Abstract: The present invention relates to an aqueous coating composition comprising polyurethane A and vinyl polymer, wherein the polyurethane A comprises as building blocks at least: (a) a polyisocyanate(s) containing at least two cyclic groups, (b) a non-cyclic aliphatic diisocyanate(s) whereby the non-cyclic aliphatic group connecting the two isocyanate groups has from 4 to 36 carbon atoms, and (c) a component(s) containing an isocyanate-reactive group(s), whereby the summed amount of (a) and (b) is 10 to 60 wt. %, relative to the total weight amount of components used to prepare the polyurethane A; and whereby the weight ratio between (a) and (b) is in the range from 50:50 to 99:1.
Type:
Grant
Filed:
February 7, 2018
Date of Patent:
July 12, 2022
Assignee:
COVESTRO (NETHERLANDS) B.V.
Inventors:
Ilse Van Casteren, Ronald Tennebroek, Gerardus Cornelis Overbeek, Jourraine Celestijn
Abstract: A deformable yet mechanically resilient microcapsule having electrical properties, a method of making the microcapsules, and a circuit component including the microcapsules. The microcapsule containing a gallium liquid metal alloy core having from about 60 to about 100 wt. % gallium and at least one alloying metal, and a polymeric shell encapsulating the liquid core, said polymeric shell having conductive properties.
Type:
Grant
Filed:
August 12, 2020
Date of Patent:
July 5, 2022
Assignee:
United States of America as represented by the Secretary of the Air Force
Abstract: The present invention is a composite stretchable film including: a surface film which is a cured product of a polyurethane 1 containing a copolymer of one or more of units “a1” to “a4” and silicone-pendant type urethane units “b1” and/or “b2” represented by the following general formula (1); and an inner film which is a cured product of a polyurethane 2 containing a unit “c” having polyether and urethane bonds represented by the following general formula (2), on which the surface film is laminated. The present invention provides a stretchable film that has excellent stretchability and strength, with the film surface having excellent water repellency, and a method for forming the same.
Type:
Grant
Filed:
November 4, 2019
Date of Patent:
July 5, 2022
Assignee:
SHIN-ETSU CHEMICAL CO., LTD.
Inventors:
Jun Hatakeyama, Motoaki Iwabuchi, Joe Ikeda
Abstract: The present invention addresses a problem of providing, for example, a metal surface treatment agent capable of forming a coating film that exhibits good corrosion resistance at edges, such as cut portions, of a coated metal material. The problem is solved by a metal surface treatment agent comprising: an ion (A) containing at least one kind of metal selected from zirconium, titanium and hafnium at a metal-equivalent molar concentration of 0.1 mmol/L or higher; and an aqueous urethane resin (B) having a weight-average molecular weight of 50,000 or higher at a solid mass concentration of 0.5 to 10 g/L, in which the ratio of a solid mass (BM) of the resin (B) to a metal-equivalent mass (AM) of the ion (A), [BM/AM], is 0.7 or higher.
Abstract: Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and an emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the emulsifier is the product of a reaction between an alkyl cyclic anhydride and a polar reactant, wherein the polar reactant is one or more selected from a group containing alkyl amine, alkanolamine, and polyamine. Methods may include drilling a wellbore with an oil-based mud, wherein the oil-based mud is an invert emulsion containing an emulsifier stabilizing the invert emulsion, wherein the emulsifier is the product of a reaction between an alkyl cyclic anhydride and a polar reactant, wherein the polar reactant is one or more selected from the group of alkyl amine, alkanolamine, and polyamine.
Type:
Grant
Filed:
December 18, 2017
Date of Patent:
July 5, 2022
Assignee:
SCHLUMBERGER TECHNOLOGY CORPORATION
Inventors:
Yiyan Chen, Dimitri M. Khramov, Reda Karoum
Abstract: A quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of synthesizing a quaternary amine composition comprising the steps of reacting an alkoxylated dimer diamine with a methyl halogen, where the methyl halogen is selected from the group consisting of methyl chloride, methyl iodine, and combinations of the same; and allowing the reaction to proceed to produce the quaternary amine composition, the quaternary amine composition selected from the group consisting of Formula I, Formula II, Formula III, and combinations of the same. A method of treating a well comprising the steps of introducing an additive-containing well fluid to a well, where the additive-containing well fluid comprises a quaternary amine composition and a well fluid, allowing the additive-containing well fluid to interact with the well, and treating the well with the additive-containing fluid.
