Patents Examined by Jeffrey Mullis
  • Patent number: 8466234
    Abstract: The present invention relates to the production of amphiphilic copolymer networks, or co-networks, and to methods for preparing amphiphilic co-networks. Furthermore, the present invention relates to products and/or films made from the amphiphilic co-networks produced in accordance with the synthesis methods of the present invention. In one embodiment, the present invention is related to crosslinkable and/or polymerizable compositions that can be utilized to form amphiphilic co-networks, where such compositions are block copolymer compositions that are formed from the combination of at least one hydrophilic segment, at least one hydrophobic segment, and at least one crosslinkable and/or polymerizable segment. In yet another embodiment, the present invention relates to amphiphilic co-networks that are optically clear and highly oxyphilic.
    Type: Grant
    Filed: April 4, 2008
    Date of Patent: June 18, 2013
    Assignee: The University of Akron
    Inventors: Joseph P. Kennedy, Radhakrishnan Karunakaran
  • Patent number: 8465844
    Abstract: Hot melt adhesive compositions containing radial polystyrene-polyisoprene/polybutadiene block copolymer and use as elastic attachment adhesive in the manufacture of disposable absorbent elastic articles.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: June 18, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Qiwei He, Michael G. Harwell
  • Patent number: 8466233
    Abstract: A polylactic acid-based resin composition including a polylactic acid (A), a multilayered polymer (B) and a multilayered polymer (C), wherein the content of each of the multilayered polymer (B) and the multilayered polymer (C) is 0.5 to 8% by mass of the whole resin composition; the multilayered polymer (B) and the multilayered polymer (C) are each constituted of a core layer(s) and a shell layer(s); the core layer constituting the multilayered polymer (B) contains an acrylic rubber; and the core layer constituting the multilayered polymer (C) contains a composite rubber containing an acrylic component and a silicone component.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: June 18, 2013
    Assignee: Unitika Ltd.
    Inventors: Keisuke Kimura, Kazue Ueda
  • Patent number: 8466232
    Abstract: The invention concerns a biodegradable copolymer composition of a polysaccaride backbone grafted with amphiphilic diblock copolymers, as well as a process for the preparation of such composition and a particle suitable for the release of active ingredients made of such a composition.
    Type: Grant
    Filed: October 30, 2006
    Date of Patent: June 18, 2013
    Assignee: Firmenich SA
    Inventors: Damien Berthier, Lahoussine Ouali
  • Patent number: 8466214
    Abstract: Processes for making a core and core-shell copolymers are provided herein. Processes for making crosslinked elastomeric core particles includes emulsion polymerizing, in the presence of a radical polymerization initiator, a polymerization mixture containing at least one ethylenic elastomeric monomer, at least one crosslinking agent, and at least one sulfur-containing additive of the formula I below, where R and Z are defined herein. The core-shell copolymers formed are useful for example as additives in polymer matrices such as for modifying impact strength and improving optical properties.
    Type: Grant
    Filed: August 4, 2009
    Date of Patent: June 18, 2013
    Assignee: Arkema France
    Inventors: Rosangela Pirri, Philippe Hajji
  • Patent number: 8461246
    Abstract: The present invention provides a mixture of conjugated diene-vinyl aromatic hydrocarbon copolymers and an adhesive having the same. The mixture of conjugated diene-vinyl aromatic hydrocarbon copolymers comprises 10 to 45 wt. % of a conjugated diene-vinyl aromatic hydrocarbon di-block copolymer, 10 to 45 wt. % of a conjugated diene-vinyl aromatic hydrocarbon tapered di-block copolymer and 10 to 80 wt. % of a conjugated diene-vinyl aromatic multi-block copolymer.
