Patents Examined by John F Pettitt
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Patent number: 12129972Abstract: The present disclosure relates to a system for pressurizing liquid hydrogen (LH2). The system has a pressure vessel for containing an initial quantity of LH2, with the pressure vessel containing an inlet orifice and an outlet orifice. A vaporizer is used which has an inlet and an outlet. A supply tube is used to couple the outlet orifice of the pressure vessel with the inlet of the vaporizer. A discharge tube couples the discharge outlet of the vaporizer with the inlet orifice of the pressure vessel. The vaporizer receives LH2 from the pressure vessel via the supply tube during a pressurization operation, warms the LH2 using an ambient environment, and discharges heated and pressurized H2 back to the pressure vessel through the supply tube.Type: GrantFiled: July 16, 2019Date of Patent: October 29, 2024Assignees: Lawrence Livermore National Security, LLC, Gas Technology InstituteInventors: Guillaume Petitpas, Kenneth Kriha, Sandeep Alavandi
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Patent number: 12104850Abstract: A process for recovering at least one fluid (e.g. xenon gas and/or krypton gas, etc.) from a feed gas can include utilization of a compression system, primary heat exchanger unit, a pre-purification unit (PPU), and other units to separate and recover at least one desired fluid. In some embodiments, fluid flows output from a first heat exchanger or separation system of the plant can be split so that a portion of a stream is output for downstream processing to purify xenon (Xe) and/or krypton (Kr) product flow(s) while another portion of the stream is recycled to a compression system or the PPU to undergo further purification and heat exchange so that the product output for downstream processing has a higher concentration of Xe or Kr. Some embodiments can be configured to provide an improved recovery of Xe and/or Kr as well as an improvement in operational efficiency.Type: GrantFiled: May 6, 2021Date of Patent: October 1, 2024Assignee: Air Products and Chemicals, Inc.Inventors: Declan Patrick O'Connor, Garret C. Lau
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Patent number: 12072143Abstract: Plant and method for liquefying a flow of gas, having a cooling circuit that includes at least one exchanger (5) for cooling the gas, and at least one expansion turbine (6) which is mounted on a rotary axle which is supported by at least one bearing (7) of the gas-static type, the cooling circuit (2) also including a pressurized gas injection conduit that is configured to supply pressurized gas to the bearing (7) in order to provide support to the rotary axle, the plant (1) further includes a recovery conduit (9) that is configured to recycle at least a portion of the gas which has been used to support the rotary axle of the bearing (7) with a view to liquefying the gas.Type: GrantFiled: June 8, 2020Date of Patent: August 27, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Pierre Barjhoux, Fabien Durand, Franck Delcayre
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Patent number: 12060873Abstract: A cryopump includes a cryopump container, a pressure sensor that measures a pressure in the cryopump container and generates time-series pressure data indicating the measured pressure, a vent valve that is provided on the cryopump container, is electrically operable to open and close, and is capable of being mechanically opened by a differential pressure between inside and outside the cryopump container, and a controller that, during cryopump regeneration, detects stabilization of the measured pressure based on the time-series pressure data from the pressure sensor and controls the vent valve to open upon detection of the stabilization of the measured pressure.Type: GrantFiled: March 17, 2021Date of Patent: August 13, 2024Assignee: SUMITOMO HEAVY INDUSTRIES, LTD.Inventor: Kakeru Takahashi
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Patent number: 12050056Abstract: A method for liquefying a feed gas stream. A refrigerant stream is cooled and expanded to produce an expanded, cooled refrigerant stream. Part or all of the expanded, cooled refrigerant stream is mixed with a make-up refrigerant stream in a separator, thereby condensing heavy hydrocarbon components from the make-up refrigerant stream and forming a gaseous expanded, cooled refrigerant stream. The gaseous expanded, cooled refrigerant stream passes through a heat exchanger zone to form a warm refrigerant stream. The feed gas stream is passed through the heat exchanger zone to cool at least part of the feed gas stream by indirect heat exchange with the expanded, cooled refrigerant stream, thereby forming a liquefied gas stream. The warm refrigerant stream is compressed to produce the compressed refrigerant stream.Type: GrantFiled: December 15, 2022Date of Patent: July 30, 2024Assignee: ExxonMobil Technology and Engineering CompanyInventors: Yijun Liu, Fritz Pierre, Jr.
