Abstract: A process for making modified polybutylene terephthalate random copolymers from a polyethylene terephthalate component includes reacting an oligomeric diol component selected from the group consisting of bis(hydroxybutyl) terephthalate, bis(hydroxybutyl)isophthalate, hydroxybutyl-hydroxyethyl terephthalate, and combinations thereof to a reactor; (i) a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers with (ii) a diol component selected from the group consisting of 1,4-butanediol, ethylene glycol, propylene glycol, and combinations thereof, in the reactor under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; combining the first molten mixture is combined with 1,4-butanediol under conditions to form a second molten mixture; and placing the second molten mixture under conditions sufficient to produce the modified polybutylene terephthalate random copolymers.
Abstract: The invention relates to amide-containing polymers of the general formula (I) A-X—CO—(CH2)2—NR1—R2—[Y—R3—Y—R4)a—B??(I) and also their salts with carboxylic acids, phosphoric esters and sulphonic acids. The invention further relates to processes for preparing the amide-containing polymers and to their use as rheology control agents.
Type:
Grant
Filed:
November 16, 2007
Date of Patent:
September 21, 2010
Assignee:
BYK-Chemie GmbH
Inventors:
Karlheinz Haubennestel, Stefan Moessmer, Ulrich Orth, Daniela Betcke
Abstract: A barrier coating composition includes a polymer material and a structuring agent dispersed in said polymer material, wherein the structuring agent decreases oxygen or water permeability through the polymer material. The barrier coating composition can be used to coat a core component, which can be oxygen or water sensitive, to form a microencapsulated material. The microencapsulated material can be formed by microencapsulation methods, which include atomization or coacervation methods, including forming an oil emulsion of an oil phase and an aqueous phase, the oil phase including the core component and the aqueous phase including the polymer material, adding the structuring agent to one of the oil phase and the aqueous phase, mixing the oil emulsion to form desired particle sizes of the core component, forming the shell component around the core component to form the microencapsulated material, and extracting the formed microencapsulated material from the oil emulsion.
Type:
Grant
Filed:
September 4, 2003
Date of Patent:
September 14, 2010
Assignee:
Southwest Research Institute
Inventors:
Niraj Vasishtha, Herman W. Schlameus, Darren E. Barlow
Abstract: A polymer of Formula or structure (I) wherein at least one of R1 and R2 is a suitable hydrocarbon, hydrogen, a heteratom containing group, or a halogen; Ar and Ar? represent an aromatic moiety; x, y, a, b, c, d, e, f, and g represent the number of groups or rings, respectively; and n represents the number of repeating units.
Abstract: It is to provide a compound which has a low vapor pressure and low viscosity, which is less problematic in deterioration during its use and which is useful as e.g. a lubricant, a surface modifier or a surfactant. A fluoropolyether compound represented by the formula (X—)xY(—Z)z, wherein X is a group represented by the formula HO—(CH2CH2O)a.(CH2CH(OH)CH2O)b—(CH2)c—CF2O(CF2CF2O)d— (wherein “a” is an integer of from 0 to 100, b is an integer of from 0 to 100, c is an integer of from 1 to 100, and d is an integer of from 1 to 200), Z is a group represented by the formula RFO(CF2CF2O)g— (wherein RF is e.g. a C1-20 perfluoroalkyl group having an etheric oxygen atom inserted between carbon-carbon atoms, and g is an integer of from 3 to 200), Y is e.g. a (x+z) valent perfluorinated saturated hydrocarbon group, x is an integer of at least 2, z is an integer of at least 0, and (x+z) is an integer of from 3 to 20.
Abstract: Provided herein are methods and compositions for generating acids for use downhole, for example, to break fluid-loss control pills. The delayed-release acid breakers of the present invention comprise orthoesters and/or poly(orthoesters).
Type:
Grant
Filed:
June 22, 2009
Date of Patent:
September 14, 2010
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Rajesh K. Saini, Karen Savery, Bradley L. Todd
Abstract: In accordance with the present invention there are provided hyperbranched benzobisazole polymers having repeating units of the formulas: and hyperbranched bibenzazole polymers having repeating units of the formulas: wherein Q is —S— or —NH—; the terminal groups X and Y are COOH and respectively, with their total number (X+Y) equals n+1, where n=degree of polymerization. The ratio X:Y can be controlled by varying the stoichiometric ratio of trimesic acid (A3 monomer) and 2,5-diamino-1,4-dimercaptobenzene dihydrochloride (B2 monomer) from 1:1 to 1.1.35.
