Patents Examined by Jeffrey Washville
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Patent number: 10190036Abstract: The present invention is related to the obtaining and using of multifunctional foaming compositions with wettability modifying, corrosion inhibitory and inhibitory/dispersants mineral scale properties with high stability in environments of high temperature, high pressure and tolerance to high concentrations of divalent ions such as calcium, magnesium, strontium and barium. The multifunctional foaming compositions are obtained from the combination of supramolecular complexes resulting from interactions of alkyl amido propyl hydroxysultaines and/or alkyl amido propyl betaines and/or alkyl hydroxysultaines and/or alkyl betaines and anionic surfactant of type alkyl hydroxyl sodium sulfonate and alkenyl sulphonates of sodium, with cationic surfactants as tetra-alkyl ammonium halides and copolymers derivatives of itaconic acid/sodium vinyl sulfonate and/or terpolymers derived from itaconic acid/sodium vinyl sulphonate/aconitic acid.Type: GrantFiled: November 17, 2015Date of Patent: January 29, 2019Assignee: INSTITUTO MEXICANO DEL PETROLEOInventors: Raúl Hernández Altamirano, Luis Silvestre Zamudio Rivera, Violeta Yázmin Mena Cervantes, Erick Emanuel Luna Rojero, David Aarón Nieto Álvarez, Rodolfo Cisneros Devora, Mirna Pons Jiménez, Alejandro Ramírez Estrada, América Elizabeth Mendoza Aguilar, Sung Jae Ko Kim
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Patent number: 10100243Abstract: The present invention relates to an environmentally preferable microemulsion composition that is suitable for formation stimulation, remediation, and drilling operations, and a method to make and use the same. Specifically, the environmentally preferable microemulsion composition of the present invention can comprise glycol ether, terpene, ethoxylated alcohol, polyoxyethylene sorbitan ester, and a carrier fluid.Type: GrantFiled: June 30, 2016Date of Patent: October 16, 2018Assignee: KMP HOLDINGS, LLCInventors: Sean R. Beach, Joel A. Hebert, Derek C. Mouton
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Patent number: 10087354Abstract: A downhole treatment composition comprises a rare earth-containing compound comprising one or more of the following: scandium; yttrium; lanthanum; cerium; praseodymium; neodymium; promethium; samarium; lutetium; europium; gadolinium; terbium; dysprosium; holmium; erbium; thulium; or ytterbium, wherein the downhole treatment composition is a cement slurry, a drilling fluid, or a spacer fluid. Also disclosed are methods of cementing a wellbore, methods of displacing a first fluid, and methods of drilling a wellbore in a subterranean formation using the cement slurry, the spacer fluid, or the drilling fluid.Type: GrantFiled: October 21, 2015Date of Patent: October 2, 2018Assignee: BAKER HUGHES, A GE COMPANY, LLCInventors: Shannon E. Bryant, Sumit Bhaduri, Terry D. Monroe
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Patent number: 10081761Abstract: The present invention relates to a proppant laden fracture fluid having a Mitchell quality of at least 50% and fracturing a subterranean formation therewith.Type: GrantFiled: December 22, 2014Date of Patent: September 25, 2018Assignee: PRAXAIR TECHNOLOGY, INC.Inventors: Richard M. Kelly, Afshin Esmaeil Zadeh, Mark K. Weise
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Patent number: 10067266Abstract: Disclosed is a method of producing a high-quality thiourethane-based optical material using a general-purpose polyisocyanate compound. According to the method, the pH of a polythiol compound is adjusted to 3.1 to 7 to prevent the occurrence of whitening, which is a problem of the prior art arising from the dissolution of a pressure-sensitive adhesive from a pressure-sensitive adhesive tape upon lens casting. The pH adjustment increases the reaction rate of a resin composition including the polythiol compound. The use of the polythiol compound whose pH is adjusted enables the production of a thiourethane-based optical material that does not suffer from whitening at the edges of the optical lens and nonuniformity polymerization. Further disclosed are a resin composition for a thiourethane-based optical material, and an optical material including a resin produced by the method.Type: GrantFiled: March 2, 2012Date of Patent: September 4, 2018Assignee: KOC SOLUTION CO., LTD.Inventors: Dong Gyu Jang, Soo Gyun Roh, Jong Hyo Kim
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Patent number: 10066105Abstract: A renewable material for releasing a self-healing agent includes a renewable polymeric substrate with capsules and a reactant dispersed in the renewable polymeric substrate. The capsules may be formed from a first renewable shell polymer and may enclose the renewable self-healing agent. The reactant may be suitable for reacting with the renewable self-healing agent to form a polymer.Type: GrantFiled: April 14, 2016Date of Patent: September 4, 2018Assignee: International Business Machines CorporationInventors: Dylan J. Boday, Jason T. Wertz
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Patent number: 10066051Abstract: The present invention relates to a thermoplastic copolymer, block copolymer, and statistical copolymer comprising plural acrylated polyol monomeric units having different degrees of acrylation of hydroxyl groups. The acrylated polyol monomeric units have an average degree of acrylation greater than 1 and less than the number of the hydroxyl groups of the polyol. The present invention also relates to a method of making the thermoplastic copolymer, block copolymer, and statistical copolymer, and using them in various applications, such as asphalt rubber modifiers, adhesives, or an additive in a fracking fluid for oil fracking.Type: GrantFiled: May 20, 2015Date of Patent: September 4, 2018Assignee: Iowa State University Research Foundation, Inc.Inventors: Eric W. Cochran, R. Christopher Williams, Nacu Hernandez, Elvira Joana Ferreira Peralta, Michael John Forrester