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Patent number: 12038230Abstract: A chiller can be configured as a chiller for a gasification system or other type of system or plant. In some embodiments, the chiller can be configured to utilize a single heat source, such as low grade waste heat in the form of hot water, and/or low pressure steam to drive one or more absorption-based chillers to cool inlet air to one or more adsorbers of a pre-purification unit (PPU). In the event of the detection of an undesired impurity spike (e.g. carbon dioxide spike, etc.) an additional amount of heat source can be withdrawn from the gasification system to increase the level of cooling the absorption chiller can provide to improve the removal of impurities. An automated control loop can be utilized in some embodiments. The control loop can be configured to check for an impurity concentration and adjust operations accordingly.Type: GrantFiled: September 29, 2020Date of Patent: July 16, 2024Assignee: Air Products and Chemicals, Inc.Inventors: Gowri Krishnamurthy, Nasim Ul Hassan Malik, Qiao Zhao
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Patent number: 12025373Abstract: A system and method for treating associated gas in which a stream of raw gas is passed through safety valving, an inlet pressure control mechanism, and an inlet scrubber. Pressure/temperature data is transmitted to a control system via pressure and temperature transducers. The raw gas is sent to a gas compressor to generate pressurized gas, which is sent to an aerial cooler and a chiller heat exchanger, in which a chilling media contacts the pressurized gas. The chilled pressurized gas is sent to a vapor liquid separator to generate processed gas, which is routed through either a system backpressure valve or a pressure reducing recycle valve that directs the processed gas to the inlet scrubber. The processed gas that has passed through the system backpressure valve is delivered as fuel or routed through a backpressure regulating recycle valve that directs the processed gas to a system inlet pressure reducing valve.Type: GrantFiled: August 15, 2021Date of Patent: July 2, 2024Inventors: Mark Peterson, James L. Haider, Brian R. Cebull, Austin VanDelinder, Tim Boelter, Stephen Doll, Wade Wolf, Joey Hope
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Patent number: 12005999Abstract: A ship comprises: a liquefied gas storage tank; a multi-stage compressor for compressing a boil-off gas discharged from a storage tank and comprising a plurality of compression cylinders; a second heat exchanger for heat exchanging a fluid, which has been compressed by the multi-stage compressor, and thus cooling same; a first decompressing device for expanding a flow (“flow a1”) partially branched from the flow (“flow a”) that has been cooled by the second heat exchanger; a third heat exchanger for heat exchanging, by “flow a1” which has been expanded by the first decompressing device as a refrigerant, the remaining flow (“flow a2”) of “flow a” after excluding “flow a1” that has been branched and thus cooling same; and a second decompressing device for expanding “flow a2” which has been cooled by the third heat exchanger.Type: GrantFiled: October 21, 2016Date of Patent: June 11, 2024Assignee: HANWHA OCEAN CO., LTD.Inventors: Seung Chul Lee, Seon Jin Kim
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Patent number: 11988445Abstract: A system and process that are configured to prepare incoming hydrocarbon feedstocks for storage. For incoming ethane gas, the embodiments can utilize a plurality of vessels to distill the incoming feedstock to vapor and liquid ethane that is suitable for storage. The embodiments can direct the vapor to a demethanizer column that is downstream of the vessels and other components. The process can include stages for distilling an incoming feedstock at a plurality of vessels to form a vapor and a liquid for storage; directing the vapor to a demethanizer column; and circulating liquid from the demethanizer column back to the plurality of vessels.Type: GrantFiled: February 18, 2021Date of Patent: May 21, 2024Assignee: GE Oil & Gas, Inc.Inventors: David Allen Kennedy, Mark Mulherin Salamon, Christopher Scott Yount
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Patent number: 11988446Abstract: A method and apparatus for producing high-purity nitrogen and low-purity oxygen using three-column rectification are provided, in which: nitrogen and oxygen undergo rectification in different columns, with high-purity nitrogen and low-purity oxygen being separated out of air simultaneously, thereby overcoming the shortcomings of conventional low-purity oxygen production equipment, and also reducing equipment investment, lowering energy consumption, increasing product added value, and realizing a circular economy effect.Type: GrantFiled: September 8, 2021Date of Patent: May 21, 2024Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Alain Briglia, Huali Xie, Yongshun Zhang
