Patents Examined by Joan Thierstein
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Patent number: 4180452Abstract: A method for hydrogenating coal to produce benzene and other gas and liquid products. In the process, the coal is pulverized and dried, and then saturated with methanol. The methanol saturated coal is slurryed in benzene and the slurry is exposed to microwave energy of a frequency and for a period of time sufficient to effect hydrogenation of the coal. The benzene liquid effects an immediate quench and the hydrogenation products are collected and separated. The principal product of the hydrogenation is benzene. Unreacted coal and char may be recycled or subjected to gasification with steam and oxygen to produce synthesis gas which can be converted to methanol.Type: GrantFiled: August 22, 1977Date of Patent: December 25, 1979Assignee: Cameron Engineers, Inc.Inventor: Jerry E. Sinor
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Patent number: 4158637Abstract: Hydrocarbons are formed of coal and water. The water is converted or dissociated separately into hydrogen and oxygen in a first chemical reactor by thermochemical and/or electrolytic processing. The resulting hydrogen is then reacted with the coal in a second reactor to produce the hydrocarbons. Residual carbon from the second reactor is reacted in a third reactor with oxygen derived from the first reactor to produce carbon monoxide. The carbon monoxide is reacted with residual hydrogen from the second reactor or hydrogen from the first reactor to produce additional hydrocarbons. The energy for the endothermic and/or electrolytic processing in the reactors and for auxiliary equipment of the apparatus is supplied by a very high-temperature, gas-cooled, nuclear reactor by heat interchange with the cooling gas, helium. The cooling gas operates through heat-exchange means which isolates the cooling gas from the processing apparatus.Type: GrantFiled: April 30, 1976Date of Patent: June 19, 1979Assignee: Westinghouse Electric Corp.Inventor: Andrew R. Jones
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Patent number: 4141847Abstract: Lubricating oil additives having both dispersant and viscosity index-improving properties are prepared by reacting a selectively hydrogenated star-shaped polymer having at least four arms of polymers or copolymers of dienes and monoalkenyl arenes with an alpha-beta unsaturated carboxylic acid or derivative, and then reacting the resulting intermediate with an amine.Type: GrantFiled: May 11, 1977Date of Patent: February 27, 1979Assignee: Shell Oil CompanyInventor: Thomas E. Kiovsky
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Patent number: 4136013Abstract: In the catalytic hydrogenation of a substance in a water-immiscible organic liquid medium, a metallic hydrogenation catalyst is conveniently and effectively dispersed in the reaction mixture by addition as an emulsion of an aqueous solution of a salt of the metal in the liquid medium. The method is particularly applicable to the liquefaction of coal.Type: GrantFiled: February 28, 1977Date of Patent: January 23, 1979Assignee: The Dow Chemical CompanyInventors: Norman G. Moll, George J. Quarderer
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Patent number: 4136044Abstract: This specification discloses a lubricant composition containing esters of arylaminophenoxyalkyl carboxylic acids as an antioxidant and new compositions of matter useful as antioxidants.Type: GrantFiled: October 12, 1977Date of Patent: January 23, 1979Assignee: Mobil Oil CorporationInventor: Milton Braid
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Patent number: 4134821Abstract: A coal liquefaction process is provided in which a solvent is used to at least partially liquefy the coal. The process is maintained in solvent balance without extraneous addition of make-up solvent. The required balance is effected by selectively recovering from the liquefaction product an oil-containing liquid phase, at least a portion of the liquid phase being thereafter hydrogenated to form coal solvent in sufficient amount to replenish that lost. The selective recovery of the desired liquid phase is effected by means of a deasphalting solvent that preferentially separates asphaltenes and benzene insolubles from the coal extract.Type: GrantFiled: June 1, 1977Date of Patent: January 16, 1979Assignee: Continental Oil CompanyInventor: Everett Gorin