Type:
Grant
Filed:
June 15, 2006
Date of Patent:
September 7, 2010
Assignee:
The United States of America as represented by the Secretary of the Air Force
Inventors:
Loon-Seng Tan, David H. Wang, Jong-Beom Baek
Abstract: Methods for forming maleimide functionalized polymers are provided. In one such embodiment, a maleimide functionalized polymer is prepared in a method that includes a step of carrying out a reverse Diels-Alder reaction. Intermediates useful in the methods, as well as methods for preparing the intermediates, are also provided. Also provided are polymeric reagents, methods of using polymeric reagents, compounds and conjugates.
Type:
Grant
Filed:
December 3, 2004
Date of Patent:
September 7, 2010
Assignee:
Nektar Therapeutics
Inventors:
Samuel P. McManus, Antoni Kozlowski, Tracy L. Hutchison, Brian Bray, Xiaoming Shen
Abstract: Disclosed herein is a novel functional diamine compound having a dendron structure, polyamic acid which is produced using functional diamine, aromatic cyclic diamine, aliphatic cyclic acid dianhydride, and aromatic cyclic acid dianhydride, polyimide which is produced by imidizing polyamic acid, and an LC alignment film produced using polyimide. Even if the diamine compound is used in a small amount, it is possible to realize a high pretilt angle, thus the pretilt angle is easily controlled. Therefore, it can be used to produce an LC alignment film using a twisted nematic (TN) mode, in which the pretilt angle of liquid crystal is low, and a vertically aligned (VA) mode, which requires a high pretilt angle of about 90°.
Type:
Grant
Filed:
November 23, 2009
Date of Patent:
September 7, 2010
Assignee:
Cheil Industries Inc.
Inventors:
Jae Min Oh, Moo Young Lee, Bum Jin Lee, O Bum Kwon, Won Seok Dong, Yusuke Tsuda
Abstract: The present invention relates to subterranean drilling operations, and more particularly, to drilling fluids that may be used to drill a well bore in a subterranean formation that may demonstrate improved shale inhibition and methods of using such drilling fluids in subterranean formations. One embodiment of the methods of the present invention provides a method of drilling a well bore in a subterranean formation comprising providing a drilling fluid comprising an aqueous-based fluid and a shale inhibiting component comprising a nanoparticle source; and placing the drilling fluid in the well bore in the subterranean formation. Another embodiment of the present invention provides a method of flocculation comprising providing a fluid comprising suspended particles, and adding a shale inhibiting component comprising a nanoparticle source to the fluid comprising suspended particles to form flocculated particles.
Abstract: To provide a process for producing a polyester ether poly- or mono-ol having a narrow molecular weight distribution, which is obtained by copolymerizing an initiator having hydroxyl groups with a cyclic ester compound and an alkylene oxide. It is possible to produce a polyester ether poly- or mono-ol having a molecular distribution (Mw/Mn) of from 1.02 to 1.4 by copolymerizing a cyclic ester compound which carbon number is from 3 to 9 and an alkylene oxide which carbon number is from 2 to 20 with an initiator having from 1 to 12 hydroxyl groups and having a number average molecular weight (Mn) of from 18 to 20,000 in the presence of a double-metal cyanide complex catalyst is having tert-butyl alcohol as at least a part of an organic ligand.
Abstract: Disclosed are methods of treating subterranean formations with rapidly hydratable treatment fluids based upon heteropolysaccharides. In particular, the invention relates to treatment methods with fluids containing a heteropolysaccharide, aqueous medium, and an electrolyte, wherein the fluids may further include a gas component, a surfactant and/or an organoamino compound. The fluids exhibit good rheological properties at elevated temperatures, and unusually rapid hydration rates which allows utilizing such fluids without the need of hydration tanks.