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Patent number: 11965693Abstract: Disclosed are a helium gas liquefier and a method for liquefying a helium gas. The disclosed helium gas liquefier includes: a first cooling part including a first cooling column; a first cold head installed on the first cooling column, and a first cylinder in which the first cooling column and the first cold head are built; a second cooling part including a second cooling column, a second cold head installed on the second cooling column, and a second cylinder in which the second cooling column and the second cold head are built; and a liquid helium storage disposed under the second cooling part.Type: GrantFiled: December 18, 2020Date of Patent: April 23, 2024Assignee: KOREA BASIC SCIENCE INSTITUTEInventors: Yeon Suk Choi, Myung Su Kim
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Patent number: 11965694Abstract: In a process of the separation of a mixture of carbon monoxide, hydrogen and methane, the mixture is sent to a scrubbing column, a bottom liquid withdrawn at the bottom of the scrubbing column is depleted in hydrogen with respect to the mixture and is sent to a stripping column, a bottom liquid from the stripping column is sent to a separation column and a liquid enriched in methane withdrawn from the bottom of the separation column is vaporized in order to form a final product.Type: GrantFiled: July 24, 2019Date of Patent: April 23, 2024Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Manon Cortale, Bertrand Demolliens, Antoine Hernandez, Guillaume Teixeira
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Patent number: 11933541Abstract: A system and method for producing two or more nitrogen product streams and a crude argon stream from a nitrogen and argon producing air separation unit is provided. The disclosed embodiments of the cryogenic-based nitrogen and argon producing air separation units and associated air separation cycles include the means for directing a first portion of a boil-off stream from an argon condenser of the air separation unit to a waste expansion refrigeration circuit and concurrently recycling a second portion of the boil-off stream from the argon condenser to the main air compression system of the air separation unit to be mixed or blended with the incoming feed air. Optionally, a third portion of the boil-off stream from the argon condenser may be further compressed in a cold compressor and returned to the lower pressure column.Type: GrantFiled: August 11, 2021Date of Patent: March 19, 2024Assignee: Praxair Technology, Inc.Inventor: Zhengrong Xu
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Patent number: 11933539Abstract: A system and method for improving the performance of an oxygen, nitrogen, and argon producing air separation unit configured to produce a gaseous nitrogen product stream is provided. By recycling the argon condenser boil-off vapor stream to the main air compression train, the argon recovery and oxygen recovery while maintaining the production level of a medium or high pressure gaseous nitrogen product stream. In addition, some operational cost savings in terms of lower power costs can also be realized compared to some prior art oxygen, nitrogen, and argon producing air separation units.Type: GrantFiled: August 11, 2021Date of Patent: March 19, 2024Assignee: Praxair Technology, Inc.Inventors: Zhengrong Xu, Neil M. Prosser
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Patent number: 11874055Abstract: An embodiment of a method for supplying refrigerants to a liquefied natural gas (LNG) facility includes: advancing a first refrigerant from a first storage device to a heat exchanger, the first refrigerant having a first temperature; advancing a second refrigerant from a second storage device to the heat exchanger, the second refrigerant having a second temperature different than the first temperature; flowing the first refrigerant and the second refrigerant through the heat exchanger; adjusting the second temperature based on at least a transfer of heat between the first refrigerant and the second refrigerant in the heat exchanger; and transferring the first refrigerant and the second refrigerant to the LNG facility.Type: GrantFiled: February 18, 2015Date of Patent: January 16, 2024Assignee: CONOCOPHILLIPS COMPANYInventors: Paul R. Davies, James L Harris
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Patent number: 11815308Abstract: A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a first heat exchanger and re-combined with the natural gas stream, and heavy hydrocarbons are removed therefrom to generate a separated natural gas stream and a separator bottom stream. Liquids are separated from the separator bottom stream to form an overhead stream, which is cooled and separated to form a recycle gas stream. The recycle gas stream is compressed. A first portion of the compressed recycle gas stream is directed through the first heat exchanger and directed to the separator as a column reflux stream. The separated to natural gas stream is used as a coolant in the first heat exchanger to thereby generate a pretreated natural gas stream, which is compressed and liquefied.Type: GrantFiled: April 17, 2020Date of Patent: November 14, 2023Assignee: ExxonMobil Technology and Engineering CompanyInventors: Yijun Liu, Fritz Pierre, Jr.