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Patent number: 10053641Abstract: A viscosity reducer based on vegetable extracts of natural origin is disclosed. The vegetable extracts include a mixture of phosphoglycerides and vegetable oils. A method of reducing the viscosity in heavy and extra heavy crude oil using the viscosity reducer is also disclosed. No aromatic base solvents are needed. A reduction in diluent usage is achieved using the viscosity reducer based on vegetable extracts. The viscosity reducer composition includes a mixture of phosphoglycerides, vegetable oil, non-aromatic solvent, polycyclic aromatic hydrocarbon and stabilizer.Type: GrantFiled: August 24, 2016Date of Patent: August 21, 2018Assignee: OIL & GAS TECH ENTERPRISES C.V.Inventor: Cridal Del Valle Sencial Bello
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Patent number: 10047275Abstract: In one aspect, a method of recovering hydrocarbons from a subterranean zone includes flowing carbon dioxide in a first state into the subterranean zone including hydrocarbons, wherein a density of the carbon dioxide in the first state is greater than a density of carbon dioxide in a gaseous state, and recovering at least a portion of the hydrocarbons in the subterranean zone in response to flowing carbon dioxide in the first state into the subterranean zone.Type: GrantFiled: December 3, 2015Date of Patent: August 14, 2018Assignee: Saudi Arabian Oil CompanyInventors: Fawaz M. Al-Otaibi, Sunil Kokal
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Patent number: 10047280Abstract: A composite having a solid particulate and a surface modifying treatment agent on the solid particulate wherein the surface modifying treatment agent has a hydrophobic tail and an anchor for adhering the hydrophobic tail onto the solid particulate. The anchor is an organophosphorus acid derivative. The composite may be used as a proppant in a hydraulic fracturing operation as well as a sand control particulate in a gravel packing operation. The presence of the surface modifying treatment agent on the surface of the solid particulate reduces the generation of fines and dust as well as the migration of sand during a hydraulic fracturing operation or a sand control operation. The presence of the surface modifying treatment agent on the surface of the solid particulate further enhances the crush resistance of the solid particulate.Type: GrantFiled: September 19, 2014Date of Patent: August 14, 2018Assignee: Baker Hughes, a GE company, LLCInventors: Terry D. Monroe, Brian B. Beall, Naima Bestaoui-Spurr, Sumit Bhaduri, Kimberly Lant, Hoang Le, Qi Qu
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Patent number: 10047283Abstract: The present invention relates to carbon-based fluorescent nano-agent tracers for analysis of oil reservoirs. The carbon-based fluorescent nano-agents may be used in the analysis of the porosity of a formation. The nanoagents are suitable for injection into a petroleum reservoir and may be recovered from the reservoir for the determination of hydrocarbon flow rates and retention times.Type: GrantFiled: November 14, 2016Date of Patent: August 14, 2018Assignees: Saudi Arabian Oil Company, Cornell UniversityInventors: Mazen Y. Kanj, Mohammad Harunar Rashid, Emmanuel Giannelis
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Patent number: 10040990Abstract: A method for improving the performance of fracturing processes in oil production fields may rely on polymer coated particles carried in the fracturing fluid. The particles may include heavy substrates, such as sand, ceramic sand, or the like coated with polymers selected to absorb water, increasing the area and volume to travel more readily with the flow of fluid without settling out, or allowing the substrate to settle out. Ultimately, the substrate may become lodged in the fissures formed by the pressure or hydraulic fracturing, resulting in propping open of the fissures for improved productivity.Type: GrantFiled: February 3, 2016Date of Patent: August 7, 2018Inventors: Tommy K. Thrash, Calder Hendrickson
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Patent number: 10040988Abstract: The present invention relates to a milk-like friction reducer used in slick water fracturing and belongs to the technical field of oilfield chemicals. This friction reducer is obtained via free radical polymerization in water by using component A, component B and component C; wherein said component A is a mix of nonionic water-soluble monomers having carbon-carbon double bond; wherein said component B is a mix of water-soluble polymeric stabilizers obtained from monovalent cationic monomers; and wherein said component C is a mix of monovalent inorganic salts. The present invention is environmentally-friendly and easy to use. Its subsequent friction reducer is convenient to add on-the-fly and leads to no foaming without adding anti-foamer. Moreover, unlike other regular friction reducers, it is tolerant with various brines and compatible with common oilfield additives. The subject friction reducer can achieve an extent of friction reduction of greater than 70%.Type: GrantFiled: February 28, 2015Date of Patent: August 7, 2018Assignee: Phoenix C&W, Inc.Inventors: Weichu Yu, Jun Wu
