Abstract: A thermoplastic elastomer foaming material is provided. The thermoplastic elastomer foaming material includes a hydrogenated styrenic/conjugated diene copolymer in a range from 5 to 35 weight percent; at least one of an acetate copolymer and an acrylate copolymer in a range from 3 to 30 weight percent; an amorphous polyolefin in a range from 20 to 60 weight percent; and a plasticizer in a range from 10 to 40 weight percent.
Type:
Grant
Filed:
December 21, 2009
Date of Patent:
February 16, 2016
Assignee:
TSRC CORPORATION
Inventors:
Jan-Rong Su, Cheng-Te Lee, Ching-En Tsai
Abstract: A carbanionic polymer chain that contains polyene mer can be provided with a terminal functionality separated from the polymer chain by a sulfide linkage. The terminally functionalized polymer can be provided by reacting a carbanionic polyene-based polymer with an episulfide compound to provide a polymer with a terminal thiolate moiety, followed by reaction with an epoxide compound that also includes at least one other heteroatom-containing functional group.
Abstract: Extruded or molded profiles comprising a polyolefin composition consisting of 85% by weight or more of a copolymer of 1-butene with ethylene (A) having an ethylene copolymerized content up to 18% by mol, and having Mw/Mn lower than 3, hardness shore A (measured according to ISO 868) lower than 90, no melting point (TmII) detectable at the DSC after cancelling the thermal history, melting enthalpy (?Hf), measured by DSC after 10 days of aging at room temperature, comprised between 4 and 15 J/g; and up to 15% by weight of a propylene copolymer or a composition of copolymers of propylene (B) having a melting point from about 126° C. to 200° C., isotactic index greater than 90%.
Type:
Grant
Filed:
February 12, 2013
Date of Patent:
February 2, 2016
Assignee:
Basell Poliolefine Italia S.r.l.
Inventors:
Paolo Ferrari, Luca Lunghi, Roberta Marchini, Stefano Spataro, Giampaolo Pellegatti, Caroline Cathelin, Stefano Pasquali
Abstract: An adduct of (a) at least one divinylarene dioxide, and (b) at least one end-functionalized polymer. For example, the adduct may be beneficially used as a toughening agent for toughening thermoset resins such as epoxy resins.
Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
Type:
Grant
Filed:
May 15, 2014
Date of Patent:
January 26, 2016
Assignee:
Dow Global Technologies LLC
Inventors:
Daniel J. Arriola, Edmund M. Carnahan, Yunwa Wilson Cheung, David D. Devore, David D. Graf, Phillip D. Hustad, Roger L. Kuhlman, Colin Li Pi Shan, Benjamin C. Poon, Gordon R. Roof, James C. Stevens, Pamela J. Stirn, Timothy T. Wenzel
Abstract: Fluorinated macromonomers, a PCTFE-g-poly(M) graft copolymer, and moisture barrier films and articles formed therefrom are provided. The PCTFE-g-poly(M) graft copolymers have a PCTFE backbone component and a plurality of pendant groups attached to the PCTFE backbone component.
Type:
Grant
Filed:
December 13, 2012
Date of Patent:
January 12, 2016
Assignee:
Honeywell International Inc.
Inventors:
Alagappan Thenappan, Eric Rainal, Bruno Ameduri, Frédéric Boschet, Noureddine Ajellal, Gerald Lopez
Abstract: Coating compositions are disclosed. In some embodiments, the coating compositions are used to coat substrates such as packaging materials and the like for the storage of food and beverages. The coating compositions can be prepared by reacting an epoxidized vegetable oil and a hydroxyl functional material in the presence of an acid catalyst to form a hydroxyl functional oil polyol, mixing the hydroxyl functional oil polyol (with or without epoxidized polybutadiene) and a functional polyolefin copolymer to form a mixture, reacting the mixture with an ethylenically unsaturated monomer component in the presence of an initiator to form a graft copolymer, and crosslinking the graft copolymer with a crosslinker to form the coating composition, wherein the graft copolymer or the crosslinked graft copolymer is inverted into water.
