an active material is impregnated on the surface of a metal oxide support and the active material is surrounded by a surfactant, a method of preparing the same, and a method of producing a synthetic gas using the catalyst. Since the surfactant on the surface of the active material prevents the active material from being sintered and the active material surface from being covered with carbon, the dry reforming catalyst exhibits high activity at high temperature for a long period of time without having to use a precious metal, and thus is useful for the production of a synthetic gas.
Type:
Grant
Filed:
August 7, 2017
Date of Patent:
April 4, 2023
Assignees:
Korea Advanced Institute of Science and Technology, Saudi Arabian Oil Company
Abstract: A method for producing a sulfide solid electrolyte includes a firing step of firing a raw material containing Li2S in a hydrogen sulfide-containing atmosphere at a temperature of 300° C. or higher, Li2S having a purity of 50 to 90% by mass at the start of firing. The Li2S may contain impurities including at least one of LiOH, Li2O, LiHCO3, and Li2CO3. In the firing step, it is preferable that a concentration of a hydrogen sulfide in the hydrogen sulfide-containing atmosphere is 50 volume % or more. It is preferable that the raw material further contains P2S5 and LiX (X represents at least one type of elemental halogen), and the sulfide solid electrolyte has an argyrodite-type crystal structure.
Abstract: A method for fabricating nanodiamond particles in a nanodiamond fabrication reactor, which method entails: a) forming a composite of a plurality of diamond monolayers interspersed with a plurality of non-monolayer dihydrobenzvalene (DHB), one over the other, by reacting kinetically energized carbyne radicals with a supported layer of DHB, thus sealing off any subtended, unreacted DHB from further reaction with the kinetically energized carbyne radicals. b) subjecting the diamond monolayers to an anvil having a nanomachined strike face, with sufficient force to fracture the diamond monolayers, to thereby produce nanodiamond having a shape in the X-Y plane matching that of the nanomachined strike face and a Z-axis dimension (thickness) which is that of a diamond monolayer.