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: June 11, 2013
    Assignee: TSRC Corporation
    Inventors: Kung-Hsi Chan, Tsung Hsin Chen, Tai Wen Chiu
  • Patent number: 8455587
    Abstract: The invention provides a crystalline polyamide-type resin composition comprises (a) a crystalline polyamide resin composition comprising (i) 50 to 90% by weight of crystalline polyamide resin (A) having a relative viscosity in 96% sulfuric acid of not less than 3.5 and (ii) 50 to 10% by weight of a crystalline polyamide resin (B) having a melting point lower than the melting point of polyamide resin (A) by 20° C. or more and a relative viscosity dissolved in 96% sulfuric acid of not more than 3.6, and (b) 1 to 10 part(s) by weight of a modified polyolefin resin (C) having a reactive functional group being able to react with the terminal group and/or main-chain amide group of the polyamide resin. The invention also provides a door checker for automobiles prepared from the crystalline polyamide-type resin composition.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: June 4, 2013
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Shyuji Kubota, Satoshi Sakai
  • Patent number: 8440764
    Abstract: The present invention relates to a molding composition comprising (A) a copolymer containing at least one ?,?-unsaturated monocarbonitrile and at least one aromatic vinyl monomer, (B) a graft rubber with an average particle size of from 100 to 280 nm, composed of at least one ?,?-unsaturated monocarboxylic ester, and at least one graft shell composed of at least one aromatic vinyl monomer and of at least one ?,?-unsaturated monocarbonitrile, (C) a graft rubber with an average particle size of from 410 to 1000 nm, composed of at least one ?,?-unsaturated monocarboxylic ester, and at least one graft shell composed of at least one aromatic vinyl polymer and of at least one ?,?-unsaturated monocarbonitrile, and wherein the ratio by weight of component (B) to component (C) is from 3:1 to 1:1. The invention also relates to the process of producing the molding composition and its use.
    Type: Grant
    Filed: May 6, 2011
    Date of Patent: May 14, 2013
    Assignee: Styrolution GmbH
    Inventor: Norbert Nieβner
  • Patent number: 8426030
    Abstract: Compositions suitable for use as adhesives in multi-layer structures. The compositions comprise a blend of an ethylene copolymer of butene and a propylene-based polymer; a polyolefin grafted with an ethylenically unsaturated carboxylic acid or acid derivative; and an olefin polymer resin different than the ethylene copolymer of butene, the propylene-based polymer and the grafted polyolefin.
    Type: Grant
    Filed: December 1, 2009
    Date of Patent: April 23, 2013
    Assignee: Equistar Chemicals, LP
    Inventors: Maged G. Botros, Charles S. Holland
  • Patent number: 8420736
    Abstract: An object of the present invention is to provide a thermoplastic resin composition capable of improving impact resistance and surface gloss of a molded article, and a molded article thereof. A thermoplastic resin composition of the present invention is comprising 100 parts by weight of a thermoplastic resin (a) and 0.5 to 30 parts by weight of a core-shell polymer composition (b), wherein the core-shell polymer composition (b) is obtained by polymerizing the shell-constituting components in the presence of a core obtained by polymerizing a monomer mixture (100% by weight in total) of 70% to 99.95% by weight of an alkyl acrylate having an alkyl group of 2 to 18 carbon atoms, 0.05% to 10% by weight of a polyfunctional monomer, and 0% to 20% by weight of a monomer copolymerizable with the alkyl acrylate and the polyfunctional monomer, and the polyfunctional monomers contains at least a compound having a plurality of same radically polymerizable functional groups in the molecule thereof.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: April 16, 2013
    Assignee: Kaneka Corporation
    Inventors: Fuminobu Kitayama, Kouhei Fujimoto, Yuya Manabe
  • Patent number: 8420210
    Abstract: There are provided a resin composition comprising a crosslinking component with a weight average molecular weight of 1,000 or less having a plurality of styrene groups and represented by the following formula: wherein R is a hydrocarbon skeleton, each of R1s is a hydrogen atom or a hydrocarbon group, each of R2, R3 and R4 is a hydrogen atom or an alkyl group, m is an integer of 1 to 4, and n is an integer of 2 or more, at least one high-molecular weight compound, an inorganic filler, and at least one treating agent for said inorganic filler; its cured product; and a prepreg, a laminate sheet having a conductor layer, and a multilayer printed wiring board obtained by processing the conductor layer of the laminate sheet into wiring.
