Abstract: Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, a method of producing crosslinked polymers using said curable compositions, crosslinked polymers thus produced, and orthodontic appliances comprising the crosslinked polymers.

Abstract: Various photo-luminescent films and associated methods are enabled. For instance, a photo-luminescent film comprises a substrate layer comprising a plurality of pores, and a composite comprising luminescent nanoparticles disposed in the plurality of pores.

Abstract: Powder including low molecular weight polytetrafluoroethylene having a melt viscosity of 1×102 to 7×105 Pa·s at 380° C., having a melt viscosity of 1×102 to 7×105 Pa·s at 380° C., having an average particle size of 1.0 to 50 ?m, and containing 30 or more carboxyl groups at ends of the molecule chain per 106 carbon atoms in the main chain, wherein the powder is substantially free from C8-C14 perfluorocarboxylic acids and salts thereof.

Abstract: A coating system for the decoration of a recyclable plastic substrate. The coating system includes a primer layer and a decorative layer. The primer layer includes at least one coating which is made from at least one coating material having 60 to 80 wt.-% of at least one difunctional, alcoxylated acrylate monomer, 5 to 15 wt.-% of at least one acrylate oligomer, 5 to 15 wt.-% of at least one of at least one carbonyl-functional acrylate and at least one methacrylate oligomer or 5 to 15 wt.-% of at least one of at least one polyethylene glycol acrylate and at least one polyethylene glycol methacrylate, and 1 to 10 wt.-% of at least one photoinitiator, each of which are based on a total weight of the coating material.

Abstract: The present invention relates to processes for selective reshaping of nanoparticles in three dimensional articles, three dimensional articles produced by such processes, and methods of using such three dimensional articles. As a result of the aforementioned process, such three dimensional articles can have selective tuning that arises, at least in part, from the reshaped nanoparticles found in such articles. Such tuning provides the aforementioned articles with superior performance that can be advantageous in the areas including such as optical filters, multi-functional composites and sensing elements.

Abstract: A method of preparing a polyolefin is disclosed. In some examples, the method comprises contacting an olefin monomer with an olefin polymerization precatalyst and a photoacid generator (PAG) to provide an olefin polymerization mixture; and irradiating the olefin polymerization matrix for a first period of time with ultraviolet or visible light, activating the precatalyst to catalyze polymerization of the olefin monomer, thereby preparing a polyolefin. Additive manufacturing approaches employing the methods are also disclosed, as are ink compositions comprising an olefin polymerization precatalyst and a PAG.

Abstract: This disclosure relates to polysiloxanes and polysiloxane compositions having dual-curable properties, to methods for forming articles from such compositions, and to articles formed thereby. In one embodiment, the polysiloxane comprises at least about two alkenyl groups and at least about two (meth)acryloyl groups.

Abstract: The present application provides a method for preparing a composite material. The present application provides a method for preparing a composite material comprising a metal foam and a polymer component, wherein the polymer component is formed in an asymmetrical structure on both sides of the metal foam, and a composite material prepared in such a manner.

Abstract: Provided is an acrylic resin composition having high chemical resistance and high oil resistance. This acrylic resin composition contains a polymer that includes a unit derived from a predetermined monomer, wherein the proportion of the unit derived from the predetermined monomer contained in the polymer to 100% by mass of all monomer units constituting the polymer is 40-99% by mass, and the tensile strength of the acrylic resin composition after being immersed in oleic acid for 24 hours is 50% or more of the value of the tensile strength thereof before being immersed in oleic acid.

Abstract: A method for producing shortened anionically modified cellulose fibers having an average fiber length of 1 ?m or more and 500 ?m or less, the method including cleaving sugar chains of anionically modified cellulose fibers by thermal decomposition under temperature conditions of 50° C. or higher and 230° C. or lower, wherein the average fiber length of the anionically modified cellulose fibers is 700 ?m or more and 10000 ?m or less. By the use of shortened anionically modified cellulose fibers or the like obtained by the method for production of the present invention, a dispersion containing fine cellulose fibers having a low viscosity and excellent handling property can be prepared while at a high concentration, so that the dispersion can be suitably used in various industrial applications such as daily sundries, household electric appliance parts, packaging materials for household electric appliances, automobile parts, and materials for three-dimensional modeling.

Abstract: Provided is a composition for optical stereolithography the stereolithography (photocuring) of which is completed in a shorter time and which provides a stereolithographic object having excellent strength (strength that prevents the occurrence of a fracture and the like when the stereolithographic object is subjected to an impact, or dropping, and strength with which the stereolithographic object can withstand repeated folding). The composition for optical stereolithography of the present invention includes (A) a diallyl phthalate-based polymer; (B) radical polymerizable compounds having a methacrylic group and/or an acrylic group; (C) a radical polymerization initiator; and (D) a sensitizer. The (B) radical polymerizable compounds includes at least (B1) an epoxy (meth)acrylate having a methacrylic group and/or an acrylic group, or (B2) a dioxane (meth)acrylate having a methacrylic group and/or an acrylic group. The composition contains 0.

