Abstract: A process for drilling cavities in subterranean formations includes a step of removal of the drill cuttings using an aqueous fluid in the form of a foam, obtained by mixing: an aqueous composition (Ci) including, per 100% by weight: from 0.5% by weight to 25% by weight of a compound of formula (I): R1—C(O)—NH—CH(COOM)-(CH2)n—COOM? (I) in which n represents an integer equal to 1 or 2, R1 represents a linear or branched, saturated or unsaturated aliphatic hydrocarbon-based radical including from eight to eighteen carbon atoms, M represents a monovalent cation and M?, which is identical to or different from M, represents a hydrogen atom or a monovalent cation; or of a mixture of compounds of formula (I), and from 75% to 99.5% by weight of water, with a gas or a mixture of gases, chosen from air, nitrogen or carbon dioxide.
Type:
Grant
Filed:
December 13, 2011
Date of Patent:
February 2, 2016
Assignee:
SOCIETE D'EXPLOITATION DE PRODUCTS POUR LES INDUSTRIES CHIMIQUES SEPPIC
Inventors:
Marie-Francoise Gayral Chirac, Jerome Guilbot, Andre Benattar
Abstract: Methods and compositions relating to poly(hydroxyl urethane) compounds are described herein that are useful as, among other things, binders and adhesives. The cross-linked composition is achieved through the reaction of a cyclic carbonate, a compound having two or more thiol groups, and a compound having two or more amine functional groups. In addition, a method of adhesively binding two or more substrates using the cross-linked composition is provided.
Type:
Grant
Filed:
February 3, 2014
Date of Patent:
January 26, 2016
Assignee:
U.S. Department of Energy
Inventors:
David Luebke, Hunaid Nulwala, Chau Tang
Abstract: An improved drilling and completion fluid can be used in subterranean drilling for oil and gas. Sodium silicate and potassium silicate-based drilling fluids are commonly used drilling fluids with the notable attributes of exceptional shale stabilization characteristics coupled with exceptional environmental performance Environmental and wellbore stabilization characteristics are improved by using high ratio aqueous silicates wherein ratio is defined as the molar ratio of SiO2:Me2O, where Me is an alkali and is most commonly sodium or potassium (i.e. Na2O and K2O). For high ratio aqueous alkali silicates, the molar ratio of SiO2:Me2O can range from just over 4.0 to about 12.0.
Abstract: An expanded bead of a polylactic acid resin, having an exterior surface, a surface region including the entire exterior surface and having a weight of one-sixth to one-fourth the weight of the expanded bead, and a center region located inside the surface region and having a weight of one-fifth to one-third the weight of the expanded bead, wherein the expanded bead, the surface region and the center region, after having been subjected to a pretreatment including a heat treatment at 110° C. for 120 minutes followed by cooling at a cooling speed of 2° C./min, have endothermic calorific values of (Br:endo), (Brs:endo) and (Brc:endo), respectively, when measured by heat flux differential scanning calorimetry at a heating speed of 2° C./min in accordance with JIS K7122 (1987), and wherein (Br:endo) is greater than 25 J/g and (Brs:endo) is smaller than (Brc:endo) and is not smaller than 0 J/g.
Abstract: The present invention relates to a process for mineral oil extraction by means of Winsor type III microemulsion flooding, in which an aqueous surfactant formulation comprising at least three ionic surfactants which are different with regard to the alkyl moiety (R1)(R2)—CH—CH2— and are of the general formula (R1)(R2)—CH—CH2—O-(D)n-(B)m-(A)l-XYa?a/bMb+ is injected through injection boreholes into a mineral oil deposit, and crude oil is withdrawn from the deposit through production boreholes. The invention further relates to surfactant formulations of ionic surfactants of the general formula.
Type:
Grant
Filed:
April 21, 2011
Date of Patent:
September 29, 2015
Assignee:
BASF SE
Inventors:
Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel, Petra Neumann, Veronika Wloka, Martin Bock
Abstract: A method is disclosed to inhibit scale formation in aqueous systems whereby a threshold amount of a scale inhibiting agent, represented by an aminoacid alkylphosphonic acid, is added to the aqueous system. The aminoacid moiety can be represented by ?-species or by species having, at least, two or more carbon atoms between the carboxylic moiety and the amine group. These aminoacid based inhibitors exhibit unusually superior performance and system acceptability compared to leading state-of-the-art inhibitors.
Type:
Grant
Filed:
June 5, 2013
Date of Patent:
August 18, 2015
Assignee:
ITALMATCH CHEMICALS SPA
Inventors:
Patrick P. B. Notte, Albert Devaux, Jan H. J. Van Bree, Tessa Johnson
Abstract: Elongated microcapsules, such as elongated hydrophobic-core and hydrophilic-core microcapsules, may be formed by pulse stirring an emulsion or shearing an emulsion between two surfaces moving at different velocities. The elongated microcapsules may be dispersed in a coating formulation, such as paint.