Abstract: The radiation curable compositions (I) that comprise from 10 to 80 by weight of at least one silicone-modified urethane (meth) acrylate (A), from 0.5 to 60 by weight of at least one (meth) acrylated compound (B) bearing at least 5 (meth) acryloyl groups per molecule, and optionally, from 10 to 60% by weight of at least one compound (C) different from (A) or (B), wherein the weight percentages are on the total weight of the composition (I). These materials can be used for producing coatings, inks and overprint varnishes with excellent anti-stain properties, to their use and preparation. Materials of the invention are compatible with standard radiation curable materials. They allow to obtain excellent anti-stain properties for high gloss coatings as well as for matte coatings (II) with a gloss level at 60° of at most 15, even at most 10.
Abstract: The invention relates to melt spun multifilaments based on thermoplastic polyurethane, their production and the use of said melt spun multifilaments to produce technical textiles and clothing such as socks, stockings, compression textiles like medical bandage, surgical hose, orthopedic elastic bandage, sport textiles, underwear etc.
Type:
Grant
Filed:
September 8, 2017
Date of Patent:
May 31, 2022
Assignee:
Covestro Deutschland AG
Inventors:
Christian Wamprecht, Jochen Norwig, Christoph Gürtler, Pavan Manvi, Gunnar Seide, Thomas Gries
Abstract: Lightweight proppant particles are disclosed. The lightweight proppant particle can include a proppant particle having an apparent specific gravity of at least about 1.5 g/cc, a coating of a hydrophobic material formed on an outer surface of the proppant particle, and a coating of an amphiphilic material formed on an outer surface of the coating of the hydrophobic material.
Type:
Grant
Filed:
May 17, 2019
Date of Patent:
May 24, 2022
Assignee:
CARBO CERAMICS INC.
Inventors:
Todd Roper, Thu Lieng, Olatunji Orekha, William Scott Woolfolk
Abstract: Spherical polyester-based resin particles characterized in that the spherical polyester-based resin particles contain a polyester-based resin and have a crystallinity of 20% or less and an average circularity of 0.96 or more. The spherical polyester-based resin particles according to the present invention can provide suitable resin particles as compounding agents for cosmetics such as foundation, antiperspirants, and skin scrubs; various agents such as matte coating agents for paints, rheology modifying agents, antiblocking agents, slipperiness-imparting agents, light diffusion agents, electroconductive agents, and diagnostic testing agents for medical use; and additives to molded articles such as automobile materials and construction materials.
Abstract: A cementitious mixture to make structures with reduction of gas permeability was disclosed. The mixture includes, cementitious materials, and one or more divalent magnesium-iron silicate that in neutral or basic aqueous solutions have the capacity to be a latent hydraulic binder comprising 2% to 99% of divalent magnesium-iron silicate by weight of total hydraulic solid materials. This can be used to produce a cementitious structure for preventing gas transfer between a first region and a second region. A cement slurry was also disclosed.
Abstract: The invention relates to an aqueous viscoelastic solution comprising: at least one polymer selected from among hyaluronic acid and the salts thereof, and cellulosic derivatives and the salts thereof, in particular hydroxypropyl methylcellulose and the salts thereof; and at least one water-soluble polymer of the polyether-polyurethane or polyether-polyester-urethane type, and to the use thereof in a device intended for the injection of an intraocular implant.
Type:
Grant
Filed:
February 9, 2018
Date of Patent:
May 3, 2022
Assignee:
POLYMEREXPERT SA
Inventors:
Marc Dolatkhani, Anne Pagnoux, Sonia Dakhli
Abstract: The disclosure relates to an electrocrushing drilling fluid with an electrocrushing drilling base fluid including a non-polar oil, water, and glycerin. The base fluid may further include a polar oil and an alkylene carbonate. The electrocrushing drilling fluid may further contain at least one additive. The electrocrushing drilling fluid may have a dielectric constant or dielectric strength of at least a set amount, an electric conductivity less than a set amount, or a combination of these properties. The disclosure further relates to an electrocrushing drilling system containing the electrocrushing drilling fluid and an electrocrushing drill bit.
Type:
Grant
Filed:
June 10, 2020
Date of Patent:
May 3, 2022
Assignees:
Halliburton Energy Services, Inc., Chevron U.S.A. Inc.
Inventors:
Donald Curtis Van Slyke, William Walter Shumway
Abstract: The present invention relates to a method for producing biodegradable microspheres having improved safety and storage stability, and a method for producing the same. The present invention provides a method for preparing said biodegradable microspheres while minimizing the morphological changes of microspheres and significantly reducing residual solvents.