Type:
Grant
Filed:
December 18, 2012
Date of Patent:
January 5, 2016
Assignee:
AKZO NOBEL COATINGS INTERNATIONAL B.V.
Inventors:
Cathy Li, Timothy I Memmer, Daniel Bode, Stefan Posakiwsky
Abstract: The invention relates to compounds for producing polymethacrylimide foam materials (PMI foams) with particularly good mechanical properties, in particular with a particularly advantageous elongation at tear. The invention further relates to methods for producing, processing, and using said foam materials. In particular, the invention relates to novel materials, the propensity of which to form tears is clearly reduced in comparison to the prior art. This is tantamount to an elongation at tear that is higher in comparison to the prior art.
Type:
Grant
Filed:
June 29, 2011
Date of Patent:
December 15, 2015
Assignee:
Evonik Roehm GmbH
Inventors:
Kay Bernhard, Mathias Hempler, Werner Geyer, Thomas Barthel, Torsten Jahn
Abstract: The application provides a method of producing a comb polymer comprising the steps of: (a) Providing: (i) a plurality of monomers which are linear, branched or star-shaped, substituted or non-substituted, and have an olefinically unsaturated moiety, the olefinically unsaturated moiety being capable of undergoing addition polymerisation; (ii) an initiator compound; the initiator compound comprising a homolytically cleavable bond. (iii) a catalyst capable of catalysing the polymerisation of the monomer; and (b) Causing the catalyst to catalyse, in combination with the initiator, the polymerisation of a plurality of the monomers to produce the comb polymer. Catalysts and polymers obtainable by the process are also provided. Preferably, the comb polymer is capable of binding proteins and may be produced from monomers which are alkoxy polyethers, such as poly(alkyleneglycol) or polytetrahydrofuran.
Type:
Grant
Filed:
April 5, 2013
Date of Patent:
December 1, 2015
Assignee:
Warwick Effect Polymers Limited
Inventors:
David M. Haddleton, Francois LeColley, Lei Tao, Giuseppe Mantovani, Adrian Carmichael, Adam Peter Jarvis, Andrew Gregory Steward
Abstract: The present invention provides an optical film and a retardation film that each include an acryl resin, and 20 to 65 parts by weight of a graft copolymer including a conjugated diene rubber based on 100 parts by weight of the acryl resin, and an electronic device including the same.
Type:
Grant
Filed:
May 2, 2014
Date of Patent:
November 17, 2015
Assignee:
LG CHEM, LTD.
Inventors:
Byoung-Il Kang, Chan-Hong Lee, Chang-Hun Han
Abstract: A highly active and environment-friendly catalyst for use in a living radical polymerization is provided. A catalyst for use in a living radical polymerization method is provided. The catalyst comprises a central element, which is selected from nitrogen and phosphorus, and at least one halogen atom, which is bound to the central element. A monomer having a radical reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, thereby it is possible to obtain a polymer having narrow molecular weight distribution. The present invention has the merits such as low toxicity of the catalyst, a small amount of the catalyst being required, high solubility of the catalyst in the polymerization media, mild reaction conditions, no coloration, no odor (unnecessary post-treatment of molded products). The method of the present invention is more environment-friendly and economical than other living radical polymerization methods.
Abstract: An acrylic pressure-sensitive adhesive tape including an acrylic pressure-sensitive adhesive layer, wherein a 180° peel adhesive force of the acrylic pressure-sensitive adhesive tape to a glass plate is 10 N/20 mm or more and a 180° peel adhesive force of the acrylic pressure-sensitive adhesive tape to an acrylic plate is 10 N/20 mm or more. The acrylic pressure-sensitive adhesive layer contains an acrylic polymer (A), has a gel fraction of 65% or more, and has a 300% tensile residual stress of from 7 to 16 N/cm2.
Abstract: This invention relates to a reaction product obtained by ring-opening metathesis polymerization of norbornene ketones functionalized with the residual portion of a vinyl terminated macromonomer.