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Patent number: 4134822Abstract: A process for reducing the amount of catalyst required for coal hydrogenation-liquefaction reactions involving dry fed, short-residence coal reaction systems. Coal particles are mixed with dry catalyst material having a vapor pressure of 1 to 1000 mm Hg at reaction conditions. Catalysts having such high vapor pressure have demonstrated greatly improved ability to establish the required intimate contact for efficient catalysis when dry mixed and enable significant reduction of amounts of catalyst material required. In systems utilizing ZnCl.sub.2 as the catalyst material, reductions in percent weight concentration to the range of 1 to 2% are accomplished.The invention disclosed herein was developed in part under contract funding provided by the Energy Research and Development Administration of the United States Government.Type: GrantFiled: January 3, 1977Date of Patent: January 16, 1979Assignee: University of UtahInventors: Ralph E. Wood, Wendell H. Wiser, Larry L. Anderson, Alex G. Oblad
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Patent number: 4133742Abstract: An efficient and practical process is provided, permitting greatly increased recovery of hydrocarbons from oil shales and tar sands. Steps involved include mixing oil shale or tar sand in water, with pulverized coal, to form an amalgam, and separation of water to be reused in the process. The separated amalgam contains the hydrocarbons of the shale or sand and constituents of coal in which mineral matter content is considerably reduced.Type: GrantFiled: July 29, 1977Date of Patent: January 9, 1979Inventor: William H. Hill
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Patent number: 4133741Abstract: A plurality of hydrocarbon fractions are recovered from hydrocarbon-bearing material such as oil shale in a continuous retort wherein a bed of the material is moved through a heating chamber, the heating being for a time and at a temperature effective to strip increasingly heavier hydrocarbon fractions from the material as it moves through the heating chamber. The hydrocarbon fractions are collected by a plurality of collection means disposed along the path of movement of the bed for recovery of a corresponding plurality of hydrocarbon fractions.Type: GrantFiled: November 5, 1974Date of Patent: January 9, 1979Assignee: The Superior Oil CompanyInventors: Bernard E. Weichman, John H. Knight
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Patent number: 4132627Abstract: An integrated process for the conversion of coal to liquid and gaseous fuels is disclosed. Coal and oil are hydrocracked in the presence of a particulate mixture of sand or clay and an iron and chromium alloy to form carbon-coated sand and an overhead product comprising cracked oil vapors and fuel gases. The carbon is removed from the sand to form carbon monoxide with the concomitant generation of heat. The carbon monoxide is used to reduce oxidized iron and chromium alloy located in a hydrogen generating bed. Steam is passed into the bed of reduced metallic alloy to form hydrogen for use in the coal reactor and the regenerated particulate mixture of sand and iron and chromium alloy is returned to the coal reactor to continue the sequence of carbon removal and to provide heat for the hydrocracking reaction.Type: GrantFiled: December 6, 1977Date of Patent: January 2, 1979Inventor: Arnold M. Leas
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Patent number: 4130495Abstract: A non-factice sulfohalogenated jojoba oil characterized by a M.W. under 4,500, an I.V. greater than 5, a sulfur content below 8.7% and having a sulfur to halogen mole ratio of about 1.1:1.0 to about 1.0:1.1.Type: GrantFiled: November 18, 1976Date of Patent: December 19, 1978Assignee: Ben-Gurion University of the Negev Research and Development AuthorityInventors: Jaime Wisniak, Hanoch Benajahu
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Patent number: 4128471Abstract: A process for liquefying coal employing a low temperature preheater zone, a higher temperature non-catalytic hydrocracking zone and a catalytic hydrogenation zone in series. Carbon monoxide passes through the preheater and non-catalytic hydrocracking zones but is removed from the process in advance of the catalytic hydrogenation zone.Type: GrantFiled: November 30, 1976Date of Patent: December 5, 1978Assignee: Gulf Research & Development CompanyInventors: Huey P. Malone, John A. Paraskos, Herman Taylor, Jr.