Abstract: Embodiments of the present application relate to commercial manufacturing processes for making bupivacaine multivesicular liposomes (MVLs) using independently operating dual tangential flow filtration modules.
Type:
Grant
Filed:
November 29, 2021
Date of Patent:
April 26, 2022
Assignee:
Pacira Pharmaceuticals, Inc.
Inventors:
Jeffrey S. Hall, David J. Turnbull, John J. Grigsby, Jr., Soroush M. Ardekani, Paige N. Davis, Louie D. Garcia, Stephanie M. Kurz, Kathleen D. A. Los
Abstract: Embodiments of the present application relate to commercial manufacturing processes for making bupivacaine multivesicular liposomes (MVLs) using independently operating dual tangential flow filtration modules.
Type:
Grant
Filed:
November 29, 2021
Date of Patent:
April 19, 2022
Assignee:
Pacira Pharmaceuticals, Inc.
Inventors:
Jeffrey S. Hall, David J. Turnbull, John J. Grigsby, Jr., Soroush M. Ardekani, Paige N. Davis, Louie D. Garcia, Stephanie M. Kurz, Kathleen D. A. Los
Abstract: An ultra low density film and an ultra low density solid material are produced by the steps of providing a vessel, introducing two immiscible fluids into the vessel, adding nanocrystals to at least one of the two immiscible fluids, applying a shear force to the two immiscible fluids and the nanocrystals in a manner that causes the nanocrystals to self-assemble and form colloidosomes. The colloidosomes amass and evaporation of the two fluids produces dried colloidosomes. The ultra low density self-assembled colloidosomes are hollow self-assembled colloidosomes, which are formed into the ultra-low density film and the ultra-low density solid.
Type:
Grant
Filed:
October 24, 2018
Date of Patent:
April 19, 2022
Assignees:
Lawrence Livermore National Security, LLC, Carnegie Mellon University
Inventors:
Christine A Orme, Sarah Baker, Yixuan Yu, Shelley L Anna, Charles Sharkey
Abstract: The present invention is directed to an aqueous curable film-forming composition comprising: (a) a film-forming component comprising an aliphatic di- or higher functional polyisocyanate; and (b) a catalyst additive comprising: (i) a catalytic organic compound comprising iron and/or tin; and (ii) a beta-diketone. The present invention is further directed to a method of controlling the rate of cure of an aqueous curable film-forming composition. The method comprises adding to the aqueous curable film-forming composition the catalyst additive described above; the aqueous curable film-forming composition comprises a film-forming component comprising an aliphatic di- or higher functional polyisocyanate. The present invention is additionally directed to a coated article comprising a cured coating layer applied on at least one surface of a substrate to form a coated substrate; wherein the cured coating layer is deposited from the aqueous curable film-forming composition described above.
Type:
Grant
Filed:
March 1, 2018
Date of Patent:
April 19, 2022
Assignee:
PPG Industries Ohio, Inc.
Inventors:
Silvia Bezer, Steven R. Zawacky, Diane Schillinger
Abstract: A thermoplastic polyurethane film including a cured product of a polyurethane resin composition is provided. The polyurethane resin composition includes a polyurethane resin, a first isocyanate-based curing agent, and an organic solvent. The thermoplastic polyurethane film has a tensile strength break of 50 MPa to 80 MPa. A method for preparing the thermoplastic polyurethane film is also provided.
Type:
Grant
Filed:
March 27, 2018
Date of Patent:
April 12, 2022
Inventors:
Sang Yool Lee, Joo Hee Hong, Se Jung Park, Sang Hwan Kim, Jang Soon Kim
Abstract: Described herein are penetrating compositions that include ethoxylated C12-C16 alcohols, 2-ethyl hexanol, and isopropyl alcohol, and are injectable into a near-wellbore subterranean formation. The penetrating compositions may include water or brine. The penetrating compositions are free of ethylene glycol monobutyl ether (EGMBE) and nonylphenol ethoxylates (NPE). Also described are methods of using penetrating compositions that that include introducing a penetrating composition into a near-wellbore formation and reducing surface tension at an oil/water interface within the formation.
Type:
Grant
Filed:
August 6, 2019
Date of Patent:
March 29, 2022
Assignee:
Halliburton Energy Services, Inc.
Inventors:
Shoy Chittattukara George, Antonio Recio, III, Rahul Chandrakant Patil, Jason Maxey