Abstract: A method of making a graft copolymer, comprising the steps of obtaining a first polymer comprising at least one carbon-carbon double bond, the first polymer derived from at least one first monomer, the at least one first monomer comprising a conjugated diene monomer; obtaining a second polymer, the second polymer capable of exhibiting a lower critical solution temperature (LCST) and comprising a terminal functional group capable of reacting with the carbon-carbon double bond; and reacting the second polymer with the first polymer to form a graft copolymer, the graft copolymer comprising a backbone derived from the first polymer and sidechains derived from the second polymer.
Type:
Grant
Filed:
December 21, 2011
Date of Patent:
October 13, 2015
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Ralf Mruk, Frank Schmitz, Robert Fokko Roskamp, Alexandra Hermann, Rudolf Wilhelm Zentel
Abstract: Provided is a block copolymer of a conjugated diene compound and a non-conjugated olefin, a rubber composition including the block copolymer, a crosslinked rubber obtained by crosslinking the rubber composition, and a tire using the rubber composition or the crosslinked rubber composition. The copolymer of the present invention is a block copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer having a peak area in a temperature range in a range of 70° C. to 110° C. that accounts for at least 60% of a peak area in a range of 40° C. to 140° C. and a peak area in a range of 110° C. to 140° C. that accounts for 20% or less of a peak area in a range of 40° C. to 140° C., the peak areas being measured by the differential scanning calorimetry (DSC) according to JIS K 7121-1987.
Abstract: The present invention is directed to a copolymer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer capable of exhibiting a lower critical solution temperature (LCST).
Type:
Grant
Filed:
December 21, 2011
Date of Patent:
September 15, 2015
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Ralf Mruk, Frank Schmitz, Robert Fokko Roskamp, Alexandra Hermann, Rudolf Wilhelm Zentel
Abstract: The present invention provides for monodispersed dendrimers having a core, branches and periphery ends, wherein the number of branches increases exponentially from the core to the periphery end and the length of the branches increases exponentially from the periphery end to the core, thereby providing for attachment of chemical species at the periphery ends without exhibiting steric hindrance.
Type:
Grant
Filed:
January 29, 2013
Date of Patent:
September 15, 2015
Assignees:
UNIVERSITY OF MARYLAND, BALTIMORE, UNIVERSITY OF MARYLAND, COLLEGE PARK
Abstract: Methods for preparing an impact copolymer by selecting a continuous phase polymer having a first melt flow rate and selecting a rubber phase polymeric material such that the final melt flow rate of the impact copolymer is within 2 g/10 min of the first melt flow rate. Impact copolymers made from such methods and films and molded articles produced from such impact copolymers are also included.
Abstract: Disclosed herein is a curable composition comprising a polyhydroxy curable fluoroelastomer, a polyhydroxy curative, a cure accelerator and an unsaturated metal compound process aid comprising a siloxane having at least one vinyl or allyl group bonded to a silicon atom. Such curable compositions have a lower Mooney viscosity than do similar compositions absent the process aid.
Abstract: The invention provides a composition comprising a first composition, which first composition comprises the following: A) a first interpolymer comprising, in polymerized form, ethylene, an ?-olefin and a nonconjugated polyene; B) a second interpolymer comprising, in polymerized form, ethylene, an ?-olefin and a nonconjugated polyene; and wherein the first composition has at least one of the following features: a) an [(ML(1+4, 125° C.))/Mw(conv)]*1000 greater than 0.429 mole/g; b) a Mooney Viscosity (ML, 1+4, 125° C.) greater than, or equal to, 70, and has a low shear viscosity (? at 0.1 rad/sec) less than, or equal to, 100,000 Pa·sec; and c) a Mooney Viscosity (ML(1+4, 125° C.)) greater than, or equal to, 70, and has an [Mw(abs)]/[Mw(conv)] less than 1.2.
Type:
Grant
Filed:
July 14, 2010
Date of Patent:
August 11, 2015
Assignee:
Dow Global Technologies LLC
Inventors:
Wenbin Liang, Brian W. Walther, Timothy E. Clayfield, Arnis U. Paeglis, Sherrika D. Daniel, Larry A. Meiske