    Type: Grant
    Filed: August 10, 2007
    Date of Patent: April 16, 2013
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Satoru Amou, Morimichi Umino, Akira Nagai, Yoshihiro Nakamura, Nobuyuki Minami
  • Patent number: 8415429
    Abstract: We disclose a monovinylarene-conjugated diene block copolymer containing a plurality of monovinylarene-conjugated diene mixed blocks, wherein each mixed block contains conjugated diene units and monovinylarene units in a weight ratio of about 0.05 to about 0.33. We also disclose a composition containing (a) from about 50 parts by weight to about 95 parts by weight of the monovinylarene-conjugated diene block copolymer and (b) from about 5 parts by weight to about 50 parts by weight of polystyrene; wherein the monovinylarene-conjugated diene block copolymer and the polystyrene total 100 parts by weight.
    Type: Grant
    Filed: December 11, 2006
    Date of Patent: April 9, 2013
    Assignee: Chervron Phillips Chemical Company LP
    Inventors: John Mark Brown, Michael A. Smith, Nathan E. Stacy, Carleton E. Stouffer, John D. Wilkey
  • Patent number: 8415428
    Abstract: The present invention provides a thermoplastic elastomer composition obtained by dynamically crosslinking, under a melting condition, 100 parts by mass of a block copolymer (I), 1 to 1,000 parts by mass of a polar resin (II), 1 to 500 parts by mass of a modified polymer (III), and 0.01 to 50 parts by mass of a crosslinking agent (IV), wherein the block copolymer (I) comprises at least one polymer block (A) comprising as a main component an alkylene unit, and/or at least one copolymer block (B) comprising as main components an alkylene unit (b-1) and a vinyl aromatic monomer unit (b-2), and comprises at least one unsaturated block (C) comprising as a main component a conjugated diene monomer unit having 5 or more carbon atoms at an end.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: April 9, 2013
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Daisuke Shimizu, Yasuhiro Kusanose, Yoshifumi Araki, Masahiro Fujiwara
  • Patent number: 8410214
    Abstract: The present invention provides a thermoplastic resin composition comprising 100 mass parts of a polycarbonate resin composition comprising 50 to 95 mass % of (A) a polycarbonate resin and 50 to 5 mass % of (B) a polylactic acid based resin and 5 to 65 mass parts of (C) a vinyl based graft copolymer. The above thermoplastic resin composition comprising the polycarbonate resin and the lactic acid based resin and endowed with a mechanical characteristic of polycarbonate and an excellent fluidity of polylactic acid in combination is improved in a hydrolysis resistance and provides a molded article further improved in an impact resistance and a thin-walled falling weight impact strength.
    Type: Grant
    Filed: December 27, 2005
    Date of Patent: April 2, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Yusuke Hayata, Akio Nodera
  • Patent number: 8410215
    Abstract: A thermoplastic resin composition contains (i) a polylactic acid, (ii) a polyolefin, and (iii) a compatibilizer (functional group-containing polymer that includes a functional group selected from functional groups X including a carboxyl group, an acid anhydride group, an epoxy group, a (meth)acryloyl group, an amino group, an alkoxysilyl group, a hydroxyl group, an isocyanate group, and an oxazoline group). The thermoplastic resin composition contains (iii-1) a functional group-containing hydrogenated diene polymer and (iii-2) a functional group-containing olefin polymer as the component (iii).
    Type: Grant
    Filed: August 23, 2007
    Date of Patent: April 2, 2013
    Assignee: JSR Corporation
    Inventors: Takuya Sano, Toshiyuki Hayakawa, Takeo Nakamura, Teruo Aoyama, Akihiko Okubo, Satoshi Kura
  • Patent number: 8409664
    Abstract: Superabsorbent polymer particles, coated with a block copolymer comprising at least four blocks being at least two hard blocks, one soft block and one hydrophilic block, wherein a the soft block is sandwiched between the hard blocks.