Type:
Grant
Filed:
January 20, 2012
Date of Patent:
August 18, 2015
Assignee:
The United States of America as Represented by the Administrator of the National Aeronautics and Space Administration
Inventors:
Luz M. Calle, Wenyan N. Li, Jerry W. Buhrow, Stephen A. Perusich, Scott T. Jolley, Tracy L. Gibson, Martha K. Williams
Abstract: The invention relates to radiation-curable aqueous composition comprising an (meth)acrylated polyurethane prepolymer obtained from the reaction of a polyisocyanate, optionally a polyol, at least one hydrophilic compound containing at least one reactive group capable to react with isocyanate groups and which is capable to render the polyurethane pre-polymer dispersible in aqueous medium either directly or after the reaction with a neutralizing agent to provide a salt, an (meth)acrylated compound containing at least two reactive groups capable to react with isocyanate groups and an (meth)acrylated compound containing essentially one reactive group capable to react with isocyanate groups, said composition comprising an amount of (meth)acrylated and polymerizable ethylenically unsaturated groups of at least 3 meq per g.
Type:
Grant
Filed:
March 30, 2007
Date of Patent:
July 21, 2015
Assignee:
ALLNEX BELGIUM S.A.
Inventors:
Michel Tielemans, Dirk Bontinck, Jean-Claude Van Overvelt
Abstract: Disclosed is an arylsulfonic acid compound characterized by being represented by formula (1). By using this compound as an electron-acceptor material, highly uniform film formability can be achieved. By using a thin film containing the arylsulfonic acid compound in an OLED device or a PLED device, there can be obtained excellent EL device characteristics such as low driving voltage, high luminous efficiency and long life. (In the formula, X represents O, S or NH; Ar represents an aryl group; and n represents the number of sulfonic groups, which is an integer of 1-4.).
Abstract: The proposal is made for a process for the preparation of a minisuspoemulsion of submicron core/shell particles, wherein the starting material is a suspoemulsion of a first disperse liquid phase I in a second continuous liquid phase II, which comprises, in the first disperse liquid phase I, submicron particles of a solid C forming the core, and a precursor substance PS for the shell dissolved in molecularly disperse form and, if appropriate, a reactant R, and wherein the submicron core/shell particles CS are prepared in the first disperse liquid phase I of the suspoemulsion by chemical or physical conversion of the precursor substance PS for the shell.
Type:
Grant
Filed:
November 13, 2007
Date of Patent:
July 14, 2015
Assignee:
BASF Aktiengesellschaft
Inventors:
Thomas Danner, Bernd Sachweh, Sonja Viereck
Abstract: In one aspect, hollow nanoparticles are described herein. In some embodiments, a hollow nanoparticle comprises a metal shell and a cavity substantially defined by the shell, wherein the shell has a thickness greater than or equal to about 5 nm and the cavity has a curved surface. In another aspect, methods of making hollow nanoparticles are described herein. In some embodiments, a method of making hollow nanoparticles comprises forming a plurality of gas bubbles and forming a shell on the surface of at least one of the plurality of gas bubbles, wherein at least one of the gas bubbles is electrochemically generated. In another aspect, composite particles are described herein. In some embodiments, a composite particle comprises at least one nanoparticle and a polycrystalline metal shell substantially encapsulating at least one nanoparticle, wherein at least one surface of at least one nanoparticle is not in contact with the shell.
Type:
Grant
Filed:
June 15, 2011
Date of Patent:
May 26, 2015
Assignee:
BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM
Abstract: The hydration of clays in drilling operations can be inhibited by employing an aqueous based drilling fluid containing from about 0.2 to about 5 wt % of a hydration inhibitor that comprises bis-hexamethylene-triamine, bis-hexamethylene-triamine salts, or mixtures thereof.
Type:
Grant
Filed:
June 18, 2013
Date of Patent:
May 19, 2015
Assignee:
LAMBERTI SPA
Inventors:
Luigi Merli, Franscesca Giani, Pierangelo Pirovano, Giovanni Floridi, Giuseppe Li Bassi
Abstract: Disclosed is an aqueous polyurethane dispersion obtained by dispersing in water a reaction product obtained by reacting a reaction mixture comprising at least one organic, aliphatic, cycloaliphatic or aromatic di, tri or poryisocyanate, at least one isocyanate reactive polycarbonate diol, triol or polyol, at least one compound comprising at least one isocyanate reactive group and at least one free radically polymerizable unsaturated group, and at least one compound comprising at least one isocyanate reactive group and at least one at least dispersing active group, and optionally at least one compound comprising at least two isocyanate reactive groups and having a molecular weight of less than 1000 g/mol.