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Patent number: 4125459Abstract: This invention relates to the production of oils of specified higher quality at the same yield or to the production of a higher yield of oils of the same quality from a bituminous material by a combination of propane and pentane deasphalting than would otherwise be obtainable by utilizing either propane or pentane deasphalting processes alone. This is effected by subjecting the bituminous material first to a pentane deasphalting process to produce a light fraction containing resins and oils, followed by a propane deasphalting process on the resin-oil fraction previously obtained and the recycle of at least a portion of the resins fraction back to the pentane deasphalting process.Type: GrantFiled: December 19, 1977Date of Patent: November 14, 1978Assignee: Kerr-McGee Refining CorporationInventor: Leo Garwin
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Patent number: 4125452Abstract: In a process for the liquefaction of coal in which coal liquids containing phenols and other oxygenated compounds are produced during the liquefaction step and later hydrogenated, oxygenated compounds are removed from at least part of the coal liquids in the naphtha and gas oil boiling range prior to the hydrogenation step and employed as a feed stream for the manufacture of a synthesis gas or for other purposes.Type: GrantFiled: June 10, 1977Date of Patent: November 14, 1978Assignee: Exxon Research & Engineering Co.Inventor: Edward Effron
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Patent number: 4124485Abstract: Ash-containing solids are separated from coal liquid by adding a blend comprising alcohol and a light oil fraction to said coal liquid, followed by a solids-liquid separation step.Type: GrantFiled: April 4, 1977Date of Patent: November 7, 1978Assignee: Gulf Research & Development CompanyInventors: Norman L. Carr, Edgar L. McGinnis
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Patent number: 4123347Abstract: A process for liquefying a particulate coal feed to produce useful petroleum-like liquid products which comprises contacting; in a series of two or more coal liquefaction zones, or stages, graded with respect to temperature, an admixture of a polar compound; or compounds, a hydrogen donor solvent and particulate coal, the total effluent being passed in each instance from a low temperature zone, or stage to the next succeeding higher temperature zone, or stage, of the series. The temperature within the initial zone, or stage, of the series is maintained about 70.degree. F and 750.degree. F and the temperature within the final zone, or stage, is maintained between about 750.degree. F and 950.degree. F. The residence time within the first zone, or stage, ranges, generally, from about 20 to about 150 minutes and residence time within each of the remaining zones, or stages, of the series ranges, generally, from about 10 minutes to about 70 minutes.Type: GrantFiled: September 26, 1977Date of Patent: October 31, 1978Assignee: Exxon Research & Engineering Co.Inventor: Peter S. Maa
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Patent number: 4123348Abstract: A process for performing reactions in a reaction vessel contaning a catalyst bed of solid particles wherein the reaction between reactants is enhanced by imparting pulsating motion to the solid particles. The pulsating motion can be produced by pulsating introduction of at least one of the reactants, pulsating the introduction of recycled reaction products, etc.Type: GrantFiled: November 17, 1976Date of Patent: October 31, 1978Assignee: Saarbergwerke AktiengesellschaftInventor: Helmut Wurfel
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Patent number: 4121995Abstract: A slurry of carbonaceous particles such as coal containing an oil soluble polar substituted oleophilic surfactant, suitably an amine substituted long chain hydrocarbon, is liquefied at high temperature and high hydrogen presence. The pressure of surfactant results in an increase in yield and the conversion product contains a higher proportion of light and heavy oils and less asphaltene than products from other liquefaction processes.Type: GrantFiled: October 7, 1976Date of Patent: October 24, 1978Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: George C. Hsu
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Patent number: 4120775Abstract: A system for effecting a sharp separation from tar sands of the large weight fraction of coarse materials present therein and for recovering bitumen, or tar, from the remaining product, wherein, as a first step, finely divided particles of a tar sand are added to a liquid hydrocarbon solvent in an agitation zone to form a dilute solution of the bitumen component which is agitated to maintain both the coarse as well as the fine solid particles present in a well dispersed condition. This dispersion flows downwardly from the agitation zone and through a shallow conduit, generally rectangular in cross section and having an opening extending across its bottom portion over which the dispersion passes. During the short residence time of the dispersion over the opening, the coarse sand particles, which under the influence of gravity fall faster than the fines, selectively drop out of the dispersion and pass through the conduit opening into an underlying sand-receiving chamber.Type: GrantFiled: July 18, 1977Date of Patent: October 17, 1978Assignee: Natomas CompanyInventors: Robert G. Murray, Benjamin J. Gikis
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Patent number: 4120803Abstract: Mono-alkenes, aliphatic conjugated dienes and unsaturated fatty acids or esters thereof copolymerize with a Friedel-Crafts catalyst to yield a copolymer containing carboxylic acid or ester groups which are reacted with a polyamine to amidate the carboxyl group leaving free amine groups. The free amine groups are reacted with polycarboxylic acids to form inter- and intra-molecular bridged polyamides. These compounds are effective ashless dispersants in lubricating oil and have detergency properties in distillate fuels.Type: GrantFiled: November 15, 1976Date of Patent: October 17, 1978Assignee: Ethyl CorporationInventor: Robert E. Malec