    Type: Grant
    Filed: June 27, 2011
    Date of Patent: April 2, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Robin Lynn McKiernan, Steve Daryl Smith, Axel Meyer
  • Patent number: 8399561
    Abstract: The present invention relates to a process for preparing a high impact monovinylaromatic polymer comprising admixing a rubber, at least one monovinylaromatic monomer and optionally one or more comonomer in the presence of at least a borane complex of the L-BH3 type wherein L is a Lewis base and polymerizing the monovinylaromatic monomer. The borane complex initiator, L may be an ether (e.g THF, tetrahydrofurane), a thioether (e.g dimethylthioether) or an amine. A preferred complex is an amine borane such as by way of example triethylamine borane. The present invention also relates to a high impact monovinylaromatic polymer having a weight ratio of grafted monovinylaromatic monomer and optional comonomer to the initial monovinylaromatic monomer and optional comonomer above 0.1%, advantageously above 2% and preferably in the range 2 to 4%. The invention is of particular interest to make high impact polystyrene.
    Type: Grant
    Filed: January 21, 2008
    Date of Patent: March 19, 2013
    Assignees: Total Petrochemicals France, Centre National de la Recherche Scientifique
    Inventors: Michel Duc, Bruno Vuillemin, Denis Bertin, Sylvain Marque, Christophe Galindo
  • Patent number: 8399560
    Abstract: The invention relates to the use of polyalkyl(meth)acrylate bead polymers with an average particle size V50 that ranges between 30 and 70 ?m for improving the stress cracking resistance of moulding materials containing polyalkyl(meth)acrylate. The invention also relates to moulding materials comprising: a) at least 50 wt. % of an impact resistance modifying agent, which contains at least one polyalkyl(meth)acrylate phase; b) at least 8 wt. % of a polyalkyl(meth)acrylate bead polymer with an average particle size V50 that ranges between 30 and 70 ?m; and c) between 0 and 42 wt. % of a polyalkyl(meth)acrylate with a molecular weight ranging between 20,000 and 350,000 g/mol, whereby the wt. % of the components a) to c) amounts to 100 wt. %, and to moulded bodies that can be obtained from said materials.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: March 19, 2013
    Assignee: Evonik Roehm GmbH
    Inventors: Klaus Schultes, Peter Battenhausen, Ursula Golchert, Stefan Nau, Werner Hoess
  • Patent number: 8399101
    Abstract: Disclosed is a toughened poly(hydroxyalkanoic acid) resin composition comprising poly(hydroxyalkanoic acid) and an impact modifier comprising a core/shell polymer that does not comprise a vinyl aromatic comonomer, having a refractive index not greater than 1.5; wherein the core comprises elastomer and the shell comprises non-elastomeric polymer. Also disclosed are packaging materials and packaged products comprising the composition.
    Type: Grant
    Filed: September 19, 2006
    Date of Patent: March 19, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Benjamin Andrew Smillie, Julius Uradnisheck
  • Patent number: 8394892
    Abstract: The present invention provides a thermoplastic elastomer composition comprising: 100 parts by weight of component (A), 10 to 100 parts by weight of component (B), 50 to 200 parts by weight of component (C), and 5 to 30 parts by weight of component (D). Component (A) is a propylene polymer having a melting point of 155° C. or more. Component (B) is a crystalline propylene-ethylene copolymer. Component (C) is an ethylene-?-olefin rubber having Mooney Viscosity of 30 to 100(ML1+4, 125° C.). Component (D) is a hydrogenated product of block copolymer comprising blocks of aromatic vinyl compound units and blocks of conjugated diene compound units.
    Type: Grant
    Filed: September 14, 2009
    Date of Patent: March 12, 2013
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Nadeem Akhtar Bokhari, Kousuke Ohtani, Yasuhito Ijichi