Type:
Grant
Filed:
March 16, 2006
Date of Patent:
May 19, 2015
Assignee:
PERSTORP CHEMICALS AB
Inventors:
Göran Ziegler, David James, Kent Sörensen
Abstract: The invention relates to radiation curable coating systems on the basis of aqueous polyurethane dispersions, to a method for the production thereof, to the use of the coating systems as paints and/or adhesives, and to objects and substrates provided with said paints and/or adhesives.
Type:
Grant
Filed:
January 30, 2010
Date of Patent:
May 19, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Stefan Sommer, Harald Blum, Jürgen Lippemeier, Miguel Fernandez
Abstract: The present invention provides a silicone microparticle, wherein the silicone microparticle comprises 100 parts by mass of a silicone elastomer spherical microparticle having volume-average particle diameter of 0.1 to 100 ?m and 0.5 to 25 parts by mass of a polyorganosilsesquioxane to cover surface of the silicone elastomer spherical microparticle, wherein the polyorganosilsesquioxane has a shape of granule with the size thereof being 60 nm or less. There can be provided a silicone microparticle having low agglomerating tendency and excellent dispersibility even if rubber hardness of a silicone elastomer microparticle is low and a particle diameter thereof is small.
Abstract: Thermoplastic polymer mixture (M) comprising at least one poly(aryl ether ketone) (P1), at least one poly(arylene sulfide) (P2), and between 0 and 25 wt. % of the total weight of the thermoplastic mixture (M), of a thermoplastic polymer material (P3) consisting of (i) at least one poly(biphenyl ether sulfone) (P3a), and/or (ii) at least one poly(ether imide) (P3b), and/or at least one poly(ether imide sulfone) (P3c), wherein: the combined weight amount of the poly(aryl ether ketone) (P1) and the poly(arylene sulfide) (P2), based on the total weight of the polymer mixture (M), is of at least 30%, and the weight amount of the poly(aryl ether ketone) (P1), based on the combined weight of the poly(aryl ether ketone) (P1) and the poly(arylene sulfide) (P2), is of at most 90%.
Type:
Grant
Filed:
April 23, 2008
Date of Patent:
April 7, 2015
Assignee:
Solvay Advanced Polymers, L.L.C.
Inventors:
Mohammad Jamal El-Hibri, Edward Ryan, Brian A. Stern
Abstract: The invention relates to hydrophilic aliphatic polyurethane foams obtained by reacting special prepolymers having a low monomer concentration and hydrophilic polyisocyanates in the presence of water. The absorptive properties make said polyurethane foams particularly suitable for producing wound dressings, cosmetic articles, or incontinence products.
Abstract: A polyurethaneurea system that includes in some embodiments Parts A and B reaction components for a polyurethaneurea, wherein an exemplary embodiment provides a Part A that comprises between 55 and 75 wt. % of an oligomeric polyol, between 3 and 7 wt. % of an aromatic diamine chain extender, and between 0.1 and 1.5% of a reactivity catalyst; Part B includes between 1 and 15 wt. % of a short aromatic diisocyanate and between 5 and 35 wt. % of an aromatic diisocyanate prepolymer that is the reaction product of a short aromatic diisocyanate and a diol. The polyurethaneurea system may further comprise an elastomer-surface activator comprising a second short aromatic diisocyanate and a second aromatic diisocyanate prepolymer, wherein at least one of the second diisocyanates may be the same as at least one of the diisocyanates of Part B.
Type:
Grant
Filed:
October 30, 2007
Date of Patent:
March 17, 2015
Assignees:
Michelin Recherche et Technique S.A., Compagnie Generale des Etablissements Michelin
Abstract: A polyurethane/polyisocyanurate foam is obtainable from the reaction of A) a polyol component comprising A1) an aromatic polyester polyol, A2) a polyether polyol started on a carbohydrate polyol and A3) a polyether polyol started on ethylene glycol, wherein the total hydroxyl number of the polyol component A) is from ?150 mg KOH/g to ?300 mg KOH/g; with B) a polyisocyanate component, wherein the equivalent ratio of NCO groups to the sum of the hydrogen atoms reactive towards NCO groups is from ?110:100 to ?200:100. This foam has improved adhesion properties to facings and is suitable for the production of composite elements without requiring the use of an additional adhesion promoter.
Type:
Grant
Filed:
November 9, 2010
Date of Patent:
March 17, 2015
Assignee:
Bayer MaterialScience AG
Inventors:
Rolf Roers, Torsten Heinemann, Maria Dolors Mateu