Abstract: Novel treating fluid compositions containing crosslinkable non-ionic cellulose derivatives and methods of use in petroleum recovery operations are disclosed. The treating fluid polymers are prepared by reacting vinyl monomers having a crosslinkable substituent with a cellulose derivative using a redox system comprising the reaction product of hydrogen peroxide with ferrous salt. The polymers readily crosslink with polyvalent metal ions, such as zirconium and titanium, to form temperature-stable gels useful in petroleum recovery operations.
Abstract: Early-rain-resistant joint-sealing compounds containing(a) aqueous polymer dispersions (I),(b) nonionic cellulose ethers (II) selected from the group consisting of hydroxyethyl, hydroxyethyl-methyl, hydroxypropyl-methyl and hydroxypropyl cellulose,(c) fillers, and(d) optionally typical additives, such as pigments, plasticizers, extenders, thickeners, foam inhibitors, dispersion aids, pH regulators, preservatives and anti-aging agents,which can be produced by thorough mixing of (I) with the other constituents. To be able to introduce (II) in quantities above the solubility limit, the joint-sealing compounds are characterized in that (II) is added and intermixed in retarded form in admixture with the fillers.
Type:
Grant
Filed:
October 19, 1990
Date of Patent:
June 2, 1992
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Helmut Loth, Klaus Helpenstein, Tore Podola, Bernhard Knop