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Raw material gas liquefying device and method of controlling this raw material gas liquefying device
Patent number: 11808502Abstract: A raw material gas liquefying device includes a feed line which feeds a raw material gas, a refrigerant circulation line which circulates a refrigerant, the refrigerant circulation line including an expansion unit of a turbine type which expands the refrigerant to generate cryogenic energy, and an expansion unit entrance valve provided at an entrance side of the expansion unit, a heat exchanger which exchanges heat between the raw material gas and the refrigerant, a cooler which performs initial cooling of the raw material gas and the refrigerant by heat exchange with liquid nitrogen, and a controller which manipulates the opening rate of the expansion unit entrance value and performs a feedback control so that the rotation speed of the expansion unit reaches a predetermined target value, and outputs the opening rate command to the expansion unit entrance valve, at start-up and stop of the expansion unit.Type: GrantFiled: December 4, 2017Date of Patent: November 7, 2023Assignee: KAWASAKI JUKOGYO KABUSHIKI KAISHAInventors: Naotaka Yamazoe, Tomohiro Sakamoto, Hidetaka Miyazaki, Daisuke Kariya, Yasuo Miwa, Yuichi Saito, Yosuke Kimura -
Patent number: 11808518Abstract: A natural gas liquefaction system and method for effectively and efficiently removing heavy hydrocarbons and converting natural gas into liquefied natural gas. Natural gas streams entering the system may consist of varied gas compositions, pressures, and temperatures. In embodiments the system may comprise a natural gas (NG)-to-liquefied natural gas (LNG) portion and a closed-loop refrigeration portion comprising a closed-loop single mixed refrigerant system. In other embodiments the system may comprise an NG-to-LNG portion and a closed-loop refrigeration portion comprising a closed-loop gaseous nitrogen expansion refrigeration system. All embodiments utilize an integrated heat exchanger with cold-end and warm-end sections and integrated multi-stage compressor and expander configurations (e.g. compander) in order to increase overall operation flexibility and efficiency.Type: GrantFiled: May 21, 2020Date of Patent: November 7, 2023Assignee: EnFlex, Inc.Inventors: James Zhao, Shukui Zhao
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Patent number: 11774173Abstract: A technology liquefies natural gas. The natural gas liquefaction method pre-cools treated natural gas by ethane evaporation, sub-cools liquefied gas using cooled nitrogen as a refrigerant, reduces liquefied gas pressure, separates non-liquefied gas and diverts liquefied natural gas. Before pre-cooling the natural gas is compressed, ethane is evaporated during the multi-stage pre-cooling of liquefied gas with simultaneous evaporation of ethane using cooled ethane as a refrigerant. Ethane generated by evaporation is compressed, condensed and used as a refrigerant during the cooling of liquefied gas and nitrogen, with nitrogen being compressed, cooled, expanded and fed to the natural gas sub-cooling stage. The natural gas liquefaction unit contains a natural gas liquefaction circuit, an ethane circuit and a nitrogen circuit. The natural gas liquefaction circuit includes a natural gas compressor, a cooler unit, ethane vaporizers, a closed-end subcooling heat exchanger, and a separator, connected in series.Type: GrantFiled: September 8, 2022Date of Patent: October 3, 2023Assignee: Publichnoe Aktsionernoe Obshchestvo “NOVATEK”Inventors: Rafail Minigulovich Minigulov, Sergei Vladimirovich Rudenko, Oleg Evgenievich Vasin, Dmitriy Nikolaevich Gritsishin, Evgeniy Igorevich Sobolev
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Patent number: 11719387Abstract: A method for conditioning a liquid cryogen in a tank includes reducing a pressure of the liquid cryogen in the tank for reducing a temperature of the liquid cryogen and condensing any vapor boil-off in the tank for reclaiming the liquid cryogen in the tank. The liquid cryogen may be selected from the group consisting of liquid nitrogen (LIN), liquid oxygen (LOX), and liquid argon (LAR).Type: GrantFiled: December 5, 2018Date of Patent: August 8, 2023Assignee: Messer Industries USA, Inc.Inventors: Simon J. Shamoun, Isaiah Edmonds