Abstract: A rubber-reinforcing cord of the present invention is a rubber-reinforcing cord for reinforcing a rubber product. The rubber-reinforcing cord includes at least one strand. The strand includes at least one filament bundle and a coating provided to cover at least a portion of a surface of the filament bundle. The coating includes a rubber component and a crosslinking agent. The crosslinking agent includes two or more isocyanate compounds.

Abstract: Disclosed is a composition comprising at least one interpolymer dispersed within an aqueous medium, the interpolymer comprising at least one unsaturated monomer and at least one selected from the group consisting of at least one conjugated acid, at least one mono-ester of a conjugated acid, and mixtures thereof, and, optionally, at least one surfactant configured to stabilize the interpolymer within the aqueous medium. The conjugated acid may be derived from a naturally-occurring oil, such as tung oil. There is also provided a method for preparing a composition, comprising forming an interpolymer comprising the at least one unsaturated monomer and the at least one selected from the group consisting of at least one conjugated acid, at least one mono-ester of a conjugated acid, and mixtures thereof. There is still further provided a pressure sensitive adhesive comprising the composition prepared according to the disclosed method.

Abstract: The present invention provides a thermosetting material, which contains the following components (A) to (C) and which, when measured with a rotational viscometer at a constant shear rate (JIS K7117-2:1999), exhibits a viscosity at 25° C. and 10 s?1 of 5 Pa·s or more and 200 Pa·s or less and, when measured with a rotational viscometer at a constant shear rate in the same manner as above, exhibits a viscosity at 25° C. and a shear rate of 100 s?1 of 0.3 Pa·s or more and 50 Pa·s or less. (A): a (meth) acrylate compound in which a substituted or unsubstituted alicyclic hydrocarbon group having 6 or more carbon atoms is ester-bonded, and which, when measured with a rotational viscometer at a constant shear rate in the same manner as above, exhibits a viscosity of 5 to 300 mPa·s as a viscosity measured at 25° C. and 10 to 100 s?1; (B): spherical silica; and (C): a black pigment.

Abstract: Disclosed is an ink composition for photo-curable ink jet printing, comprising (A) at least one selected from the group consisting of hexanediol acrylate, 3-methyl-1,5-pentanediol diacrylate, dipropylene glycol diacrylate, and hydroxy pivalic acid neopentyl glycol diacrylate, (B) at least one of vinyl amide monomer and acryloyl amine monomer, (C) an acrylated amine compound having two photopolymerizable functional groups and two amino groups in a molecule, (D) a monofunctional monomer (excluding vinyl amide monomer which is the (B) component), and a photopolymerization initiator, wherein a content of the (A) component is 40 to 70% by mass, wherein a content of the (B) component is 5 to 30% by mass, wherein a content of the (C) component is 0.1 to 15% by mass, and wherein a viscosity is 200 mPa·s or less.

Abstract: A polymerizable liquid useful for the production of a three-dimensional object comprised of silicone, or a copolymer thereof, which includes at least one constituent selected from the group consisting of (i) a blocked or reactive blocked siloxane-containing prepolymer, (ii) a blocked or reactive blocked siloxane-containing polyisocyanate, and (iii) a blocked or reactive blocked siloxane-containing polyisocyanate chain extender. Methods of using the same in additive manufacturing processes such as continuous liquid interface production are also described.

Abstract: The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent derived from a barbiturate, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization.

Abstract: This disclosure provides resin formulations which may be used for 3D printing and thermally treating to produce a ceramic material. The disclosure provides direct, free-form 3D printing of a preceramic polymer, followed by converting the preceramic polymer to a 3D-printed ceramic composite with potentially complex 3D shapes. A wide variety of chemical compositions is disclosed, and several experimental examples are included to demonstrate reduction to practice. For example, preceramic resin formulations may contain a carbosilane in which there is at least one functional group selected from vinyl, allyl, ethynyl, unsubstituted or substituted alkyl, ester group, amine, hydroxyl, vinyl ether, vinyl ester, glycidyl, glycidyl ether, vinyl glycidyl ether, vinyl amide, vinyl triazine, vinyl isocyanurate, acrylate, methacrylate, alkacrylate, alkyl alkacrylate, phenyl, halide, thiol, cyano, cyanate, or thiocyanate.

Abstract: Disclosed here is a method for making an architected three-dimensional aerogel, comprising providing a photoresin comprising a solvent, a photoinitiator, a crosslinkable polymer precursor, and a precursor for graphene, metal oxide or metal chalcogenide; curing the photoresin using projection microstereolithography layer-by-layer to produce a wet gel having a pre-designed three dimensional structure; drying the wet gel to produce a dry gel; and pyrolyzing the dry gel to produce an architected three-dimensional aerogel. Also disclosure is a photoresin for projection microstereolithography, comprising a solvent, a photoinitiator, a crosslinkable polymer precursor, and graphene oxide.

Abstract: The present disclosure relates to polyurethane based switchable adhesives. In at least one embodiment, a switchable adhesive composition comprises an adhesive component, which is formed from at least one isocyanate and a material or materials capable of undergoing cross-linking with isocyanate other than by free radical polymerization.