Abstract: Methods for treating wellbores using fluids containing a sphingan heteropolysaccharide which contributes viscosity stability and a decrease in friction pressure. Some methods are clean-out operations using recyclable-viscosity fluids containing at least a sphingan heteropolysaccharide and an optional salt. Others include methods of pumping fluids incorporating sphingan heteropolysaccharides to reduce pumping frictional pressure.
Type:
Grant
Filed:
August 16, 2006
Date of Patent:
August 17, 2010
Assignee:
Schlumberger Technology Corporation
Inventors:
Alexander Shapovalov, Alejandro Pena, Bernhard Lungwitz, Rene Schuurman
Abstract: A continuous process for producing polyamides, their oligomers or mixtures thereof, if appropriate with further reaction products, comprises reaction of aminonitriles or dinitriles and diamines or mixtures thereof, if appropriate together with further polyamide-forming monomers and/or oligomers, with an aqueous medium composed of aqueous monomer and oligomer extracts obtained from polyamide production by extraction of the polymer with water in a reactor which has a vertical longitudinal axis and through which there is a flow substantially in the longitudinal direction wherein water and/or the aqueous medium are introduced into the reactor at two or more different locations along the vertical longitudinal axis, wherein the aqueous medium is introduced at one or more locations.
Type:
Grant
Filed:
February 8, 2005
Date of Patent:
August 17, 2010
Assignee:
BASF Aktiengesellschaft
Inventors:
Jürgen Deininger, Jürgen Demeter, Thilo Hahn, Gad Kory, Oliver Sötje, Peter Zehner
Abstract: Injectable hydrogel microspheres are prepared by forming an emulsion where hydrogel precursors are in a disperse aqueous phase and polymerizing the hydrogel precursors. In a preferred case, the hydrogel precursors are poly(ethylene glycol) diacrylate and N-isopropylacrylamide and the continuous phase of the emulsion is an aqueous solution of dextran and a dextran solubility reducer. The microspheres will load protein, e.g., cytokines, from aqueous solution.
Abstract: What is disclosed relates to polymers that resist dissolution in organic solvents, are vasodilators, and are tunable explosives. These polymers also form solvent resistant coatings and solvent resistant fibers as well as bonding materials.
Type:
Grant
Filed:
February 3, 2006
Date of Patent:
August 17, 2010
Assignee:
Central Michigan University Board of Trustees
Abstract: A process and apparatus for rapidly producing an emulsion and microcapsules in a simple manner is provided wherein a dispersion phase is ejected from a dispersion phase-feeding port toward a continuous phase flowing in a microchannel in such a manner that flows of the dispersion phase and the continuous phase cross each other, thereby obtaining microdroplets, formed by the shear force of the continuous phase, having a size smaller than the width of the channel for feeding the dispersion phase.
Abstract: According to the present invention, there is provided expandable beads of a styrene-modified linear low-density polyethylene-based resin comprising a volatile blowing agent and a base resin, the base resin containing more than 300 parts by weight and less than 1000 parts by weight of a polystyrene-based resin component relative to 100 parts by weight of a non-crosslinked linear low-density polyethylene-based resin component, wherein the base resin contains 2 to 40 wt % of a gel component comprising a graft copolymer of the polystyrene-based resin component and the low-density polyethylene-based resin component.
Abstract: According to the present invention, there is provided expandable beads of a styrene-modified linear low-density polyethylene-based resin comprising a volatile blowing agent and a base resin, the base resin containing more than 50 to 1000 parts by weight of a polystyrene-based resin component relative to 100 parts by weight of a non-crosslinked linear low-density polyethylene-based resin component, wherein the base resin contains less than 2 wt % of a gel component comprising a graft polymer of the polystyrene-based resin component and the low-density polyethylene-based resin component.
Abstract: The invention relates to a process for increasing the molecular weight of a polyamide via solid-state post-condensation by exposing the polyamide in the solid-state at elevated temperature to an inert gas atmosphere, that comprises a step (a) wherein the gas atmosphere to which the polyamide is exposed has a dew temperature Tdew-1, followed by a step (b) wherein the gas atmosphere to which the polyamide is exposed has a dew temperature Tdew-2, whereby Tdew-1 is higher than Tdew-2. The effect is that a high molecular weight polyamide can be obtained in a shorter production time.