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Patent number: 10023785Abstract: A thixotropic agent comprised of a gel which is comprised of a polymeric organic material cross-linked with certain boehmite aluminas having a crystallite size of less than about 100 ? as measured on the 120 plane.Type: GrantFiled: August 22, 2012Date of Patent: July 17, 2018Assignee: Sasol Performance Chemicals GmbHInventor: David A. Barclay
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Patent number: 10018017Abstract: Copolymers containing acryloylmorpholine and vinylimidazole, and optionally vinylcaprolactam and/or n-vinyl pyrrolidone, have shown superior results in hydrate inhibition tests at conditions of 7° C. subcooling dosed at 1 vol % based on the water cut of the system fluids. The copolymer product has also passed high TDS (total dissolved solids) brine compatibility tests and secondary property tests including foaming and hot injection tests which make it useful as a kinetic hydrate inhibitor in gas production systems susceptible to the formation of natural gas hydrates.Type: GrantFiled: July 17, 2015Date of Patent: July 10, 2018Assignee: Baker Hughes, a GE company, LLCInventors: Howard James Spencer, Ravinder Virdee, Michael P. Squicciarini, Gordon T. Rivers, Marc N. Lehmann
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Patent number: 10017680Abstract: Crosslinked polymers that may be useful, for example, as viscosifiers or fluid-loss control additives for well treatment and servicing fluids are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising a base fluid and a crosslinked polymer composition comprising at least one polymer that comprise at least one N-vinyl lactam monomeric unit, and at least one crosslinker selected from the group consisting of: an acrylamide-based crosslinker, an acrylate-based crosslinker, an ester-based crosslinker, an amide-based crosslinker, any derivative thereof, and any combination thereof; and introducing the treatment fluid into at least a portion of a wellbore penetrating at least a portion of a subterranean formation.Type: GrantFiled: August 15, 2014Date of Patent: July 10, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Hui Zhou, Jay Paul Deville, Chesnee Lae Davis
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Patent number: 10005951Abstract: The present invention relates to resin compositions for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include obtaining or providing a resin composition that includes a hardenable composition including a hardenable resin. The resin composition also can include a hardening composition including a water control hardening agent. The method can include contacting a subterranean material downhole with the resin composition, and reacting the hardenable composition and the hardening composition, to give a hardened resin composition. In some embodiments, the resin composition provides both particulate consolidation and water control.Type: GrantFiled: August 1, 2013Date of Patent: June 26, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Loan K. Vo, Philip D. Nguyen
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Patent number: 10005953Abstract: The present disclosure provides for shape memory proppants, methods for making shape memory proppants, and methods of using shape memory proppants, and the like. The strong expandable proppants of the present disclosure may be used in maintaining fracture openings.Type: GrantFiled: November 4, 2015Date of Patent: June 26, 2018Assignee: BOARD OF SUPERVISORS OF LOUISIANA STATE UNIVERSITY AND AGRICULTURAL AND MECHANICAL COLLEGEInventors: Arash Dahi Taleghani, Amir Shojaei, Guoqiang Li
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Patent number: 10000683Abstract: Crosslinked sulfonate-containing polymers may be stable in high density, monovalent brines, which may render such polymers particularly useful in drilling fluids in general and, especially, in the subclass of drilling fluids known as drill-in fluids. For example, a drilling fluid may include a crosslinked sulfonate-containing polymer dispersed in a monovalent brine having a density of about 8 lb/gal to about 20 lb/gal, wherein the crosslinked sulfonate-containing polymer comprises: reactants of a first repeating unit and a crosslinker that react to form the crosslinked sulfonate-containing polymer, wherein the first repeating unit is a sulfonic acid-containing monomer present from 50% to 99.99% by weight of the reactants, and wherein the crosslinker comprises at least two olefinic bonds.Type: GrantFiled: July 1, 2015Date of Patent: June 19, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Kay Ann Galindo, Hui Zhou, Weibin Zha
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Patent number: 10000692Abstract: A method of treating a treatment zone of a subterranean formation penetrated by a wellbore of a well, the method including the steps of: (A) forming a treatment fluid comprising: (i) an aqueous phase comprising water having at least 1,000 ppm total dissolved inorganic salts; (ii) a carboxymethyl hydroxyethyl cellulose, wherein: (a) the carboxymethyl hydroxyethyl cellulose has a carboxymethyl degree of substitution is in the range of about 0.3 to about 0.45 per glucopyranose unit in the polymer; and (b) the carboxymethyl hydroxyethyl cellulose has a hydroxyethyl molecular substitution is in the range of about 2.1 to about 2.8 per glucopyranose unit in the polymer; and (iii) a breaker for the carboxymethyl hydroxyethyl cellulose; and (B) introducing the treatment fluid into the treatment zone. In embodiments, the carboxymethyl hydroxyethyl cellulose may or may not be crosslinked.Type: GrantFiled: August 9, 2013Date of Patent: June 19, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Loan Vo, Tingji Tang